AIEEE Sample Paper-2

Part1 : CHEMISTRY
Useful Data :
Atomic Mass : H = 1, C = 12, N = 14, O = 16, Na = 23, S = 32, Cl = 35.5, K = 39, Ca=40,
Mn = 55, Fe = 56, Cu = 63.5, Br=80, I = 127.
SECTIONI
Straight Objective Type
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B),
(C) and (D), out of which ONLY ONE is correct.
1. Give the correct order of increasing acidic strength of the following compounds :
(I) OH (II) OH
(III) COOH (IV) CCH

(a) II < I < IV < III (b) IV < II < I < III
(c) I < II < IV < III (d) IV < I < II < III
2. Which of the following compounds does not have a meso isomer ?

(a) 2, 3Dibromobutane (b) 2, 3Butanediol
(c) 2, 4Dibromopentane (d) 2Bromo4chloropentane
3. Which of the following represents the structure of ethyl3oxobutanoate ?

O O
O
O
(a) (b)
O O
O O O
(c) (d)
O O O
4. Which of the following compounds is isomeric with methyl vinyl ether ?

(a) Propanal (b) Propanol
(c) Ethyl methyl ether (d) Ethanol
 Space for rough work
5. Which of the following compounds can exhibit tautomerism ?
(a) C6H5CHO (b) C6H5COC(CH3)3
(c) C6H5COCH2CHO (d) C6H5COC6H5
6. Which of the following conformations of nbutane has a cetnre of symmetry ?

CH3 CH3
CH3H H
H
(a) (b) H H
H
H H CH3
CH3
H3C H
H
H H
(c) H CH3 (d) H H
H CH3
7. 2.84 g methyl iodide was completely converted into methyl magnesium iodide and the
product was decomposed by excess of ethanol. The volume of the gaseous hydrocarbon
produced at NTP will be
(a) 22.4 litre (b) 22400 litre
(c) 0.448 litre (d) 0.224 litre
8. Identify the final product in the given sequence of reactions :

CH2Br
alc. 
KOH
  A B
 B H
2 H6
 C
2O2 / OH
CH2OH OH
(a) (b)
CH3
H3C OH
OH
(c) (d)
SECTIONII
Multiple Correct Answer Type
This section contains 4 multiple correct answer(s) type questions. Each question has 4
choices (A), (B), (C) and (D), out of which ONE OR MORE is/are correct.
9. The empirical formula of a compound is CH2. To which of the hydrocarbon series does it
belong ?
(a) alkanes (b) alkenes
(c) alkynes (d) cycloalkanes
10. Which of the organic compounds will give white precipitate with AgNO3 ?
(a) C6 H5 NH3 Cl  (b) CH2=CHCl
(c) C6H5Cl (d) 2, 4, 6trinitrochlorobenzene
11. Which of the following statements is/are correct about tautomers ?

(a) They posses different electronic and atomic arrangement.
(b) They posses different electronic but same atomic arrangement.
(c) They have different atomic arrangement but same electronic arrangement.
(d) They exist in equilibrium.
12. Which of the following IUPAC name(s) is/are wrong ?

(a) HCCCH2CH=CH2 pent1en4yne
(b) CH3CH= CHCCH pent4en2yne
(c) C2H3COOCOCH3 acetyl propanoate
(d) CH3C(OH)=CHCOOC2H5 ethyl3hydroxybut2enoate
SECTIONIII
Linked Comprehension Type
This section contains 2 paragraphs. Based upon each paragraph, 3 multiple choice
questions have to be answered. Each question has 4 choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.
Paragraph1
The organic compound (A) having molecular formula C5H10 does not react with bromine
in the dark but react with bromine slowly in sunlight with the formation of acid vapours.
5.60 g of organic compound (A) reacts with 12.78 g of bromine to give 11.91 g of
bromoderivative of (A) isolated as an oily liquid. The fractional distillation of bromo
derivative of (A) gives three, and only three, different fractions with slightly, but
significantly, different boiling points.
Question:
13. The structural formula of organic compound (A) is
CH3CH2 H
(a)
(b) C=C
H CH3
H3C CH3 H3C CH3
(c) (d)
14. The acid vapours obtained are dissolved in water to give a strongly acidic solution that
required V ml of 0.250 M aqueous sodium hydroxide to neutralize it. The volume of
aqueous sodium hydroxide required for neutralization is
(a) 320 ml (b) 450 ml
(c) 250 ml (d) 150 ml
15. The incorrect statement for organic compound (A) is

