1.

OH
CH2N2
1 eqv.  A, A is :

HO
NO 2 OH
OCH3 OH

(A) (B)
HO HO CH3

NO2 OH NO 2 OH
OH OH

(C) (D)
H3CO HO

NO2 OH NO 2 O CH3
1. C

CH3
2. OH  O C
HCl
   X
CH3
[X] is:
CH3 CH3
(A (B HO O C CH
HO C CH3
) ) H
OH
CH3 CH3

(C HO C C CH (D HO C OH
) O OH ) CH3

2. D
2. H3C H3C H3C

C O H C O H C O H
H3C H3C H3C
CH3 CH3

H3C C OH H3C C O H
H

+
O O O
H H H

So on
 OH
3. O
H


x
The major product (x) is
O
O
(A) (B)

OH OH

(C) (D)

3. C

OH

O
4. HCl
+  P(major)


In the given reaction ‘P’ is :

OH OH

(A) O (B)

OH
OH OH

(C) (D)

HO OH
4. C

5. For the reaction sequence

OH

PhSO Cl
NaF / DMSO

2
 A 
 B

NO 2
The compound B will be
 OH F
F

(A) (B)

NO2 NO 2
OH F

(C) (D)
F F
NO2 NO2
5. B
5. SO 2Ph
OH O F

PhSO Cl
2 NaF / DMSO
 
 


NO 2 NO 2 NO 2
(A) (B)
F– is very reactive unsolvated which can displace PhSCO3 which being a good leaving
group in presence of strong withdrawing group —NO2.

6. In the reaction given below:

OH NH2

CH3O C CH CH3 NaNO2 /HCl

  A
0o C  Major product 

CH3
The product ‘A’ is:

(A) CH3O C CH CH3 (B) H3C C CH OCH 3

O CH3 O CH 3
CH3
CH3O HC C CH3 CH3O C C H
O O
(C) (D)

CH3 CH3
6. B
6. CH3

OH NH2

CH3O C HC CH3 

NaNO2  HCl
 CH3O C CH CH3
0o C

HO N N

CH3
CH3

CH3
 N2 1,2  shift
CH3O
 C CH  H3C
CH3  C HC OCH3
HO OH

CH3
 H

 H3C C HC OCH3
O