PINNAACLE CLASSES

1. For a certain redox reaction, Eº is positive this means that

(a) ΔGº is positive, K is greater than 1
(b) ΔGº is positive, K is less than 1
(c) ΔGº is negative, K is greater than 1
(d) ΔGº is negative, K is less than 1

2. The quantity of charge required to obtain one mole of aluminum from

Al 2 O3 is _______.
(a) 1 F (b) 6 F (c) 3 F (d) 2 F

3. Given below are the standard electrode potentials of few half cells the correct order of these metals in increasing reducing power
will be
K + | K=−2 . 93 V , Ag+ | Ag=0 . 80 V ,
Mg 2+ |Mg=−2 .37 V , Cr 3 +|Cr=−0 . 74 V
(a) K <Mg <Cr< Ag (b) Ag<Cr< Mg<K
Mg <K <Cr< Ag (d) Cr <Ag< Mg<K
(c)

4. Mark the correct relationship from the following.

(a) Equilibrium constant is related to emf as
nFE
log K =
2. 303 RT
2+ 2+ ( a
( a1 ) )

(b) EMF of a cell Zn|Zn ||Cu 2

|Cu is

0. 591 [a ]
E=Eº− log 2
n [ a1 ]
(c) Nernst equation is
0. 0591 [Pr oducts ]
E cell =EºCell − log
n [Re ac tan ts ]
n+
(d) For the electrode M . M at 273 k
0 . 591
E=Eº+ log[ M n+ ]
n
+
) the standard cell potential is 0.36 V
( aq ) 2+
5. For the cell reaction: 2 Cu → Cu( s ) +Cu(aq the equilibrium constant for the reaction
is
6 12
(a) 1 .2×10 (b) 7 . 4×10
6 8
(c) 2 . 4×10 (d) 5 .5×10

6. What would be the equivalent conductivity of a cell in which 0.5 N salt solution offers a resistance offers 40 ohm whose
2
electrodes are 2 cm apart and 5 cm in area?
−1 −1
(a) 10ohm cmh eq 2
ohm−1 cm2 eq−1
(b) 20
−1 2 −1 −1 2
(c)30 ohm cm eq (d) 25 ohm cm eq

7. The equivalent conductivity of N/10 solution of acetic acid at 25 ºC is 14 .3 ohm−1 cm 2 equiv−1 . What will be the degree of
dissociation of acetic acid?
( Δ ∞CH 3 COOH =390 .71 ohm−1 cm 2 equiv−1 )
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(a)
3 . 66 % (b) 3 . 9 % (c) 2 .12 % (d) 0 . 008 %

8. Limiting molar conductivity of NaBr is

(a)
Δº m NaBr=Δº m NaCl+ Δº m KBr
0
(b) Δº m NaBr=Δº m NaCl+ Δº m KBr−Δ m KCl
0
(c) Δº m NaBr=Δº m NaOH + Δº m NaBr−Δ m NaCl
Δº m NaBr=Δº m NaCl−Δº m KBr
(d)

9. A current of 1 . 40 ampere is passed through 500 mL of 0 . 180 M solution of zinc sulphate for 200 seconds. What will be the
2+
molarity of Zn ions after deposition of zinc?
0.154 M (b) 0.177 M
(a)
(d) 0.180 M
(c) 2M

10. During electrolysis of a solution of

AgNO 3 , 9650 coulombs of charge is passed through the solution. What will be the mass of
silver deposited on the cathode?
(a) 108 g (b) 10.8 g (c) 1.08 g (d) 216 g

11. An electric current is passed through silver nitrate solution using silver electrodes. 15 .28 g of silver was found to be deposited on
cathode. What will be the weight of copper deposited on cathode if same amount of electricity is passed through copper sulphate
solution using copper electrodes?
(a) 4 .49 g (b) 6.4 g (c) 12.8 g (d) 3.2 g