(a) It is optically active.
(b) It shows geometrical isomerism.
(c) It undergoes free radical substitution reactions.
(d) It undergoes electrophilic substitution reactions.
Paragraph2
Elimination reactions are often used in the preparation of alkenes. One example of an
elimination reaction is ‘dehydrohalogenation’, in which HX (where X is some halogen,
e.g., Cl, Br) is eliminated from a haloalkane. For example, heating chloroethane in
alcoholic potassium hydroxide gives ethene as the major organic product.
H H
H H
HCCCl  C=C + HCl
alcoholicKOH
Heat
H H
H H
Where more than one elimination product is possible, Zaitsev’s rule says that the major
product is the alkene with more alkyl constituents on the carbons involved in the double
bond.
The opposite of elimination is addition, which alkenes undergo readily. Hydrogen halides
readily add across alkene double bonds, forming haloalkanes, for example hydrogen
chloride adds to ethane to give chloroethane.
H H
H H
HCl + C=C 
 HCCCl
H H
H H
The mechanism of this reaction (the sequence of steps that comprise the overall reaction)
is shown below (the arrows represent the movement of a pair of electrons)
:Cl
H H H H
H H
C=C  HCC+  HCCCl
H H
H H H H
In this case the hydrogen may become attached to either carbon atom, but in general the
more alkyl groups attached to the positively charged carbon atom, the more stable the
carbocation intermediate. As one might expect, the major product is formed from the
more stable carbocation intermediate.
Questions:
16. Zaitsev’s product is not obtained as major product in which of the following reaction
(a) CH3CHCH3   (b) CH3CHCH2CH3  
KOH KOH
EtOH ,  EtOH , 
F F
Cl
(c) CH3CHCH2CH3 EtOH

 (d) CH3CHCHCH2-CH3 EtOH

KOH KOH
, ,
Br CH3
17. The Zaitsev’s product as a major product is obtained when elimination pathway is
(a) E1, E2 and E1cB (b) only E1 and E2
(c) only E2 and E1cB (d) only E1 and E1cB
18. The reaction of propene with HOCl proceeds via the addition of
(a) H+ in the first step (b) Cl+ in the first step

(c) OH in the first step (d) Cl+ and OH in a single step
SECTIONIV
Matrix Match Type
This section contains 2 questions. Each question contains statements given in two
columns, which have to be matched. The statements in Column I are labeled A, B, C and
D, while the statements in Column II are labelled p, q, r, s and t. Any given statement in
Column I can have correct matching with ONE OR MORE statement(s) in Column II.
The appropriate bubbles corresponding to the answers to these questions have to be
darkened as illustrated in the following example:
If the correct matches are A – p, s and t; B – q and r; C – p and q; and D – s and t; then the
correct darkening of bubbles will look like the following:
p q r s t
A p q r s t
B p q r s t
C p q r s t
D p q r s t
19.
Column-I Column-II
(A) C6H5CHO + NH2OH  
 (p) Isomer of ethane nitrile
(B) C6H6 + CH3Cl an hy 
. AlCl3 (q) Homologue of benzene
(C) HCONHCH3  P2

O 5 (r) Geometrical isomer

(D) C2H5Cl  Na (s) Isomer of isobutane

dry ether
20.
Column-I Column-II
(A) nbutane, isobutene (p) Ring chain
(B) Ethanol, methoxymethane (q) Position
(C) But1ene, cyclobutane (r) Skeleton
(D) 1propanol, 2propanol (s) Functional
Part2 : MATHEMATICS
SECTIONI
y5
21. The differential equation xy  4  y  0
x
(a) cannot be solved by any method known at this stage
(b) can be solved by the method of variables separable
(c) cannot be solved by the method for homogeneous equations
(d) can be solved as it is of Bernoulli’s type which can be transformed to a linear
differential equation.
dy 9x
22. The differential equation   0 represents a family of
dx 4 y
3
(a) parallel straight lines whose slope is tan 1
2
(b) concentric circles with centre at (3, 2)
5
(c) ellipses with eccentricity
3
5
(d) hyperbola with eccentricity
2
1  1  x 
1 2
23. The value of   1  x 2 dx is
1
cos 
 1  1
(a)  log 2 (b)  log 2
2 2 2 2
(c)   2 log 2 (d)  + 2 log 2
24. The area enclosed by the two curves y  4  x 2 , y  3x and the xaxis and lying to the
right of yaxis is
 3  5 3
(a)  (b) 
3 4 3 4
2 3  5 3
(c)  (d) 
3 6 3 12
dx
25.  1  tan x is
(a) log
1  tan x   C (b)
1 x
log | sin x  cos x |   C
tan x 2 2
(c) log | sin x  cos x | C (d) none of these
 x dx
2
2
26. The value of is
0
(a) 1 (b) 3  2
(c) 3  1 (d) 5  3  2
27. The area bounded by the curves y = x2 and y = 2|x| is

