VIBRANT ACADEMY ORGANIC CHEMISTRY

Class Test-3
(India) Private Limited Target IIT JEE 2024
CLASS : XII (MEGA)

Topic : Phenol
Single Choice Questions :
OH
O
1. (i) CO2, NaOH CH3 – C – Cl
(A) (B)
(ii) H

The product (B) is

(A) Aspirin (B) Oil of winter green
(C) Salol (D) Salicylic acid
O

OH OH O O CH3
COOH COOH
(i) CO2, NaOH CH3 Cl
Sol.
(ii) H (Acetylation)
(Aspirin)
(Kolbe's Schimdt reaction)

2. The product of the reaction of benzene with oxygen in the presence of V2O5 as catalyst at 200ºC is:
(A) Maleic anhydride (B) Benzoic acid
(C) Phenol (D) None of these

3. Dow’s process used in the industrial preparation of phenol, is -

NaOH 2 SiO
(A) C6H5Cl   C6H5OH + NaCl (B) C6H5CI+H2O   C6H5OH + HCl
CuCI2' 300  425 


(C) C6H5NH2 + HNO2   C6H5OH+N2+H2O (D) C6H5N2Cl +H2O  C6H5OH + N2 + HCl

OH
Br2, CS2
A (Major)
4. A and B are respectively:
Br2, H2O
B (Major)

OH OH
OH OH
Br Br
(A) & (B) &

Br Br

OH OH OH
Br Br OH Br Br
Br
(C) & (D) &

Br Br Br

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5. Observe the following reaction, and select the correct option:

OH

dil. HNO
3 Steam distillation
  (X) + (Y)   (Y) low boiling fraction ‘Y’ is:

OH OH OH OH
NO2 NO2 NO2
(A) (B) (C) (D)
NO2
NO2 NO2

6. Phenol reacts with conc. HNO3 in the presence of conc. H2SO4 to give
(A) Meta nitrophenol (B) Ortho nitrophenol
(C) Ortho and para nitrophenol (D) Picric acid

OH

7. CHCl3 + KOH Zn-Hg

(A) (B)
 HCl

Identify B is :
Cl OH OH OH
CH2Cl CH2Cl CH3 CH=O
(A) (B) (C) (D)

NH2 N2Cl

NaNO2+2HCl PhOH
8. Dye (coloured)

Which colour of the dye is formed ?

(A) Red (B) Orange (C) Yellow (D) Blue

NH2

(1) NaNO / HCl CHCl / KOH

9. 2 
    (P) 3 (Q)
( 2) H2O

CH3

Product (Q) is :

OH OH OH OH
CHO CO2H
(A) (B) (C) (D)
CHO CO2H
CH3 CH3 CH3 CH3

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10. Consider the reaction


+ OH
 X ; here X is

(A) (B) (C) (D) None

NH2
HO CH3
NaNO 2
11.   (A) (B) , Product (B) is
HCl (0 5 ºC) mild-basic

OH OH

(A) (B)
N = N – Ph
CH3 CH3

OH OH
N = N – Ph Ph
(C) (D)

CH3 CH3

CH3

12. NaNO2 H 2O
H2SO4 (warm)
NO2
NH2

CH3 CH3 CH3 CH3

(A) (B) (C) (D)

NO2 NO2
OH OH NO2

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13. What is the product of the following reaction ?

(1) H3PO4, heat,

(2) O2, heat
+
(3) H3O , heat

O OH

(A) (B) (C) (D)

Video solution by M S Chouhan (MSC sir)

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