12. Which of the following reactions does not take place during rusting?

(a)
H 2 CO 3 2 H + +CO 2−
3

(b)
4 Fe2 + +O2 (dry )→ Fe 2 O3

(c)
4 Fe2 + +O2 +4 H 2 O→2 Fe 2 O3 +8 H +
Fe 2 O3 +xH 2 O →Fe 2 O3 . xH 2 O
(d)

13. Which cell will measure standard electrode potential of copper electrode?

(a)
Pt ( s)|H 2 (g , 0. 1 bar)|H + (aq , 1 M )|| Cu2 + ( aq , 1 M )|Cu (b)
Pt ( s)|H 2 (g , 1 bar )|H + (aq , 1 M )|| Cu 2+ (aq , 2 M )|Cu (c)
Pt ( s)|H 2 (g , 1 bar )|H + (aq , 1 M )|| Cu 2+ (aq , 1 M )|Cu
(d)
Pt ( s)|H 2 (g ,1 bar )|H + (aq ,0. 1 M )|| Cu2+ (aq , 1 M )|Cu

14. Which of the following statement is correct?

(a)
E cell and Δ r G of cell reaction both are extensive properties.
E ΔG
(b) cell and r of cell reaction both are intensive properties.
E ΔG
(c) cell is an intensive property while r of cell reaction is an extensive property.
E ΔG
(d) cell is an extensive property while r of cell reaction is an intensive property.

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15. Which of the following statements is not correct about an inert electrode in a cell?
(a) It does not participate in the cell reaction.
(b) It provides surface either for oxidation or for reduction reaction.
(c) It provides surface for conduction of electrons
(d) It provides surface for redox reaction.

16. Which of the statements about solution of electrolytes is not correct?

(a) Conductivity of solution depends upon size of ions.
(b) Conductivity depends upon viscosity of solution.
(c) Conductivity does not depend upon salvation of ions present in solution.
(d) Conductivity of solution increases with temperature.

17. Use the data given in Q. 8 and find out the most stable ion in its reduced form.
− 3+
(c) Cr
2+
(a) Cl (b) Cr (d) Mn

0
Δ m( NH ) is
18. 4 OH equal to
Δº m( NH OH ) +Δº m( NH 4 Cl )− Δº m( HCl )
(a) 4

Δº m( NH Cl ) +Δº m( NaOH )− Δº m (NaCl )

(b) 4

Δº m( NH Cl ) +Δº m( NaCl) −Δº m( NaOH )

(c) 4

Δº m( NaOH) +Δº m( NaCl )−Δº m( NH Cl)

4
(d)

19. A cell is set up as shown in the figure. It is observed that EMF of the cell comes out to be 2.36 V . Which of the given statements
is not correct about the cell?

(a) Reduction takes place at magnesium electrode and oxidation at SHE.

(b) Oxidation takes place at magnesium electrode and reduction at SHE.
2+
(c) Standard electrode potential for Mg |Mg will be −2.36 V .
(d) Electrons flow from magnesium electrode to hydrogen electrode.

20. Given below are few reactions with some expressions. Mark the expression which is not correctly matched.
(a) For concentration cell,
0 . 0591 C
Ag| Ag+ (C 1 )||Ag + (C 2 )| Ag ; Ecell =− log 1
1 C2 (b) For the cell2 Ag+ + H 2 (1 atm)→2 Ag+2 H + (1 M );
0. 0591 [ Ag+ ]2
E cell =EºCell − log
2 [ H + ]2
(c) For an electrochemical reaction at equilibrium
aA +bB cC + dD ;
0 .0591 [C ]c [ D ]d
Eº cell = log
n [ A ]a [ B ]b
M n+ + ne− →M ( s)
(d) For the cell ( aq )

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0. 0591 1
E cell =Eº− log n+
n [M ]

