KV No.

1 Hussainpur,RCF
Monthly test
Chemistry MM=35
1. Why is freezing point depression of 0.1M sodium chloride solution nearly twice that of 0.1 M
glucose solution?
2. What is the Van’t Hoff factor in K4[Fe(CN)6] a)2 b)4 c)5 d)3
3.Which colligative property is more useful to determine the molecular mass of the proteins and
polymers?
a)relative lowering in vapour pressure b)elevation in boiling point c)depression in
freezing point d)osmotic pressure
4. A plant cell shrinks when it is kept in a
(a) hypotonic solution (c) isotonic solution
(b) hypertonic solution (d) pure waterAnswer
5.Sprinkling of salt helps in clearing the snow covered roads in hills. The phenomenon involved in the
process is 1
(a) lowering in vapour pressure of snow
(b) depression in freezing point of snow
(c) melting of ice due to increase in temperature by putting salt
(d) increase in freezing point of snow
6.If two liquids A and B form minimum boiling azeotrope at some specific composition then
(a) A – B interactions are stronger than those between A – A or B – B
(b) Vapour pressure of solution increase because more number of molecules of liquids A and B
can escape
(c) Vapour pressure of solution decreases because less number of molecules of only one of the
liquids escapes from the solution
(d) A – B interactions are weaker than those between A – A or B – B.
7.KH (kbar) values for Ar (g), CO2 (g), HCHO (g) and CH4 (g) are 40.39, 1.67, 1.83 x 10 -5 and 0.413
respectively. Arrange these gases in the order of their increasing solubility.
(a) HCHO < CH4 < CO2 < Ar
(b) HCHO < CO2 < CH4 < Ar
(c) Ar < CO2 < CH4 < HCHO
(d) Ar < CH4 < CO2 < HCHO
8.In Galvanic cell, conventional,
(1) Anode is on the left hand side and is (+ve) electrode
(2) Cathode is on the left hand side and is (+ve) electrode
(3) Anode is on the left hand side and is (–ve) electrode
(4) None
9. A 5% solution of Na2SO4.10H 2O (MW = 3 22) is isotonic with 2% solution of non- electrolytic,
non volatile substance X. Find out the molecular weight of X. 3
10.A) Given the standard electrode potentials, K + /K = –2.93V, Ag+ /Ag = 0.80V, Hg2+/Hg =
0.79V Mg2+/Mg = –2.37 V, Cr3+/Cr = – 0.74V Arrange these metals in their increasing order of
reducing power.
B)Can we store CuSO4 in zinc vessel,justify your answer. 2
11.Depict the galvanic cell in which the reaction Zn(s)+2Ag+ (aq) →Zn2+(aq)+2Ag(s) takes place.
Further show: 3
(i) Which of the electrode is negatively charged?
(ii) The carriers of the current in the cell.
(iii) Individual reaction at each electrode.

12.The EMF of a cell corresponding to the reaction ( E˚ Zn2+/Zn= -0.76V)

Zn(s) +2H+(aq) -------------- zn2+(0.1M) +H2(g,1atm) is 0.28V at 250c
Write the half cell reaction and calculate the PH of the solution at Hydrogen electrode 3
13.State Henry’s law and mention some important applications? 3
(a) What type of deviation from Roult’s Law is expected when phenol and aniline are mixed
with each other? What change in the net volume of the mixture is expected? Graphically
represent the deviation.
(b) The vapour pressure of pure water at a certain temperature is 23.80 mm Hg. If 1 mole of a
non- volatile non- electrolytic solute is dissolved in 100g water, Calculate the resultant vapour
pressure of the solution. 5
14.45 g of ethylene glycol (C2H6O2 ) is mixed with 600 g of water. Calculate (a) the freezing point
depression and (b) the freezing point of the solution. 3
15.Define the following: 5
a) Reverse Omosis
b) Anoxia
c) Salt Bridge
d) Molality
e) Ebullioscopic constant

A standard reduction electrode potential of four metals are

A = –0.250 V, C = –0.126 V
B = –0.140 V D = –0.402 V
The metal that displaces A and B from its compound in aqueous solution is
(1) B
(2) C
(3) D
(4) None of the above
1. A 5% solution of Na2SO4.10H 2O (MW = 3 22) is isotonic with 2% solution of
non- electrolytic, non volatile substance X. Find out the molecular weight of X.
3
2. Given the standard electrode potentials, K + /K = –2.93V, Ag+ /Ag = 0.80V,
Hg2+/Hg = 0.79V Mg2+/Mg = –2.37 V, Cr3+/Cr = – 0.74V Arrange these
metals in their increasing order of reducing power.
2

3. Depict the galvanic cell in which the reaction Zn(s)+2Ag+ (aq)

→Zn2+(aq)+2Ag(s) takes place. Further show:
3
(i) Which of the electrode is negatively charged?
(ii) The carriers of the current in the cell.
(iii) Individual reaction at each electrode.

4. The EMF of a cell corresponding to the reaction ( E˚ Zn2+/Zn= -0.76V)

Zn(s) +2H+(aq) -------------- zn2+(0.1M) +H2(g,1atm) is 0.28V at 250c
Write the half cell reaction and calculate the PH of the solution at Hydrogen electrode
3
5. State Henry’s law and mention some important applications?
3
6. (a) What type of deviation from Roult’s Law is expected when phenol and
aniline are mixed with each other? What change in the net volume of the
mixture is expected? Graphically represent the deviation.
(b) The vapour pressure of pure water at a certain temperature is 23.80 mm
Hg. If 1 mole of a non- volatile non- electrolytic solute is dissolved in 100g
water, Calculate the resultant vapour pressure of the solution.
5
7. 45 g of ethylene glycol (C2H6O2 ) is mixed with 600 g of water. Calculate (a)
the freezing point depression and (b) the freezing point of the solution.
3
8. Define the following:
5
f) Reverse Omosis
g) Anoxia
h) Salt Bridge
i) Molality
j) Ebullioscopic constant