Chemistry (Full Test) - Paper 2

FIITJEE Mumbai JEE Advanced Mock Test
C he m ist r y PART – II
SECTION – A
Straight Objective Type
This section contains 7 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for
its answer, out which ONLY ONE option is correct.
1. CHCl3 + KOH
A + B
(Expected) (Unexpected)
OH
The unexpected product B is
(A) (B)
OH OCH 3
CHO
(C) CHCl2 (D) CHO
H C
O O
OH
2. I2(s) | I- (0.1 M) half cell is connected to a H+ (aq.) | H2(1 bar) | Pt half cell and emf is found to be
0.7714 V. If EIo |I  0.535 V, find the pH of H | H2 half cell.
2
(A) 1 (B) 3 (C) 5 (D) 7
3. In the graph between  and Z for the Mosley’s equation, the 

intercept OX is -1 on  axis. What is the frequency when
atomic number (Z) is 51?
(A) 50 Hz (B) 100 Hz C
(C) 2500 Hz (D) None 45o
O Z
4. Sulphur reacts with chlorine in 1 : 2 ratio and forms X. Hydrolysis of X gives a sulphur compound
Y. What is the hybridization state of central atom in the compound Y?
(A) sp3 (B) sp2 (C) sp (D) dsp 2 A
5. Find out correct representation of trans - decaline H
H
(A) (B)
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FIITJEE Mumbai 2 JEE Advanced Mock Test
(C) (D) None of these
6. 50 ml of a solution containing 10 3 mol of Ag+ is mixed with 50 ml of a 0.1 M HCl solution. How
+
much [Ag ] remains in solution? Given: Ksp of AgCl = 10 10
(A) 2.5 109 M (B) 2.5  107 M (C) 2.5  108 M (D) 2.5  10 10 M
7. OCH 3
Ph - CH = CH2 O2/Pt H+, 

P Q X+Y
F
Where X is a compound that forms azodye with benzene diazonium chloride in faintly basic
medium.
Hence the products P, X and Y are respectively.
(A) Ph CH3
OH
and PhCOCH 3
,
OCH 3 OCH 3
(B) CH 2Ph
OH
and PhCH 2CHO

,
OCH 3 OCH 3
(C) Ph CH3
OH
O
and CH3
,
H 3CO
OCH3
(D) CH 2Ph
OH CH 2CHO
and
,
OCH 3
OCH 3
Multiple Correct Choice Type
This section contains 4 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out which ONE OR MORE is/are correct.
8. Some organic compounds are given below:

OH OH OH
H OH H OH H OH
H H CH2OH
H OH H
OH H OH H
HO OH HO HO C O
H OH H OH O H OH O
(I) OH HO (CH2)3
H O H O CH3
H
OH H H OHH
HO H HO H (IV)
H OH OH H
(II) (III)
Select the correct statement(s) about the above compounds from the following:
(A) Compounds (I) and (III) will reduce Fehling’s solution and will also mutarotate
(B) Compound (IV) will reduce Tollen’s reagent but not mutarotate
(C) Compound (II) will not be reducing but mutarotating
(D) The product(s) of the acid catalysed hydrolysis of both (II) and (III) will be reducing but not
mutarotating
9. Which of the following solutions show lowering of vopour pressure on mixing?

(A) Aniline and cyclohexane (B) Chloroform and acetone
(C) Ethyl alcohol and pentane (D) Dimethyl ether and chloroform
10. HI cannot be prepared by the action of conc. H2SO4 on KI because

(A) HI is stronger acid than H2SO4 (B) H2SO4 is an oxidizing agent
(C) HI is a strong reducing agent (D) H2SO4 is stronger acid than HI
11. Which of the following will produce aromatic compound as a product?

Re dhot Fe tube
(A) CH3  C  CH  

Al2 O3
(B) n  C6H14    
Cr O /600o C
2 3
(C) + CHCl3 t - BuO -

N
H
(D) NH2 CHO

+
NH2 CHO
Comprehension Type
This section contains 2 paragraphs. Based upon the first paragraph 2 multiple choice questions and
based upon the second paragraph 3 multiple choice questions have to be answered. Each of these
questions has four choices A), B), C) and D) out of WHICH ONLY ONE IS CORRECT.
Paragraph For Question No.12 and 13
A white compound (A) on strong heating decomposes to produce two products (B) and (C). (B) on
reaction with white phosphorus produces (D), which is a strong dehydrating agent. (D) on reaction with
perchloric acid converts it to its anhydride.
12. The compound (A) is

(A) NH4NO2 (B) NH4 ClO4 (C)  NH4 2 Cr2 O7 (D) NH4NO3
13. The product/s obtained on hydrolysis of (D) is

(A) Mixture of H3PO3 and H3PO4 (B) Only PH3
(C) Only H3PO4 (D) Mixture of H3PO3 and H3PO2
Paragraph For Question No.14 and 16
‘A’ is a substance that converts into B, C and D by three first order parallel paths simultaneously
according to the following stoichiometry
Path I
B
t1/2 = 86.625 Path II