21. Molar conductivity of

NH 4 OH can be calculated by the equation
Δº NH OH =Δº Ba(OH ) + Δº NH Cl −Δº BaCl
(a) 4 2 4 2

Δº NH OH =Δº BaCl +Δº NH Cl −Δº Ba (OH )

(b) 4 2 4 2

Δº Ba (OH ) +2 Δº NH 4 Cl −Δº BaCl2

Δº NH OH =
2

(c) 4 2
Δº NH 4 Cl + Δº Ba(OH )
Δº NH OH =
2

(d) 4 2

22. The half cell reactions with their appropriate standard reduction potentials are

(i) Pb 2+ +2e− → Pb ; ( Eº=−0. 13 V )

+ −
(ii) Ag +e → Ag ; ( Eº =+ 0. 80 V )
Based on the above data, which of the following reactions will take place?

(a) Pb 2+ +2 Ag→2 Ag+ +Pb

+ 2+
(b) 2 Ag+Pb→2 Ag +Pb
+ 2+
(c) 2 Ag +Pb→ Pb +2 Ag
2+ +
(d) Pb +2 Ag →Pb+ Ag

23. Match the column I with column II and mark the appropriate choice.
Column I Column II
(A) Electrochemical (i) Potential difference ×
equivalent Quantity of charge
(B) Faraday (ii) Mass of substance
deposited by one
coulomb of charge
(C) Ampere (iii) Charge carried by
one mole of electrons
(D) Electrical energy (iv) One coulomb of
electric charge passed
through one second
(a) (A) → (i), (B) → (ii), (C) → (iii), (D) → (iv)
(b) (A) → (ii), (B) → (iii), (C) → (iv), (D) → (i)
(c) (A) → (iii), (B) → (iv), (C) → (i), (D) → (ii)
(d) (A) → (iv), (B) → (i), (C) → (ii), (D) → (iii)

24. Choose the option with correct words to fill in the blanks
According to preferential discharge theory, out of number of ions the one which requires ________ energy will be liberated _____
at a given electrode.
(a) Least, first (b) Least last
(c) Highest, first (d) Highest, last

0 0
25. The limiting molar conductivities Λ for NaCl, KBr and KCl are 126, 152 and 150 S cm 2 mol–1 respectively. The value of Λ
for NaBr is
(a) 128 S cm2mol–1 (b) 176 S cm2mol–1
(c) 278 S cm2mol–1 (d) 302 S cm2mol–1

26. The highest electrical conductivity among the following aqueous solutions is of :
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(a) 0.1 M acetic acid (b) 0.1 M chloroacetic acid
(c) 0.1 M fluoroacetic acid (d) 0.1 M difluoroacetic acid

27. The molar conductivities and at infinite dilution in water at 25 0C are 91.0 and 426.2 Scm2/mol respectively. To calculate , the
additional value required is :
Λ 0H 2 O Λ 0KCl Λ 0NaOH Λ 0NaCl
(b) (c) (d)
(a)

28. One g equivalent of Na metal is formed from electrolysis of fused NaCl. No. of mole of Al from the fused Na 3AlF6 with the same
current passed is
(a) 1 (b) 3 (c) 1/3 (d) 2

29. In H2 O2 fuel cell the reaction occuring at cathode is

2 H 2 O + O 2 + 4 e− ⃗ 4 OH−
(a)
2 H2 + O2 ⃗ 2 H2 O ( l )
(b)
H + + OH −
⃗ H2O
(c)
H + + e− ⃗ H 2 .
(d)

30. The conductivity of a solution of AgCl at 298 K is found to be 1 .382 × 10 -6 Ω -1 cm-1 . The ionic conductance of Ag + and Cl– at
-1
infinite dilution are 61 . 9Ω
-1
cm2 mol-1 and 76 . 3 Ω cm2 mol-1 , respecitvley. The solubility of AgCl is
(a) 1.4 × 10–5mol L–1 (b) 1 × 10–2mol L–1
(c) 1 × 10–5mol L–1 (d) 1.9 × 10–5mol L–1

