QUIZ (CHEMISTRY)

ALCOHOL, ETHER & PHENOL

NAME: ………………................ M.MARKS: M.Time: minutes SUB: CHEMISTRY

1. Reaction of tertiarty butyl alcohol with hot Cu at 350°C produces

(A) Butanol (B) Butanal (C) 2-Butene (D) 2-methyl propene
2. NaBH H / Pt
B  4  —CH=CH—CHO 2  A
A and B are:
(A)
—CH2CH2CHO, —CH=CH—CH2OH
(B) —CH2CH2CH2OH, —CH=CH—CH2OH
(C)
—CH=CH—CH2OH in both cases
(D)
—CH2CH2CH2OH in both cases

3. The end product in the following sequence of reaction is

OH

NaOH CO2 HCl

  X 
400K
 Y  Z

(A) salicyldehyde (B) benzoic acid

(C) pchlorohydroxybenzene (D) 2hydroxybenzoic acid
4. HBO process converts the following alkene into A.
HBO
A, Where A is

OH OH

(A) OH (C) OH
OH

(D) None of these

(C)

CH3
-
H3C O K
5. H3C
CH3
Br
Z would be
CH3
OCMe 3
H3C CH3
(C) H3C (D) None
(A) CH2 (B) H3C O
CH3
CH3

6. Identify the final product:

C 6H5 CH3

H
H5 C 6 C C CH3 

?
OH OH
Me C6 H 5
C6H5 CH3
(A) H5 C6 C C Me (B) H5 C 6 C C CH3 (C) (D) None
H5 C6 C C CH3
O Me CH3 O
CCl4 Zn dust Soda lim e
7. C6H5 OH 
NaOH, 
 X 
Heat
 Y 
Z
In the above sequence Z is
(A) Toluene (B) Cresol (C) Benzene (D) Benzol
 QUIZ (CHEMISTRY)
8. Cl

OEt
*  The product is
O
Cl Cl
(A) * (B) *
HO OEt EtO OH
*
EtO
(C) (D ) OEt
*
O O

9. CH3

O O H3 O 
  X  Y. X and Y are


CH3 COOH
CH3 O
H3C

(A) H3C CHO, (B) O

, H3 C CHO
CH3
COOH OH
HO
O
O

O
(C) O O (D)
, H3C CHO CH3
CH3 OH
O

10.
CH2
O

H3 O
  A, A is
CH3
OH OH H3C
HO

(A) (B) (C) (D)

CH3 CH3
CH3
OH
CH3 OH
OH

11. 14
CH2
O
H3C CH3
KOH 3 O


 A 

 
Zn / H O

2

The products of ozonolysis are,

OH
OH H3C CH3
14
H3C CH3  CO2
(A) (B)
 H3C
O
O
OH
OH
H3C CH3
H3C CH3
14 and CO2
 H3C
(C) (D)
O
O
14
O
H

12. The acidic character of 1°, 2°, 3° alcohols, H2O and RC  CH is in the order
(A) H2O  1°  2°  3° RC  CH (B) RC  CH  3°  2°  1°  H2 O
(C) 1°  2°  3°  H2 O  RCCH (D) 3°  2°  1°  H2O  RCCH
 QUIZ (CHEMISTRY)
13. The product in the following reaction is
CH3

HO H+
 Product
OH

(A) (B) CH 3 (C) O (D) None of the above

CH3
CH3

OH

14.

H



OH

Rearranged alkene product after rearrangement at low temperature will be mainly,

(A) (B) (C) (D)


H3 O
15. Ester A (C4H8O2) + CH3 MgBr (2-parts)   C4H10O(B) (alcohol) alcohol B reacts fastest with
Lucas reagent . Hence A and B are
O O
(A) CH3COC2H5, (CH3)3 COH (B) HCOC3H7, (CH3)2 CH OH
O O
(C) CH3COC2H5, (CH3)2 CH OH (D) HCOC3H7,(CH3)3 COH

16. The product (z) in the following sequence of reaction is

AlCl3 (I) BH3 / THF HF
C6H6+CH2 =CHCH2Cl   (x)   (j)   C9H10 (z)
(II) H2 O2 ,OH heat

(A) (B) (C) (D) None of the above

F

OH
17.