A 2C
mins
Path III
D
The partial t1/2 of A along path I and path II are 173.25 min and 346.5 min respectively. The energies of
activation of the reaction along path I, path II and path III are 40, 60 and 80 kJ/mol respectively.
14. The percent distribution of C in the product mixture B, C and D at any time is equal to
(A) 20 (B) 60 (C) 80 (D) 40
15. The initial rate of consumption of A and the sum of the initial rate of formation of B, C and D are
respectively, taking [A] = 0.25 M, equal to
(A) 2 103 molL1 min1 and 2.5 103 mol L1 min1
(B) 2 103 mol L1 min1 and 2 103 mol L1 min1
(C) 2.5 10 3 molL1 min1 and 3 103 mol L1 min1
(D) 4 103 molL1 min1 and 2 103 mol L1 min1
16. The overall energy of activation of A along all the three parallel paths is equal to
(A) 52 kJ/mol (B) 60 kJ/mol (C) 55 kJ/mol (D) 80 kJ/mol
SECTION-B
(Matrix-Match Type)
This section contains 2 questions. Each question contains statements given p q r s t
in two columns, which have to be matched. The statements in Column I are
A p q r s t
labelled A, B, C and D, while the statements in Column II are labelled p, q, r,
s and t. Any given statement in Column I can have correct matching with B p q r s t
ONE OR MORE statement(s) in Column II. The appropriate bubbles
corresponding to the answers to these questions have to be darkened as C p q r s t
illustrated in the following example:
D p q r s t
If the correct matches are A – p, s and t; B – q and r; C – p and q; and D – s
and t; then the correct darkening of bubbles will look like the following:
1. Match the following:
Column – I Column - II
(A) XeF4  H2 O     (p) Shows disproportionation reaction
One of the product is a monobasic Lewis
(B) P4  s   OH  aq  H2 O     (q)
acid but not bronsted acid
(C) B 2H6  H2O     (r) One/two of the products is/are gas(es)
Br2  g  k 2 CO3  aq   One of the product has trigonal

(D) (s)
pyramidal structure
One of the gaseous product is used
(t)
as Holme’s signal in sea
2. Match the following:
Column – I Column - II
H3C CH(D)Cl
C (p
(A) C Optically active
H H
Me
(q
(B) Optically inactive
Me
-
O
+
(C) H3C N H (r) Plane of symmetry
C2H5
H H
(D) (s) Number of chiral centre = 1
Cl Cl
(t) Number of stereocentres = 2
SECTION –C
Integer Answer Type
This section contains 6 questions. Each question, when worked out will result in one integer from 0 to 9
(both inclusive).
1. Number of nuclear particles (Projectiles + ejectiles) involved in the conversion of the nuclide
238
U
92
Pu 239 by neutron – capture method is ..............
into 94
2. A crystal is made up of atoms X, Y and Z. Atoms X are in FCC packing. Y occupies all octahedral
voids and Z occupies all tetrahedral voids. If all the atoms along two body diagonals are
removed, the ratio of sum of effective number of atoms of Y and Z to the effective number of
atoms of X is a : 1, what is the value of a?
3. How many aldol products may be formed by the reaction of CH3CH2CHO with CH3COCH2CH3?
4. 5.6 L an unknown gas at NTP requires 12.5 calories to rise its temperature by 10oC at constant
volume. What is the atomicity of the gas?
5. After electrolysis of a NaCl solution with inert electrodes for a certain period of time, 60 ml of the
solution was left which was found to be 1 N in NaOH. During the same time 31.75 g of Cu was
deposited in a Cu voltameter in series with the electrolytic cell. Calculate the percentage
yield of the sodium hydroxide obtained. (Atomic mass of Cu = 63.5)
6. Of the following amines how many can be identified by Hoffmann’s mustard oil reaction?
CH 3 Ph
NH2 N N
H NH 2 CH 3
(i)
(ii) (iii) (iv)
Ph NH 2 CH 2 NH 2 Ph N
CH 3 H
(v) (vi) (vii)
Answer Key
No. CHEMISTRY
1. C
2. B
3. C
4. A
5. B
6. A
7. A
8. A, B
9. B, D
10. B, C
11. A, B, C
12. D
13. C
14. D
15. A
16. C
(A)  p,r,s, (B)p,r,s,t,

1.
(C)  q, r, (D)  p, r, s
(A)p,s, (B)  q,r,t,

2.
(C)  p,s, (D) q,r,t
1. 3
2. 2
3. 6
4. 2
5. 6
6. 4

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FIITJEE Mumbai JEE Advanced Mock Test

(A) 1 (B) 3 (C) 5 (D) 7

3. In the graph between  and Z for the Mosley’s equation, the 

5. Find out correct representation of trans - decaline H

Ph - CH = CH2 O2/Pt H+, 

and PhCH 2CHO

8. Some organic compounds are given below:

9. Which of the following solutions show lowering of vopour pressure on mixing?

10. HI cannot be prepared by the action of conc. H2SO4 on KI because

11. Which of the following will produce aromatic compound as a product?

(C) + CHCl3 t - BuO -

12. The compound (A) is

13. The product/s obtained on hydrolysis of (D) is

Paragraph For Question No.14 and 16

t1/2 = 86.625 Path II

1. Match the following:

Br2  g  k 2 CO3  aq   One of the product has trigonal

2. Match the following:

(A)  p,r,s, (B)p,r,s,t,

(A)p,s, (B)  q,r,t,

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