31. 2+ and 0.015 M Fe3+ solution at 250C

157. The reduction potential of a half-cell consisting of a Pt electrode immersed in 1.5 M Fe

is .( Fe
=0 . 770 V )
0
E 3+
/ Fe 2+
(a) 0.652 V (b) 0.88 V (c) 0.710 V (d) 0.850 V

32. Conductance measurements can be used to detect the end point of acid-base titrations. Which of the following plots correctly
represent the end point of the titration of strong acid and a strong base
Conductance
Conductance

end point
end point

(a) Volum e of base added (b) Volum e of base added

Conductance
Conductance

end point

end point

(c) Volum e of base added (d) Volum e of base added

33. The equivalent conductivity of 0.1 M weak acid is 100 times lesser than that at infinite dilution. The degree
of dissociation of weak electrolyte at 0.1 Mis-

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(a) 100 (b) 10

(c) 0.01 (d) 0.001

34. For an electrochemical cell, Sn (s)|Sn 2+ (aq, 1 M) || Pb2+ (aq, 1 M)| Pb (s) , the ratio when this cell
attains equilibrium is

(a) 4.3 (b) 1

(c)-2.15 (d)2.14

35. Reduction potentials of four elements P, Q, R, S is -2.90 V, 0.34 V, 1.2 V and -0.76 V. The decreasing order
of reducing power is
(a)P>Q>R>S (b)S>R>Q>P
(c)P>S>Q>R (d)Q>S>R>P

36. The standard electrode potentials, E° of Fe3+/Fe2+ and Fe2+/Fe at 300 K are +0.77 V and -0.44 V,
respectively. The E° of Fe3+/Fe at the same temperature is
(a) 1.21V (b) 0.33V
(c) -0.036 V (d) 0.036

37. Consider the following reduction processes

Zn2+ + 2e- Zn (s); E° = -0.76 V
2+
Ca + 2e Ca (s); E° = -2. 87 V
Mg2+ + 2e- Mg (s); E° = -2.36 V
2+ -
Ni + 2e Ni (s); E° = -0.25 V
The reduction power of the metals increases in the order
(a) Ca < Zn < Mg < Ni (b) Ni < Zn < Mg < Ca
(c) Zn > Mg < Ni < Ca (d) Ca < Mg < Zn < Ni

38. The emf of the cell Zn|Zn2+ (0.01M) ||Fe2+ (0.001M) | Fe at 298 K is 0.2905 volt. Then the value of
equilibrium constant for the cell reaction is

(a)
e0.32/0.0295 (b) 100.32/0.0295
0.26/0.0295
(c) 10 (d) 100.32/0.0591
39. Consider the following cell reaction
2Fe (s) + O2 (g) + 4H+ (aq)  2Fe2+ (aq) + 2H2O (l)
E° = 1.67V
At [Fe2+] = 10-3M, P (O2) = 0.1 atm and pH = 3 , the cell potential at 25°C is
(a) 1.77V (b) 1.57V
(c) 1.87V (d) 1.47V

40. Which substance is obtained in the solution on electrolysis of aq. CuSO 4 solution using graphite
electrodes?
(a)Cu(OH)2 (b)Na2SO4
(c)H2SO4 (d)H2O

41. The passage of electricity in the Daniel cell when Zn and Cu electrodes are connected is:
(a) From to in the cell
(b) From to outside the cell
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(c) From to outside the cell

(d) In any direction of cell

42. is used in salt bridge because

(a) it forms a good jelly with agar‐agar
(b) it is a strong electrolyte
(c) it is a good conductor of electricity

(d) the transference number of and ions are almost equal

43. The number of electrons delivered at the cathode during the electrolysis by a current of 1 A in 60 seconds is charge one

electron

(a)

(b)

(c)

(d)

44. The specific conductance in of four electrolytes P, Q, R and S are given below:

The one that offers highest resistance to the passage of current is

(a) P
(b) S
(c) R
(d) Q

45. If the for a given reaction has negative value, which of the following gives the correct relationship for the values of

and ?