CS2
 Br2 
0o C
 A, A is

(A) Br (B) Br (C) OH (D) OH

Br Br

OH

OH Br

18. Two molecules given below are capable of intra molecular hydrogen bonding. Which is likely to
form more stable hydrogen bonds?
H H H
I
C C
CH3
C-CH3 H3C C C
H3C C
H
O O O O

H H
[A] [B]
(A) A
(B) B
(C) both (a) and (b) will from equally stable H-bonds
(D) None of these
 QUIZ (CHEMISTRY)
19. O

 HCl ( X ), ( X) will be

O
OH OH
OH OH
Cl

(A) (B) (C) (D)

Cl Cl Cl
OH OH
OH OH

20.
O H O
3
 A. A is

CH3
OH OH CH3
OH

(A) (B) (C) (D)

CH3 OH
HO H3C OH CH3
CH3

21. Which among the following compounds are oxidised by NaIO4?

1) H 2C OH 2) H 2C OH 3) CHO 4) H2 C OH 5)
COOH
CH 2 (CH-OH)4 H 2C OH C O
H 2C OH
H 2C OH H 2C OH CHO H2 C OH

Select the correct answer from the codes given below

(A) 1, 2, 3 (B) 2, 3, 4 (C) 1, 2 (D) 2, 3, 4, 5

22. Which one is the stronger base?

(A) CH3CH2O– (B) CF3CH2O– (C) both of equal strength (D) can’t say

23. Predict the product of reaction below

O
||
OH + CH3 – C – Cl Pyridine
 
O O
|| ||
(A) O – C – CH3
(B) C – OH

O
(C)
|| (D) CH3
C – CH3

24. CH3
cold dil alk HIO4
  X  
KMnO4
CH3
Y would be
CH3 CH3
(A) OH (B)
O
CH3
OH CH3
HO CH3
(C) (D) None
O O
 QUIZ (CHEMISTRY)
25. CH2 – CH3
Br2 h

CH2 – CH2Br CH2 – CH3 CH– CH3 Br

(A) (B) (C) CH2 – CH3
Br Br (D)
Br Br

H 
26.
 (A): (A) is
O OH

(A) (B)

(C) (D) none of the above

27. Conversion of chlorobenzene into phenol of Dow’s process is an example of

(A) free radical substitution (B) nucleophilic substitution
(C) electrophilic substitution (D) rearrangement

28. The order of reactivity of the following alcohols towards conc. HCl is
CH3 H3 C CH3
F CH3 Ph OH
F OH HO OH
I II III IV
(A) I > II > III > IV (B) I > III > II > IV
(C) IV > III > II > I (D) IV > III > I > II

29. Predict the major product

+ excess HI 
O
(A) HO – CH2 – CH2 – CH2 – CH2 – I (B) HO – CH2 – CH2 – CH2 – CH2 – OH
(C) I – CH2 – CH2 – CH2 – CH2 – I (D) No reaction

30. The principle mononitration product of o-cresol is

(A) 2-methyl-4-nitrophenol (B) 2-methyl-5-nitrophenol
(C) 2-methyl-6-nitrophenol (D) 2-methyl-3-nitrophenol


QUIZ (CHEMISTRY)
ANSWERS
ALCOHOL, ETHER & PHENOL
1. D 2. B 3. D 4. A

5. A 6. B 7. C 8. D

9. B 10. B 11. C 12. A

13. C 14. B 15. A 16. B

17. A 18. A 19. B 20. B

21. B 22. A 23. A 24. D

25. C 26. C 27. B 28. C

29. C 30. A