4 2
(a) (b)
3 3
8 1
(c) (d)
3 3
2  x 
28.  x  x 1  2
dx is equal to
x 2x
(a) C (b) C
x  x 1 x  x 1
1
(c) C (d) none of these
x  x 1
SECTIONII
2 cos x  sin x  
29. If  dx  A ln | cos x  sin x  2 | Bx  C . Then the values of A, B,  is
cos x  sin x  2
1 3
(a) (b)
2 2
(c) 3 (d) 1
1
The value of the integral  e x dx is
2
30.
0
(a) less than e (b) greater than e
(c) less than 1 (d) greater than 1
31. For which of the following values of m, the area of the region bounded by the curve
y = x  x2 and the line y = mx equals 9/2 ?
(a) 4 (b) 2
(c) 2 (d) 4
32. If a, b, c are real numbers such that 3a + 5b + 15c = 0, the equation ax4 + bx2 + c = 0 has
(a) at least one root in (1, 0) (b) at least one root in (0, 1)
(c) at least two roots in(1, 1) (d) no root in(1, 1)
SECTIONIII
Paragraph –1
d2y dy
A differential equation of the form 2
 a1  a 2 y  0 is called a linear differential
dx dx
equation, where a1 and a2 are functions of x only. In case a1 and a2 are constants, the
solution of the linear differential equation can be easily written by noting following facts
(i) y = 0 is a solution of the differential equation.
(ii) if y = f(x) is a solution, then y = cf(x) is also a solution.
(iii)if y = f1(x) and y = f2(x) are two solutions, then y = f1(x) + f2(x) will also be a solution.
(iv) If the distinct roots of the quadratic equation m2 + a1m + a2 = 0 are m1 and (real or
imaginary) then the solution of the differential is y  c1e m1x  c 2 e m2x .
In case the roots are complex, (a + ib) the solution can be transformed to the form
eax(c1 cos bx + c2 sin bx) by using Euler’s theorem.
(v) In case the roots of the equation m2 + a1m + a2 = 0 are equal (say m1) the differential
dy
equation can be made linear by putting  m1 y  V .
dx
d2y
 a 2 y  f x  can also be satisfied by some
dy
The linear differential equation 2
 a1
dx dx
other functions which are not of the above type. Such functions are called particular
integrals.
Questions:
d2y
33. Which of the following is not a solution of y0
dx 2
(a) ex (b) aex + bex
(c) e  x (d) ex + c
d2y dy
34. Which of the following is a solution of the equation 2
 6  9y  0
dx dx
(a) c1 + c2x (b) (c1 + c2x)e3x
(c) c1 cos3x + c2 sin3x (d) none of these
d2y
35. A particular integral of the equation 2
 a 2 y  sin ax is
dx
x sin ax x cos ax
(a) C1 cos ax  C2 sin ax (b) 
2a 2 2a 2
sin ax cos ax  x sin ax cos ax
(c)  (d) 
2a 2 2a 2 2a 2 2a 2
Paragraph-2
Any function f(x) is said to periodic with period T>0 such that f(x + T) = f(x) exist where
T is least positive value.
Let T is period of f(x). & nI, then definite integral property states.
nT T
(i)  f (x) dx  n  f (x) dx
0 0
when nI.
nT T
(ii) 
mT
f ( x ) dx  (n  m)  f ( x ) dx , where n, mI.
0
b  nT b
(iii) 
a  nT
f ( x ) dx   f ( x ) , where nI.
a
Using above property given the answer following questions.
Questions.
16
3
36. The value of  | sin x | dx is
0
21 23
(a) (b) 
2 2
8 16
(c) (d)
3 3
199
1  cos 2x
37. The value of 