(a)

(b)

(c)

(d)

46. For a given half cell: on increasing , the electrode potential

(a) increase
(b) decrease
(c) No change
(d) first decrease then increase

47. Assertion: Mercury cell does not give steady potential.

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Reason: In the cell reaction, ions are not involved in solution.
(a) Both A and R are true but R is correct explanation of A.
(b) Both A and R are true and R is not correct explanation of A.
(c) A is true bur R is false.
(d) A is false but R is true.

48. The standard oxidation potentials for the half cell reactions are

The emf of the cell reaction:

is
(a)
(b)
(c)
(d)

49. Matrix match.

Column 1 Column 2

(A) (p)

(B) (q)

(C) K (r)

(D) (s) V

(a)

(b)

(c)

(d)

50. How much electric charge is required to oxidize 1 mole of to ?

(a)
(b)
(c)
(d)

51. At 298 K, a 1 litre solution containing 10 mmol of Cr2O72- and 100 mmol of Cr3+ shows a pH of 3.0.

Given : Cr2O72- Cr3+; E° = i.330 V and 2.303 RT

The potential for the half cell reaction is x x 10-3 V. The value of x is

52. Consider the cell

Pt(s)|H2(s)(1atm)|H(aq,[H+] = l)||Fe3+(aq),Fe2+(aq)|Pt(s)

Given : = 0.771V and = 0V. T = 298K

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If the potential of the cell is 0.712 V the ratio of concentration of Fe 2+ to Fe2+ is________(Nearest
integer)

53. Pt(s)H2(g)(1bar)|H+(aq)(1M)||M3+(aq),M+(aq)|Pt(s)

The Ecell for the given ceil is 0.1115 V at 298 K when

The value of a is________
Given : =0.2 V

54. The equilibrium constant for the reaction

Zn(s) + Sn2+(aq) Zn2+(aq) + Sn(s) is 1 x 10 20 at 298 K. The magnitude of standard electrode
potential of Sn/Sn2+ if = -0.76 V is _______x 10-2 V. (Nearest integer)

Given: = 0.059V

55. Consider the cell

Pt(s)H2(g,1 atm)H+(aq, l M)|
Fe3+(aq),Fe2+(aq)|Pt(s)
When the potential of the cell is 0.712 V at 298 K, the ratio [Fe2+]/[Fe3+] is_________.
(Nearest integer)
Given: Fe3+ + e- = Fe2+, E°Fe3+,Fe2+ |Pt = 0.771

56. The electrode potential of the following half cell at 298 K

X|X2+ (0.001 M) || Y2+ (0.01 M) | Y is_____x10-2V (Nearest integer).
Given : =-2.36V
=+036V

57. The resistivity of a 0.8 M solution of an electrolyte is 5x10 -3 cm. Its molar conductivity is _______x104 -1

cm2 mol-1. (Nearest integer)

58. At what pH, given half cell (0.1 M) | Mn2+ (0.001 M) will have electrode potential of 1.282 V?
__________(Nearest Integer)

Given

59. 1x10-5 M AgNO3 is added to 1 L of saturated solution of AgBr. The conductivity of this solution at 298 K
is______x 10-8 S m-1.
[Given : Ksp(AgBr) = 4.9x 10-13 at 298K

]
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60. Which of the following shows the Lewis dot formula for
CO 2 ?
: Ö : C̈ :: { Ö :¿
: Ö::C:: { Ö:¿ (b) . .
(a)
: Ö ::C : Ö : : Ö :C : Ö :
. . (d) . . . .
(c)

61. How many orbitals are singly occupied in

O 2 molecule?
(a) 2 (b) 1 (c) 3 (d) 4

62. Which of the following molecules is paramagnetic in nature?

H2 (b)
Li 2 (c)
B2 (d)
N2
(a)

63. Which of the following angle corresponds to sp 2 hybridisation?

0 0 0 0
(a) 90 (b) 120 (c) 180 (d) 109

64. During a coordinate bond formation,

(a) One electron from an atom is transferred to other
(b) One electron each is lost from both the atoms
(c) A pair of electrons is contributed by one atom and shared by both the atoms
(d) A pair of electrons is transferred to the other atoms.

