LEVEL-I

CHAPTER: ALD-KET

1. The end product in the following sequence of reaction is ;

HC  CH ⎯⎯ ⎯⎯ ⎯→ A ⎯⎯
1%HgSO 4
⎯⎯→ B ⎯⎯
CH 3 MgX
⎯→
[O ]
14.On reductive ozonolysis yields.
20 % H 2 SO 4
(a) 6-oxoheptanal (b) 6-oxoheptanoic acid
(a) Acetic acid (b) Isopropyl alcohol
(c) 6-hydroxyheptanal (d) 3-hydroxypentanal
(c) Acetone (d) Ethanol
15. An alkene of molecular formula C9 H18 on ozonolysis gives 2,2
2. Compound which gives acetone on ozonolysis:
(a) CH 3 − CH = CH − CH 3 (b) (CH 3 )2 C = C(CH 3 )2 dimethyl propanal & 2-butanon, then the alkene is.
(a) 2, 2, 4-trimethyl –3-hexene (b) 2, 2, 6-trimethyl-3-hexene
(c) C6 H5 CH = CH 2 (d) CH 3CH = CH 2
(c) 2, 3, 4-trimethyl-2-hexene (d) 2, 2, 4-trimethyl-2-hexene
3. Which one of the following compounds is prepared in the (e) 2, 2dimethyl-2-heptene
laboratory from benzene by a substitution reaction;
(a) Glyoxal (b) Cyclohexane 16.
(c) Acetophenone (d) Hexabromo cyclohexane
CH 3 COCl ⎯⎯⎯→ CH 3 CHO + HCl ;
2H
Pd / BaSO 4
4.
The above reaction is called
(a) Reimer-Tiemann reaction (b) Cannizzaro reaction
(c) Rosenmund reaction (d) Reformatsky reaction Relationship between products (Q) and (S) is ?
(a) Positional isomer (b) Chain isomer
5. The oxidation of toluene to benzaldehyde by chromyl chloride
is called; (c) Stereoisomer (d) Functional isomer
(a) Cannizzaro reaction (b) Wurtz reaction 17. Correct order of reactivity of following compound towards
(c) Etard reaction (d) Reimer-Tiemann reaction Grignard reagent :
6. From which of the following tertiary butyl alcohol is obtained
by the action of methyl magnesium iodide;
(a) HCHO (b) CH 3 CHO
(c) CH 3 COCH 3 (d) CO 2
(a) I > II > III (b) II > I > III
CH 3 − CH 2 − C  CH ⎯⎯→ R
(c) II > III > I (d) I > III > II
H 2O
7. Butanone, R is. O
++ ||
(a) Hg (b) KMnO 4 (c) KClO 3 (d) K2Cr2O7
18. Ph − C− OH ⎯⎯⎯2 →(A) ⎯⎯→
SOCl H
2
(B)
8. Dry heating of calcium acetate gives. Pd− BaSO 4
(a) Acetaldehyde (b) Ethane Product (B) is .
(c) Acetic acid (d) Acetone O
||
9. Acetophenone is prepared by the reaction of which of the (a) Ph − C− H (b) Ph − CH 2 − OH
following in the presence of AlCl 3 catalyst;
(a) Phenol and acetic acid (c) Ph − CH 2 − Cl (d) Ph − CH = CH 2

19. (A) ⎯⎯⎯4 →(B) ⎯⎯⎯4 →

(b) Benzene and acetone HgSO LiAlH
(C)
dil. H 2SO 4
(c) Benzene and acetyl chloride racemic mixture

(d) Phenol and acetone  reactant (A) is ;

10. On heating calcium acetate and calcium formate, the product (a) CH 3 − C  CH (b) HC  CH
formed is?
(a) CH 3COCH 3 (b) CH 3CHO (c) CH 3 − C  C − CH 3 (d) Ph − CH = CH 2

(c) HCHO + CaCO 3 (d) CH 3CHO + CaCO 3

11. Which of the following compound gives a ketone with
Grignard reagent;
(a) Formaldehyde (b) Ethyl alcohol
(c) Methyl cyanide (d) Methyl iodided
12. Methyl ethyl ketone is prepared by the oxidation of;
(a) 2-propanol (b) 1-butanol
(c) 2-butanol (d) t-butyl alcohol
13. Benzaldehyde can be prepared by oxidation of toluene by;
(a) Acidic KMnO 4 (b) K2Cr2O7
(c) CrO2 Cl 2 (d) All of these