VIBRANT ACADEMY ORGANIC CHEMISTRY

Class Test-2
(India) Private Limited Target IIT JEE 2024
CLASS : XII (MEGA)
Topic : Hydrocarbon (Hydrogenation)
CO2CH3
2  H
1.  ?
PtO2
CO2CH3 1 atm 
CO2CH3 CO2CH3

(A) (B)
CO2CH3 CO2CH3

2  H
2.  ?
PdC
H H
1 atm 
(A) (B) (C) Meso

3. CH2=CH2 + H–H  ?

(A) No reaction (B) CH3–CH3

CH3
2  H
4.  ?
PtO2
CH3 1 atm
CH3 CH3

(A) (B)
CH3 CH3
(cis) (Trans)

2  2H
5. CH3–CC–CH3  ?
PdC

(A) (B)

O
2 H
6.  ?
H3C Et Ni

HO H OH
H
(A) +
H3C Et H3C Et

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 HO H OH
H
(B) +
H3C Et H3C Et

7. H
2 ?

PdC

OH O OH
H
(A) (B) (C)

O ?
H2
-C
8. Ph–CH=CH–C–CH3 Pd
H2/Ni ?
O OH
(A) Ph–CH–CH–C–CH
2 2 3
and Ph–CH–CH–CH–CH
2 2 3

OH O
(B) Ph–CH–CH–CH
2 2 2
and Ph–CH–C–CH
2 3

H
2  (Major) ?
9. 
PdC

(A) (B)

2 H 1 mole 
10.  ?
PtO2
Selective reduction

(A) (B)

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 2 D
11.  ?
Ni

D D
(A) CH3 (B) CH3

D D
CH3
CH3

Me
H
2 ?
12. 
Ni
Et

Me Me

(A) H + H
Et Et
H H

Me

(B)
Et

H
2 ?
13. 
Ni

(A) (B)

O
2 ?H
14. 
H3C CH3 Ni

OH

(A) H C CH3 (B) CH3CH2–OH

3
H

O
2 ? H
15. 
H3C H Ni
(A) CH3–OH
(B) CH3–CH2–OH

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 O

H
2 ?
16. 
Ni

OH OH

(A) +

OH OH

(B) +

2H
17.  ?
Ni

OH OH OH OH

(A) + (B) +

2D
18.  ?
Ni
(A) Meso
(B) Racemic mixture

2D
19.  ?
Ni
(A) Meso
(B) Racemic mixture

2 H 1 mole 
20.  ?
Pt

(A) (B)

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 O

H
2 ?
21. 
PdC

O O O
O

(A) + (B) +

H Ph H Ph

Ph Ph H
H

CH3
CH2
2H
22.  ?
Pt

CH3 CH3
CH3 CH3
(A) +

CH3 CH3
CH3 CH3
(B) +

H
2  n–butane
23. X = total number of alkene 
Pt
(A) 3 (B) 2

H
2  Isopentane
24. y 
Ni
(A) 2 (B) 3

H
2  Neo pentane
25. z 
Ni
(A) 0 (B) 1

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 CH3
3H
2 
26.  ?
200C
CH3 200 atm

(A) (B)

CH3
3H
2 
27.  ?
200C
CH3 200 atm

(A) (B)

2 3H /Ni
28. (i) 
 ?
High temperature

(A) (B)

22H /Ni
(ii)  ?


(A) (B)

2H /Ni
(iii)  ?


(A) (B)

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 OH

2 H /Ni
29.  ?


OH

(A) (B)

O
2 H
30.  ?
H3C Cl PdBaSO4

O O
(A) (B)
H3C H H H

2 H
31. R–CH=O ?
PdBaSO4

(A) R–CH–R
OH
(B) R–CH2–OH

CH3 O
2 H
32. H C C Cl 
 ?
PdBaSO4
Et

CH3 O CH3 O
(A) H C C H (B) H C C OH
Et Et

O
2 H
33. 
 ?
PdBaSO4
Ph Cl

O O
(A) (B)
Ph OH Ph H

HCl
34. 
H–CC–CH=CH2 ?
(A) H2C=C–CH=CH2 (B) H2C=C–CH=CH2
Cl Cl

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35. Which of the following alkyne will not undergo Brich reduction :

(A) CH3–CC–Et
(B) CH3–CH2–CC–H

H3C H
2 H
36. H3C C C C CH3 
 Product
PdCaCO3
C C
H H

H3C H
(A) H3C CH CH C CH3
C C
H H

H3C H
(B) H3C CH2 CH2 C CH3
C C
H H

H3C H
2 H
37. H3C C C C H 
 'y' product and 1 chiral
PdCaCO3
C C
H CH3

H3C H
(A) H3C CH2 CH2 C CH3
C C
H H

H3C H
(B) H3C CH CH C H
C C
H CH3

Video solution by M S Chouhan (MSC sir)

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