2
dx is
(a) 200 (b) 400

220 200
(c) (d)
3 3
p q
 
38. The value of  | cos x | dx
0
where qN &
2
 p  is
2
(a) 2q –3 sin p (b) 2q – sin q
(c) 2p + sin q (d) 2q + sin p
SECTIONIV
Matrix Match Type
p q r s t
A p q r s t
B p q r s t
C p q r s t
D p q r s t
39.
Column-I Column-II
(A) Area enclosed between the curve y=log (x + e), (p) 1
1
x = log   and x-axis is
y
(B) Area enclosed by |x| + |y| = 1 is (q) 2
(C) The area bounded by the curves y = |x| –1 and (r) 3
y = –|x| + 1 is
(D) The order of the differential equation whose general (s) 4
solution is given by y = (C1 + C2)sin(x + C3)  C 4 e x C5 is
dx
40. If a, b, c be real numbers and I   , then match the various forms of I with
ax  bx  c
2
values of a, b, c.
Column-I Column-II
(A) b  4ac < 0, (a  0)
2
(p) A
C
xB
(B) b2  4ac > 0, (a  0) (q) A log(x + B) + C
(C) b2  4ac = 0, (a  0) (r) A tan1(Bx + C) + D
(D) a = 0 (s) xB
A log D
x C
Part3 : PHYSICS
SECTIONI
41. A transverse wave is described by the equation y = A sin 2(t  x / ). The maximum
particle velocity is equal to four times the wave velocity if:
(a)   A / 4 (b)   A / 2 (c)   A (d)   2A
42. A spring of force constant k is cut into two pieces such that one piece is double the length
of the other. Then the longer piece will have a force constant of
2 3
(a) k (b) k
3 2
(c) 3 k (d) 6 k
43. A body of mass 1 kg is executing simple harmonic motion. Its displacement x (in cm) at
time t (in second) is given by
 
x  6 sin 100 t  
 4
The maximum kinetic energy of the body is
(a) 6 J (b) 18 J
(c) 24 J (d) 36 J
44. A body connected at the end of a spring executes S.H.M. with a period t 1, while the
corresponding period for another spring is t2. If the period of oscillation with the two
springs in series is T, then
(a) T = t1 + t2 (b) T2 = t 12  t 22
1 1 1 1 1 1
(c)   (d) 2  2  2
T t1 t 2 T t1 t 2
45. The ends of a rod of length l and mass m are attached two identical springs as shown in
Fig.. The rod is free to rotate about its centre O. The rod is depressed slightly at end A and
released. The time period of the resulting oscillation is
m 2m
(a) 2 (b) 2
2k k
2m 3m
(c)  (d) 
3k 2k
k

A 2
O  B
k 2

46. One end of a massless spring of relaxed length
50 cm and spring constant k is fixed on top of a
frictionless inclined plane of inclination k
  30 o as shown in Fig. When a mass m = 1.5
kg is attached at the other end, the spring extends
by 2.5 cm. The mass is displaced slightly and m
released. The time period (in seconds) of the
resulting oscillation will be   30 o
 2
(a) (b)
7 7
 2
(c) (d)
5 5
47. A particle is executing linear simple harmonic motion about the origin x = 0. Which of the
graphs shown in Fig. represents the variation of the potential energy function U(x) versus
x?
U(x) U(x)
x x
(a) (b)
U(x) U(x)
x x
(c) (d)
48. One end of a light spring of force constant k is fixed to a block A of mass M placed on a
horizontal frictionless table; the other end of the spring is fixed to a wall (fig). A smaller
block B of mass m is placed on block A. The system is displaced by a small amount and
released. What is the maximum amplitude of the resulting simple harmonic motion of the
system so that the upper block does not slip friction between the two blocks is  .
m B
M A
Mg mg
(a) A max  (b) A max 
k k
 ( M  m)g
(c) A max  (d) None of these
k
SECTIONII
49. Which of the following expressions represent simple harmonic motion?

