FIITJEE

Physics: - Full Electro state: -Test-4

SMCQ

1.

2.

3.

4.

5.

6.

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7.

8.

9.

10.

SMCQ

11.

Ranchi (Lalpur) :7th Floor, Hari Om Towers, (Opp. Women’s College, Arts Block), Circular Road, Ranchi, Ph : 0651- 2563187/88/89/90.
Ranchi (SOP, Doranda): Samriddhi Complex, Ground Floor, Near St. Xavier’s School, South Office Para Doranda, Ranchi.
Jamshedpur : Om Plaza, 3rd Floor, Thakurbari Road, Aam Bagan, Sakchi, Jamshedpur
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12.

13.

14.

15.

Ranchi (Lalpur) :7th Floor, Hari Om Towers, (Opp. Women’s College, Arts Block), Circular Road, Ranchi, Ph : 0651- 2563187/88/89/90.
Ranchi (SOP, Doranda): Samriddhi Complex, Ground Floor, Near St. Xavier’s School, South Office Para Doranda, Ranchi.
Jamshedpur : Om Plaza, 3rd Floor, Thakurbari Road, Aam Bagan, Sakchi, Jamshedpur
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Chemistry: - ALCOHOL, ETHER & PHENOL

SMCQ
Q1. Identify the end product (B) of the following sequence of reactions.
OH

Conc. H2SO4 Br2/H2O

(A) (B)
100 Co excess

OH OH
Br Br Br Br
(A) (B)

SO3H Br

OH OH

SO3H Br Br

(C) (D)
Br

Br

Q2.
OH OH

+ pH = 10 - 11
+ Ph N 2 Cl

N N Ph
The correct option according to above reaction is
(A) C – N coupling reaction, carbocation is intermediate.
(B) N – N coupling reaction, carbocation is intermediate.
(C) C – N coupling reaction, carbanion is intermediate.
(D) N – N coupling reaction, carbanion is intermediate.

Q3. Compare the properties of two isomeric products (x) and (y) formed in the following
reaction
OH

 H
+ CCl4/OH ? (X) + (Y)
Major Minor

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Acidic strength H2O solubility Volatility

(A) y>x y> x x>y
(B) x>y x>y y> x
(C) y>x x>y y> x
(D) x>y y> x x>y

Q4. Identify the product in the following reaction.

C 6H 5
H3O+
O2N C O O CH3 ?
C 6H 5
(A) Benzophenone + Phenol
(B) Nitrobenzene + Benzophenone
(C) p-Nitrobenzophenone + Phenol
(D) p-Nitrobenzophenone + benzene
Q5. Phenol on treatment with CO2 in presence of NaOH followed by acidification produces
compound (X) as the major product. (X) on treatment with (CH 3CO)2O in presence of
catalytic amount of H 2SO4 produces.
O
O O C CH3

O C CH3

(A) (B)
COOH
COOH
O O

C O C CH3 COOH
OH

(C) (D)
COOH

O C CH3
O
Q6.

O H+
Product of this reaction is

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OH

H Ph Ph Ph
(A) (B)
,
Ph Ph Ph Ph
Ph HO Ph
(C) HO Ph (D) ,
Ph Ph
Ph

Q7. An organic compound (A) with molecular formula C7H8O dissolves in NaOH gives
characteristic colour with FeCl3. On treatment with Br 2, it gives a tribromo product
C7H5OBr3. The compound is.
(A) p- Hydroxybenzene (B) 2-Methoxy-2-phenyl propane
(C) m-Cresol (D) p- Cresol

Q8. In the following compound

OH OH OH OH

NO2
CH3 NO2
(I) (II) (III) (IV)
The order of acidity is
(A) (III) > (IV) > (I) > (II) (B) (I) > (IV) (III) > (II)
(C) (II) > (I) (III) > (IV) (D) (IV) > (III) > (I) > (II)

Q9. Consider the following reaction of phenol

CH3Cl
1. AlkalineKMnO4

Zn dust
 X 
Anhydrous AlCl3
 Y  
Z
2. H2O /H

The product Z is
(A) Benzene (B) Toluene
(C) Benzaldehyde (D) Benzoic acid

Q10. In Reimer- Tiemann reaction, the intermediate which does not form is
+
O O Na
CHCl2 H
(A) (B) CCl2

O
H
(C) CCl2 (D) All of these

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MMCQ

Q11. Select wrong statements.

