PINNAACLE CLASSES

1. Butane-2-ol is CH 3
|
(a) Primary alcohol (b) Secondary alcohol CH 3 −C −OH
|
(c) Tertiary alcohol (d) Aldehyde CH 3 CH 3 CH 2 CH 2 OH
(c) (d)

2. Picric acid is 11. The alcohol which easily reacts with conc. HCl is
(a) Trinitroaniline (b) Trinitrotoluene CH 3 −CHOH −CH 2 −CH 3
(a)
(c) A volatile liquid (d) 2, 4, 6 trinitrophenol
(b) (CH 3 )3 −C−OH
CH 3 −CH 2−CH 2 −CH 2 −OH
3. Primary alcohols can be obtained from the reaction of (c)
the RMgX with (d) (CH 3 )3 −CH −CH 2 OH
(a) CO 2 (b) HCHO
12. In the following series of chemical reactions, identify Z
(c) CH 3 CHO (d) H 2 O Br 2 Y⃗
Conc . H 2 SO 4 X ⃗
C 3 H 7 OH⃗ Excess of Z
Alc . KOH
160−180 o C

CH 3 −CH −CH 2 CH 3 −CH −CH 2

4. LiAlH 4 converts acetic acid into | | | |
NH 2 NH 2 (b) OH OH
(a) Acetaldehyde (b) Methane
(c) Ethyl alcohol (d) Methyl alcohol
(a)
CH 3 −C =CH 2
NaOH Product .
⃗ |

5. CH 2 =CH 2 + B2 H 6 H 2 SO 4 (c) OH (d) CH 3 C≡CH

Product in above reaction is
13. Primary and secondary alcohols on action of reduced
(a) CH 3 CH 2 CHO (b) CH 3 CH 2 OH
copper give
(c) CH 3 CHO (d) None of these (a) Aldehydes and ketones respectively
(b) Ketones and aldehydes respectively
6. Which reagent is useful in converting 1-butanol to 1- (c) Only aldehydes
bromobutane (d) Only ketones
(a) CHBr 3 (b) Br 2
(c) CH 3 Br (d) PBr 3 14. Methyl alcohol on oxidation with acidified K 2 Cr 2 O7
gives
7. Which of the following gives ketone on oxidation (a) CH 3 COCH 3 (b) CH 3 CHO
(a) (CH 3 )3 COH (b) CH 3 CH 2 CH 2 OH (c) HCOOH (d) CH 3 COOH
(c) (CH 3 )2 CHCH 2 OH (d) CH 3 CHOHCH 3
15. Ethyl alcohol on oxidation with K 2 Cr 2 O7 gives
8. Which compound has the highest boiling point (a) Acetic acid (b) Acetaldehyde
(a) Acetone (b) Diethyl ether (c) Formaldehyde (d) Formic acid
(c) Methanol (d) Ethanol
16. Lucas test is used for
9. Dehydration of ethanol gives (a) Alcohols (b) Amines
(a) Acetic acid (b) Ethane (c) Diethyl ether (d) Glacial acetic acid
(c) Ethylene (d) Acetylene
17. In esterification, the reactivity of alcohols is
10. Which of the following compound will give positive (a) 1° > 2° > 3° (b) 3° > 2° > 1°
iodoform test (c) Same in all cases (d) None of these
H
|
CH 3 −C−OH 18. Methanol and ethanol are distinguished by the
|
CH 3 OH CH 3 (a) Action of HCl (b) Iodoform test
(a) (b)

Opp. Om Shakti Temple, Beside Naturals, Ramakrishna Road, Salem : 83009 81676 / 98403 37371
 PINNAACLE CLASSES
(c) Solubility in water (d) Sodium

19. The compound with the highest boiling point is

CH 4 CH 3 OH
(a) (b)
CH 3 Cl CH 3 Br
(c) (d)

20. The alcohol which does not give a stable compound on

dehydration is
(a) Ethyl alcohol (b) Methyl alcohol
(c) n-propyl alcohol (d) n-butyl alcohol

Opp. Om Shakti Temple, Beside Naturals, Ramakrishna Road, Salem : 83009 81676 / 98403 37371