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Aakash OBYJU'S
Ph.01147623458
Corp. Omce Aakash Tower, 8, Pusa Roed, New Delh-110005,

Poll
CHEMISTRY (C04)
Syllabus: Electrochemkstry
Choose the corTect answer 6 In the eloctrochemlcal cell:

1. Which of the following is the oored staterment? Ag|Ag(C)| Ag(Cz)| Ag:


(1) Anode is negative termlnal, both in galvankc reacion s spontaneous i
and electrolytic cel
(2) Cathode is negative teminal, both in galvanic
(1) C= Ca0.2 M
and elocrolyic cel (2) Ca0.1MCae 0.5 M
(3) Cathode is negatve lerminal in elecolyic te! (3) C MaE 0.05 M
and anode is negative terminal lo galyanic celh
(4) Cathode and anode respective are
(4) O oayc0.1 M
and positive teminal in both eecrolyic and 7. Wiat il betie AG for the galvanic cel:
galvanic cell
2 At what temperature, the cell potential ofstandard
2499Co(aq) 2AP(aq) +3Cd(s)
hydrogen electrode is taken to be zero? BSs1.66 V, E -040 V
(1) 273 K (2) 298 K
(3) 373 K (4) At all temperature 1) SF8kJ (2) -729.54 kJ

E values of ZnZn, FeFe and NPNE ane (4) 729.54 kJ


3
o.76 V, -0.44 Vand -0.25 Vrespectvelyhi 8, Wiich of the following statements is not corect?
of the following is correc? 1) In an electrolytic cell extemal source of voltage
(1) Zn oxidises Fe (2) Ni recesZn Is used to bring about a chemical reaction
(3) Zn reduces Fe? (4) Ni redsces
Fe
4 What will be the ent of the cel lwhich the (2) Dry cell is also known as Ledanche cell
following reaction takes place at 298 R? (3) Specific conductance increases with dilution
Mgls)+2Ag" (aq) Mg0.625M
(aq)+ 2Ags) (4) LI' is the strongest reducing agent
o.0025M 9. The producd oblained at anode, on electrolysis of
(Given: E3.17V) dlute sulphuric acid and concentrated sulphuric
acld respectively are
(1) 3.2 (2) 3.02
(1) HaS(9), SOg) (2) Oalg), SOaq)
(3) 2.7 (4) 2.59
5 Match column- with column-ll (3) SOg). Oz{g) (4) Halg), SO:(g)
Column-4 Column-| 10. The specific conductance of 0.01 mol L acetic
(Term) (Unit) acid is k S cr. The limiting molar conductance
a. Molar conductivity |()
of CHsCO0 and H are x and y respectlvely. The
degree of dissociation of acetic acd is
b Specific conduciance (ü) S am
c. Cell constant
d. Conductance
(if Siemen
(v)Sam² mot
(1) K109
(1) a(ii), b(v), c(i), dÖ) (2) a(i), b(v), ch), d(ii) k
*+y*10$
(3)
(3) a(iv), b(i), c(ü), d(ii) (4) a(v), b(ü), c), d(i)
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Chemlsty
Poll-04
11, Whal will be the molar conducance of CH;COOH (2)
at infinite dilution M A for NaC, HCI and
CHCOONa are 126.45, 426.16 and
91 S cm mo respectvely
(1) 461.61 S cm mol (2) 553.5 S om mot

(3) 390.7 S cm² ma (4) 208.7S am' moH (3) (4)


12. Amount of elecdrons Row through the wire Ma
Cument of 0.5 ampere lows Urough metalc wre
for 100 minutes
(1) 1.67 102 (2) 3.12 100
18. Tho oxkdation potential of a hydrogen elecrode at
(3) 3.12 100 (4) 1.67 102
pH= 10 and P, 1 atm is
13. What wil be the charpe requlred for the roduction
of 0.1 mole of MnO, to Mn7
(1) 0.0591 (2) 0.00 V
(3) 0.691 V (4) 1V
(1) 96500 C (2) 4825 C
19. Assertion (A) : Molar conductivity Increase with
(3) 9650 C (4) 48250 C decrease in concentration.
14. Mthe AG for a ghven reaction has a posithve value, (B When concontraion approaches
which of the following ghes the orrect Reasodchty
zero,tOar ls known limiting molar
rolationship lor the values of E,od R7 conductiv
(2) Eo: K Inhe iatolabove statements, selectthe comedt
(1) EBe >0; Keq <1 opion
(3) Ee >0; Keg >1 (4) Eo<0, Kgy OBoth(A)and (R) are true and (R) is the correct
jexplanation ad (A).
15. A device that coverts enargy of combustioh ofA eoth (AJand (R) are true but (R) is not the
fuels like hydrogen and methane, directly h
electrical energy is known as
eáexplanation of (A),
tAs true statement but (R) Is false.
(1) Lecdanche cell
(2) Fuel cell 3 Both (A) and (R) are false statements.
20 Assertion (A) : In electrolysis process of aqueous
(3) Ni-Cd cell
NaClsolution, Ha gas is evolved at cathodc.
(4) Mercury cell Reason (R) : Discharge polential of H* lons is
16. How much elecricity in terms of Faraday is lower than that of Na' ions
required to produce 112 g of Fe from FeOs? In the light of above statements, selec the correct
(1) 6F option
(2) 3F (1) Both (A) and (R) are true and (R) is the corect
(3) 2F explanation of (A).
(4) 4 F (2) Both (A) and (R) aro true but (R) is not the
17. Which of the following graph correcly represents corec explanation of (A).
the variation of molar conductivily of a weak (3) (A) is true statement but (R) Is false.
electrolyte with concentration? (4) Both (A) and (R) are false statements

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