VISION UDAN

BURHANPUR

Class: XII (All) DPP-8 (Alkenes, Alkynes) Subject: Chemistry

 Single Answer Type questions

1. In which case regioselectivity is observed when HBr reacts with
(a) 2-pentene (b)2-hexene (c) 1-pentene (d) in all cases
2. Consider the following reagents
I: Br2 water II: alkaline KMnO4
III: HCO3H IV: OsO4 in ether solution /H2O2
Reagents used to make distinction beteen alkane and alkene are :
(a) I, II (b) II, III (c) I, III (d) I, IV
3. Select the incorrect statement.
(a) Hydroxylation (glycol formation) can be affected by cold alkaline KMnO4/HCO3H/OsO4
in ether
(b) Addition of 2OH by KMnO4 is anti
(c) Addition of 2 OH by HCO3H is anti
(d) Addition of 2OH by KMnO4 is syn
4. Hydroxylationof alkene can be affected by
I: OsO4 in ether /H2O2 II: HCO3H III: KMnO4/OH
In which case racemic mixture is formed when cis-2-butene reacts with:
(a) I (b) II (c) III (d) any of I, II and III
5. In the following compound

Which (C = C) bond is more nucleophilic?

(a) A (b) B
(c) Equally nucleophilic (d) C = C is never nucleophilic

6. Which is the incorrect reaction?

7. Hydration of alkene takes place in following steps:

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 Rate determining step (slow step) is :
(a) I (b) II (c) III (d) I and III
8. Which is regioselective?

I: RCH  CHR H 2O / H
 II: RCH  CHR  
HBr

(a) I (b) II (c) both I and II (d) None of these
9. To prepare only B from A, reagent used is :

(a) H2O/H+ (b) Hg(OAc)2/NaBH4  NaoH

(c) Both (a) & (b) (d) None of these
10. Select the incorrect statement in oxymercuration-demercuration reaction
(a) Hydration takes place in accordance with Markownikoff’s rule
(b) No free carbocation is involved
(c) Addition is regioselective
(d) More stable carbocation is formed by 1,2-methyl or 1,2-hydride shift
11. Halohydrin formation takes place when Cl2 or Br2 in presence of H2O adds to alkene.
Species added are :
(a) OH  , Cl  (b) OH  , Cl  (c) OH, Cl (d) OH  , Cl 
12. Cl2/H2O adds to alkene RCH=CH2. Intermediate formed is :

13. In which case addition of Br2/H2O is highly regioselective?

(a) CH 3CH  CHCH 2CH 3 (b)  CH 3 2 C  CH 2
(c) CH 3CH  CHCH 3 (d) CH 2  CH 2
14. Chlorohydrin formed when Cl2/H2O adds to cyclohexene has configuration

15. Intermediate (A) changes to chlorohydrin due to attack of H2O (nucleophile). Select correct
statement about this reaction
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16.  CH 3 2 CHCH  CH 2 changes to A, B and C by using :
 CH 3 2 CHCH 2CH 2OH  CH 3 2 CHCHCH 3  CH 3 2 CHCH 2CH 3
, | , |
OH OH
A B C
(a) H 2O / H  , BH 3  THF / H 2O2  NaOH , Hg  OAc 2 / NaBH 4  NaOH
(b) H 2O / H  , Hg  OAc  2 / NaBH 4  NaOH , BH 3  THF / H 2O2  NaOH
(c) BH 3  THF / H 2O2  NaOH , Hg  OAc 2 / NaBH 4  NaOH , H 2O / H 
(d) BH 3  THF / H 2O2  NaOH , H 2O / H  , Hg  OAc 2 / NaBH 4  NaOH
17. In which case carbocation is the intermediate?
(a) Alkene + H2O/H+ 
 (b) Alkene + BH3 THF/H2O2NaOH 

(c) Alkene + Hg(OAc)2/NaBH4NaOH (d) In All cases
18. Same type of alcohol is formed by :
I: H 2O / H  II: BH 3  THF / H 2O2  NaOH III: Hg  OAc  2 / NaBH 4  NaOH
When alkene is :
(a) CH 3CH  CHCH 3 (b) CH 3CH  CH 2
(c)  CH 3 2 CHCH  CH 2 (d) CH 3CH 2CH  CH 2
19. Select the correct configuration in the following addition reaction.

20. To convert A into B

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 Reagent used is :
(a) Hg(OAc)2/NaBH4NaOH (b) BH3THF/H2O2 NaOH
(c) Both of (a) and (b) (d) None of these
21. Consider the following addition reaction,
CH 3CH  CH 2  HBr 
 CH 3CH 2CH 2 Br
This
(a) takes place by free-radical mechanism (b) takes place in presence of peroxide
(c) follows anti-Markownikoff’s rule (d) follows all these statements
22. General name of :CH2 is :
(a) Carbene (b) Carbocation (c) Carbanion (d) Carbonium ion
23. Write the correct statement about :CCl2
(a) it is an electrophile  Lewis base (b) it is a nucleophile – Lewis base
(c) it is an electrophile  Lewis acid (d) it is an nucleophile  Lewis acid
24. C10H16(A) changes C10H12(B) by ozonolysis. If B is symmetrical ketone then (A) is

25. By oxidation ozonolysis A (C4H8) changes to CH3COOH. Thus A is :

26. CH 3
A 
O3 / Zn , H 2O
  CH 3 2 CO  HCHO  |
CH 3
Thus, A is :
(a)  CH 3 2 CHCH  CHCH  CH 2 (b)  CH 3 2 C  CHCH  CH 2
(c) CH 3CH  CHCH  CHCH  CH 2 (d) None of these

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27.

28. Select the correct statement(s).

(a) Ozonide is reduced by Zn/CH3COOH so that H2O2 is not formed.
(b) Ozonide can be oxidized by Ag2O, H2O2.
(c) LiAlH4 can decomposition ozonide forming alcohol.
(d) All of the above are correct statements
29. Stabilities of alkenes can be compared by :
(a) heat of hydrogenation (b) heat of combustion
(c) both of (a) and (b) (d) none of these
30. Which is most stable alkene?

31. Which has least heat of hydrogenation?

32. When hydrogen of an alkene is replaced by alkyl/aryl group.

(a) Bond strength increases (b) Heat of hydrogenation is lowered
(c) Stability is increased (d) All of these

Answer Key DPP_ 8

1 2 3 4 5 6 7 8 9 10
C A B B A C A D B D
11 12 13 14 15 16 17 18 19 20
B C B D C C A A D B
21 22 23 24 25 26 27 28 29 30
D A C A C B D D C A
31 32
A D