65. The correct sequence of bond length in single bond, double bond and triple bond of C is.
(a) (C − C )=(C = C )= (C≡C )
(b) C≡C< C=C<C−C
(c) (C−C< C=C<C≡C )
(d) C=C<C≡C< C−C

66. What is common between the following molecules:

−
SO3 , CO 2−
3 , NO 3 ?
(a) All have linear shape.
(b) All have trigonal planar shape.
(c) All have tetrahedral shape.
(d) All have trigonal pyramidal shape.

67. In a bonded molecule, the order of repulsion between the bonded and non-bonded electrons is
(a) Lone pair – lone pair > bond pair – bond pair > line pair – bone pair
(b) Bond pair – bond pair > lone pair – lone pair > lone pair – bond pair
(c) Lone pair – lone pair > lone pair – bond pair > bond pair – bond pair
(d) Bond pair – bond pair > lone pair – bond pair > lone pair – lone pair.

68. The
BCl3 is a planar molecule whereas NCl
3 is pyramidal, because.
(a) B-Cl bond is more polar than N-Cl bond
(b) N-Cl bond is more covalent than B-Cl bond
(c) Nitrogen atom is smaller than boron atoms
(d)
BCl 3 has no lone pair but NCl 3 has a lone pair of electrons.

69. Isostructural species are those which have the same shape and hybridisation. Among the given species, identify the isostructural
pairs.

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(a)
[ NF 3 and BF 3 ] (b)
[ BF−4 and NH +4 ]
[ BCl 3 and BrCl 3 ] (d)
[ NH 3 and NO−3 ]
(c)

70. The electronic configuration of four atoms are given in brackets:

L (1s
2
s 2 2s 2 2 p 5 )
2s 2 2 p 1 ) M (1
2 2 6 1 2 2 2
Q (1s 2 p 2 p 3s ); R (1s 2s 2 p )
The element that would most readily form a diatomic molecule is.
(a) Q (b) M (c) R (d) L

2 4 SF6 ?
71. The ground state electronic configuration of S is 3 s 3 p . How does if form the compound
(a) Due to octahedral shape of S atoms
(b) Due to presence of vacant 3d-orbitals which provide 6 unpaired electrons in excited state
3
(c) Due to sp hybridisation of S atom which provides 6 electrons to 6 F atoms
(d) Due to presence of 3 sigma and 3 pi bonds between S and F

2
72. The electronic configuration of carbon is 1s 2s 2 2 p2 . There are 12 electrons in C 2 . The correct electronic. Configuration of C 2
molecule is

(a)
(σ 1 s 2 )(σ∗1 s2 )(σ 2 s 2 )(σ∗2 s 2 )( σ 2 p2z )( π 2 p2x )

(b)
(σ 1s 2 )(σ∗1s2 )(σ 2s 2 )(σ∗2s 2 )( π 2 p 2x =π2 p2y )
(c)
(σ 1s 2 )(σ∗1s2 )(σ 2s 2 )(σ∗2s 2 )( σ 2 p2z )( π2 p1x=π 2 p 1 y )
(σ 1s 2 )(σ∗1s2 )(σ 2s 2 )(σ∗2s 2 )( π 2 p 2x =π2 p1y )
(d)

73. Though covalent in nature, methanoal is soluble in water, why?

(a) Methanol is transparent like water.
(b) Due to hydrogen bonding between methanol and water molecules.
(c) Due to van der ‘waals’ forces between methanol and water.
(d) Due to covalent attraction forces.