(a) x  a sin ( t  ) (b) x  a cos ( t  )
(c) x  a sin  t  b cos  t (d) x  a sin  t cos  t
50. A simple pendulum is oscillating between extreme position P and Q about the mean
position O. Which of the following statements are correct about the motion of the
pendulum?
(a) At point O, the acceleration of the bob is different from zero
(b) The acceleration of the bob is constant throughout the oscillation
(c) The tension in the string is constant throughout the oscillation
(d) The tension is the maximum at O and the minimum at A or B.
51. Two springs A and B have force constants k1 and k2 respectively. The ratio of the work
done on A to that done on B in increasing their lengths by the same amount is  and the
ratio of the work done on A to that done on B when they are stretched with the same force
is  . Then
k k
(a)   1 (b)   2
k2 k1
k k
(c)   1 (d)   2
k2 k1
52. All the springs shown in Fig. (a), (b) and (c) are identical, each having a force constant k.
If Ta, Tb and Tc are the time periods of oscillations of the three system respectively, then
k k k k
m m
(a) k (c)
(b)
Tb 1
(a) Ta  (b) Ta  Tb  2 Tc
2 2
T
(c) Ta  2Tc (d) Ta  2Tb  c
2
SECTIONIII
Paragraph1
One end of a light spring of force constant k is fixed to a block of mass M placed on a
horizontal frictionless surface, the other end of the spring being fixed to a wall. The
springblock system is executing simple harmonic motion of amplitude A and frequency
 . When the block is passing through the equilibrium position, an object of a mass m is
gently placed on the block. As a result, the frequency of the system becomes ' and the
amplitude becomes A’.
53. The ratio ' /  is

1/ 2 1/ 2
 M   m 
(a)   (b)  
Mm Mm
 ( M  m) A ' 
1/ 2
MA
(c) (d)  
mA '  mA 
54. If v and v' are the velocities before and after the object is placed on the block, then the
ration v' /v is
M Mm
(a) (b)  
( M  m)  m 
 M  m  A' Mm A
(c)   (d)  
Mm A  M  m  A'
55. The ration A' /A is

1/ 2
Mm  
1/ 2
Am
(a)   (b)  
 m   A ' ( M  m) 
 A ' ( M  m) 
1/ 2 1/ 2
 M 
(c)   (d)  
Mm  AM 
Paragraph2
y
Q
P R
W
O x
S
T
V
U
The figure represents the instantaneous picture of a transverse harmonic wave traveling
along the negative x  direction. choose the correct alternative (s) related to the movement
of the nine points shown in the figure.
56. The points moving upward is/are

(a) P (b) R
(d) U (d) W
57. The points moving downwards is/are

(a) O (b) Q
(c) S (d) W
58. The stationary points is/are

(a) O (b) Q
(c) S (d) W
SECTIONIV
p q r s t
A p q r s t
B p q r s t
C p q r s t
D p q r s t
59. Match the functions given in column I with the kinds of motion they represent given in
column II. Here k is a positive real constant.
Column-I Column-II
(A) sin (kt) + cos (kt) (p) Non periodic and not simple harmonic
2
(B) cos (kt) + 2 sin (kt) (q) Periodic but not simple harmonic
kt
(C) e (r) Periodic and simple harmonic
(D) tan (kt) (s) Periodic with period  / k
60. In column 1 some spring block arrangement are shown and in column II correspond time
period of oscillations is given. Find the match the following. (All pullies are frictionless
and massless).
ColumnI ColumnII
(A) (p) 3M
k T  2
k
M
(B) (q) 3M
k
T  2
2k
k k
(C) (r) 4M
2
8k
Pulley has mass M
& radius R
k
M
(D) (s) 6M
k 2
k
k k k k

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Part1 : CHEMISTRY

(III) COOH (IV) CCH

2. Which of the following compounds does not have a meso isomer ?

3. Which of the following represents the structure of ethyl3oxobutanoate ?

4. Which of the following compounds is isomeric with methyl vinyl ether ?

6. Which of the following conformations of nbutane has a cetnre of symmetry ?

8. Identify the final product in the given sequence of reactions :

11. Which of the following statements is/are correct about tautomers ?

12. Which of the following IUPAC name(s) is/are wrong ?

15. The incorrect statement for organic compound (A) is

(c) CH3CHCH2CH3 EtOH

(D) C2H5Cl  Na (s) Isomer of isobutane

27. The area bounded by the curves y = x2 and y = 2|x| is

(ii) if y = f(x) is a solution, then y = cf(x) is also a solution.

(a) 200 (b) 400

 Space for rough work

49. Which of the following expressions represent simple harmonic motion?

53. The ratio ' /  is

55. The ration A' /A is

56. The points moving upward is/are

57. The points moving downwards is/are

58. The stationary points is/are

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