CLASS : ADV_CC TIME: 45 MIN CLASS TEST-6

Single Correct
Q.1 What will be reactivity order for isocyanide test for following amines?
NH2 NH2 NH2 NH2

(I) (II) (III) (IV)

OCH3 CH3
H3C CH CH3
3

(A) I > III > II > IV (B) I > IV > II > III (C*) I > II > III > IV (D) II > III > IV > I

2 
H 3C  C  C  N  CH 3 Hg / H ( i ) LAH
 X
Q.2 | H 2O (ii ) H 2 O
CH 3
Which statement is incorrect for X.
(A) X does not react with Na metal
(B*) X react with Heinsberg’s reagent to form a product which is insoluble in KOH
(C) X does not evolve N2 on reaction with HNO2
(D) X is soluble in H2SO4


H3O
Q.3 CH2(COOEt)2 + (CH2)3Br2 NaO
 Et
 I   II
EtOH
II is :

(A) (B) (C) (D*)

O
|| 18
Q.4 Me3C  C  O CMe 3 dil

.H 2SO 4

Product of this reaction and the mechanism is:
18
O O
|| 18 ||
(A) Me3C  C  OH + Me3C– OH , A (B*) Me3C  C  OH + Me3C–OH, A 1
AC1 AL

O O
|| 18 | | 18
(C) Me3C  C  OH + Me3C– OH , A (D) Me3C  C  OH + Me3C–OH, A 2
AC2 AL

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 
Q.5 H3C – CH2 – COOH HVZ
 reaction
 KCN
 H/
H 2O
 P
P is :

(A) H 3C  CH  COOH (B) H 3C  CH  COOH

| |
CH 2  COOH CH
||
O

(C*) H 3C  CH  COOH (D) H 3C  CH  COOH

| |
COOH C  CH 3
||
O

O
Cl 
Q.6 H
2O
 H A,
OH
Ais
O O
O O O
(A) O (B) (C*) O (D)
O

Q.7 Aq. Salt of which acid can produce cyclopropane after electrolysis.
(A) Maleic acid (B) Succinic acid (C*) Glutaric acid (D) Adipic acid

More than one may be correct

Q.8 Which reaction(s) can produce 2° amine as major product?
(A) H 3C  CH 2  C  NH  CH 3 NaBH
 4/ EtOH


||
O

O
NH
(B*) (
i ) LiAlH 4
 
(ii ) H 2 O

 
(i ) OH O H / H 2O
(C)   
N–H     
( ii ) CH3  CH 2 CH 2  Br


Pd / 
(D*) H 3C  CH 2  N  C H2 / 

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Q.9 Which of the following is false :
O O

(A)  Product of this reaction is a lactum.

NaOH
 NH
3
Me

(B*) CH2=CH OH SOCl

2  Major product of this reaction is chiral and having R

H
configuration.
O
Me—C

(C*) Me—C gives two molecules of iodoform per molecule when treated with NaOH + I2.

O
(D*) isopropanol gives yellow precipitate with I2 in NH4OH.

Q.10 Which will elimination CO2 onlyon heating

(A*) Me  C  CH 2  COOH (B) Ph  C  CH 2  SO 2 H
|| ||
O O
OH
COOH
(C*) (D*) CH2 = CH–CH2–COOH

Q.11 Methanoic acid and Ethanoic acid can be differentiated by:

(A*) Fehling test (B) Iodoform test (C*) Shiff's test (D) NaHCO3 test

Q.12 Method to distinguished RNH2 & R2NH

(A*) NaNO2 / HCl (B*) Hoffmann's musturd oil reaction
(C*) Hinsberg test (D) Red Litmus

Comprehension
Paragraph Question No. 13 to 15
CN +
H /H2O  NH3/
A B C
CN O OH¯/Br 2
O¯
CHO
(i) , O
O¯ D
E (ii) H2O
+
(iii) H
Q.13 D is
COO¯ COO¯ COO¯
COO¯
(A) (B) (C*) (D)
COO¯ NH2
NH2 Br
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Q.14 E is
CH = CH – COOH CH = C – COOH
(A) (B*) CH2 – COOH

CH = CH – CHO CH = C – COOH
(C) (D) CH2 – CH2 – COOH

Q.15 Which part will form after reaction of B with NaCl.

O O O
ONa O–Cl Cl
(A) (B) (C) (D*) No reaction
Cl C–ONa Cl
O O O

Match the column

Q.16 Column I Column II (Products)
(A) R  C  OCH 3 + NaCl  (P) R  C  O  C  CH 3
|| || ||
O O O

(B) R  C  Cl + O C  CH 3  (Q) R  C  Cl
|| || ||
O O O
(C) R  C  OH + SOCl2  (R) CH3O¯Na+
||
O

(D) R  C  OC 2 H 5 + O C  CH 3  (S) C 2 H 5O 
|| ||
O O
(T) No reaction
[Ans. (A) T (B) P (C) Q (D) T ]
Subjective
Q.17 Number of compounds, which can evolve CO2 on heating, are.......
O
COOH H3C – CH – COOH H3C – C–CH2 – C–O–H

NO2 NH O

O
H3C – CH– COOH
COOH
CH2–COOH COOH
OH
Ph – CH – CH2 – COOH HO – C – C – OH
H3C – CH2 – COOH
OH O O
If your answer is X then fill 000X in OMR sheet. [Ans.0006 ]

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Q.18 Number of reactions which can produce 1° amine are :
O

(i) OH–
N – H (ii) R–I
(I) R – C – NH2 OH


/ Br2
 (II)
(iii) OH –/H 2O
O O
NH
(i) LAH C N (i) LAH
(III) CH3 (IV)
(ii) H2O (ii) H2O
O
NH–Et H—/ H2O
+
(V) N C +
H / H 2O (VI)
O
(i) LAH
(VII) (ii) H2O (VIII) C N H—/ H2O
NO2
H3C Et
C PCl5
(IX)
N
OH

Q.19 Consider following reactions.


(I) HBr
 KCN
 H/
H 2O

HBr
(II) H2C = CH2  (
i ) Mg / ether
 
H 2O 2 ( ii ) CO 2
( iii ) H 

(III) H 3C  C  OH ( i ) SOCl 2


|| (ii ) CH 2 N 2
(iii ) Ag 2O / H 2O / 
O
OH
(IV) PCC

H
(V) (
i ) Tollen 's reagent
 
(ii ) H 
O
O
||
(VI) H 3C  C  CH 2 (
i ) OH ¯

| ( ii ) H 
Cl
Number of reactions which can produce propanoic acid as major product are_____.
[Ans. 4]

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Q.20 Number of reaction which gives ester as major product.
ROH
(I) R – CH = C = O 

 (II) H  C  CH 3 mcPBA
 
H ||
O

(III) H 3C  C  OH P
2O 5 / 
  (IV) H 3C  C  O  C  CH 3 O
Et

|| || ||
O O O
(V) H 3C – CH2 – O – CH2 – CH3 CO
 /
BF3

CO  MeOH
 high P
(VI) Diethyl-carbonate   
MeMgX (1eq ) (VII) HC  CH    
Ca ( CO )8

O
||
(VIII) Me  C  OH CH
2N2
 [Ans. 0006]

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