H O
74. Boiling point of 2 is higher than that of
H 2 S , because the former
(a) Is capable of forming H-bonds
(b) Has higher molecular mass
(c) Has relatively strong covalent bonds
+
(d) Is capable of forming co-ordinate bonds with H ions

75. Example of super octet molecule is :

(a) SF6 (b) PCl5

(c) IF7 (d) All of these

76. The covalency of nitrogen in HNO3 is :

(a) 0 (b) 3
(c) 4 (d) 5

77. The molecule/ion which has trigonal pyramidal shape is :

(a) PCl3 (b) SO3

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(c) CO32 – (d) NO3–

78. Which is having highest bond angle :

(a) PCl3 (b) PBr3

(c) PF3 (d) PI3

79. Which of the following species is paramagnetic ?

(a) NO– (b) O22–

(c) CN– (d) CO

80. Which statement(s) is incorrect ?

(a) Polarising power refers to cation.

(b) Polarisability refers to anion.
(c) Small cation is more efficient to polarise anion.
(d) Molecules in which cation having pseudo inert gas configuration are more Ionic.

81. Which of the following molecule exhibits hydrogen-bonding ?

(a) CH4 (b) H2Se

(c) N2H4 (d) H2S

82. Select the correct statement for the sulphuric acid.

(I) It has high boiling point and viscosity.

(II) There are two types of bond lengths in its bivalent anion.
(III) p-d bonding between sulphur and oxygen is observed.
(IV) Sulphur has the same hybridisation that is of boron in diborane.
(a) II and III only (b) II, III and IV only
(c) I, III and IV only (d) III and IV only

83. Among the following, van der Waals forces are strongest in :

(a) HBr (b) LiBr

(c) LiCl (d) AgBr

84. The correct statement for the molecule, CsI3, is :

(a) it is a covalent molecule.

(b) it contains Cs+ and
(c) it contains Cs3+ and I¯ ions.
(d) it contains Cs+, I¯ and lattice I2 molecule.

85. The intermolecular interaction that is dependent on the inverse cube of distance between the molecules is:

(a) ion-ion interaction (b) ion-dipole interaction

(c) London force (d) dipole-dipole attraction

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86. Which of the following does not contain coordinate bond ?

(a) N2O4 (b) NH4+

(c)
CO32– (d) H3O+

87. The species which is diamagnetic is :

(a) NO (b) NO2

ClO2 (d) N2O4
(c)

88. What is the formal charge on N in ?

(a) + 1 (b) – 1
(c) 0 (d) + 2

89. In which of the following compounds B–F bond length is shortest ?

(a) (b) BF3  NH3

(c) BF3 (d) BF3  N(CH3)3

90. Which of the following statement is incorrect ?

(a) During N2+ formation, one electron is removed from the bonding molecular orbital of N 2.
(b) During O2+ formation, one electron is removed from the antibonding molecular orbital of O 2.
(c) During O2– formation, one electron is added to the bonding molecular orbitals of O 2.
(d) During CN– formation, one electron is added to the bonding molecular orbitals of CN.

91. Which of the following molecules is trigonal bipyramidal?

(a) BF3 (b) CH4

(c) PCl5 (d) SF6

92. NH3 has a much higher boiling point than PH3 because :

(a) NH3 forms hydrogen bond.

(b) NH3 has a larger molecular weight.
(c) NH3 undergoes umbrella inversion.
(d) NH3 contains ionic bonds where are PH3 contains covalent bond.

93. Some of the properties of the two species, NO–3 and H3O+ are described below. Which one of them is correct?
(a) Dissimilar in hybridization for the central atom with different structures
(b) Isostructural with same hybridization for the central atom
(c) Isostructural with different hybridization for the central atom
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(d) Similar in hybridiation for the central atom with different structures

94. Which of the following is electron-deficient ?

(a) (SiH3)2 (b) (BH3)2

(c) PH3 (d) (CH3)2

95. N2 and O2 are converted into monoanions and respectively. Which of the following statements is wrong ?

(a) In , N–N bond weakens

(b) ln , O–O bond order increases

(c) ln , O–O bond order decreases

(d) becomes paramagnetic

96. Consider the statements :

is 0.02Å greater than in N2

I. Bond length in
II. Bond length in NO+ is 0.09Å less than in NO.
has shorter bond length than O2
III.
Which of the following statements are true ?
(a) I and II (b) II and III
(c) I, II and III (d) I and III
97. Which of the following cantain at least one lone pair in all of its halide

(a) Xe (b) Se
(c) Cl (d) N

98. Which contain at least one e– in 2p bonding MO

(a) O2 (b) B2
(c) C2 (d) Li2

99. Which pair of diatomic species have same bond order ?

(a) , C2 (b) ,

(c) , (d) , C2

100.Bond angle of 109º 28' is found in :

(a) NH3 (b) H2O

(c) CH3 +
(d) NH4+

101.Which one of the following has the regular tetrahedral structure ?

(a) XeF4 (b) SF4

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(c)
BF4– (d) [Ni(CN)4]2–

102.The molecular shapes of SF4, CF4 and XeF4 are :

(a) the same with 2, 0 and 1 lone pairs of electrons on the central atom, respectively.
(b) the same with 1, 1 and 1 lone pair of electrons on the central atom, respectively.
(c) different with 0, 1 and 2 lone pairs of electrons on the central atom, respectively.
(d) different with 1, 0 and 2 lone pairs of electrons on the central atom, respectively.

103.The number and type of bonds between two carbon atoms in calcium carbide are :

(a) one sigma, one pi (b) one sigma, two pi

(c) two sigma, one pi (d) two sigma, two pi

104.Which of the following hydrogen bonds is the strongest ?

(a) O – H ... O (b) O – H ... F

(c) F – H ... H (d) F – H ... F

105. The sum of p -d bonds in the gases obtained by strong heating of ferrous sulphate is :
(a) 1 (b) 2
(c)3 (d)4

106. The molecule which contains maximum number of lone pairs is

(a) IF7 (b) XeF6
(c) XeF4 (d) XeF2

107. The dipole moment of AX3, BX3 and CX3 are 1.5 D, 0.5 D and 0 D respectively. The possible shapes of
molecules may be (consider C has no Lone pair) (A, B and C are are more electronegative than X)
(a) Pyramidal, T-shape, Trigonal planar respectively.
(b) T-shape, Pyramidal, Square planar respectively.
(c) T-shape, Pyramidal, Trigonal planar respectively.
(d) Pyramidal, T-shape, Square planar respectively.

108. Which of the following molecules have zero dipole moment?

(I) gauche conformation of 1, 2-dibromoethane.
(II) anti conformation of 1, 2-dibromoethane.
(III) trans-1, 4-dibromocyclohexane
(IV) cis-1, 4-dibromocylohexane
(V) tetrabromomethane.
(VI) 1, 1-dibromocyclohexane
(a) I and II (b) II, III and V
(c) II and V (d) I, IV and VI

109. The experimental value of the dipole moment of HC1 is 1.03 D. The length of the H - Cl bond is 1.275 .
The percentage of ionic character in HC1 is:
[Given: 1D = 10-18esu cm]
(a) 43 (b)21
(c)17 (d)7

110. Number of hybrid carbon atoms in aspartame is :

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111. The total number of lone pairs of electrons on oxygen atoms of ozone is __________

112. The number of given orbitals which have electron density along the axis is_______

Px,Py,Pz,dxy, dyz, dxz,

113. Amongst the following, the number of species having the linear shape is_____.

and

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