(A) Phenol react with Na2CO3 and liberates CO2 gas
(B) Phenol turns blue litmus to red
(C) Reactivity of methanol with Na metal is more than that of isopropyl alcohol
(D) Methanol gives iodoform test

Q12. Which of the following may undergo Reimer – Tiemann reaction?

OH OH
OCH3

(A) (B)

NO2

(C) (D)

Q13. The correct statement(s) about the following reaction sequence is (are)
(i)O3 CHCl3 / NaOH
Cumene  C9H12    P 

 Q(Major)  R(Minor)
(ii)H3O
NaOH
Q 
PhCH2Br
S
(A) R is steam volatile
(B) Q gives dark violet coloration with 1% aqueous FeCl3 solution
(C) S gives yellow precipitate with 2,4- dinitrophenylhydrazine
(D) S gives dark violet coloration with 1% aqueous FeCl3 solution

Q14. Phenol is less acidic than

(A) acetic acid (B) p- methoxyphenol
(C) p- nitrophenol (D) Ethanol

Q15. Among the following reactions, which form salicylic acid (after acidification)?
OH

NaOH
(A) + CHCl 3 ?

OH

NaOH
(B) + CCl4 ?

OH

(C) + CO2 + NaOH

COOH

(D) + NaOH

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MATHEMATICS: - LCD
 
lncot   k1x 
Q1. If lim 4   1, then
x 0 tank 2 x
(A) k1 = k 2 (B) 2 k1 = k2
(C) k1 = 2k2 (D) k1 = 4k2

ex 1 x 1
Q2. Let f(x) = e (x  1)  ax2 + b and g(x)   , then the values of a and b such that
2
 x  1 x  1
f(x)  g(x) is differentiable at x = 1, can be
1
(A) , 1 (B) 1, 1
2
1 1
(C) ,  (D) 1, 1
2 2


 min x, x 2  x0
Q3. If f ( x )  
 
min 2x, ( x 2  1) x0
Then the number of points in the interval [–2,2] where f is non-differentiable, is
(A) 1 (B) 2
(C) 3 (D) 4

Q4. If f(x) is a continuous function  x  R and the range of f(x) = (2, 26 ) and
 f x 
g(x) =   is continuous  x  R ( [.] denotes the greatest integer function), then
 a 
the least positive integral value of a is
(A) 2 (B) 3
(C) 6 (D) 5

Q5. Total number of points of nondifferentiability of f(x) = min. {1, 1+ x3, x2  3x + 3} are
(A) 2 (B) 3
(C) 4 (D) None

Q6. The number of points where f(x) = [sinx + cos x] (where [ ] denotes the greatest integer
function), x  ( 0, 2) is not continuous is
(A) 3 (B) 4
(C) 5 (D) 6

2 2(x 1)
 x e , 0  x 1
Q7. Let f(x)  
2
a sgn(x  1)cos(2x  2)  bx , 1  x  2
If f(x) is differentiable at x = 1, then (Where sgn x denotes signum function of x)
(A) a = –1, b = 2 (B) a = –3, b = –2
(C) a = –3, b = 4 (D) a = –5, b = –4

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+ k
Q8. If f(x) = [2x]sin3x and f(k ) = k(–1) , (where [.] denotes the greatest integer function, f
+
(k ) denotes RHD of f(x) at x = k and k  N) then the value of  is
(A) 1 (B) 3
(C) 5 (D) 6

sin2 x
Q9. lim equals
x 0
2  1  cos x
(A) 4 2 (B) 2
(C) 2 2 (D) 4

 2 cos x  1
Q10. If f  x    cot x  1 ,x   / 4 be continuous at x   / 4 then k 
 k, x   / 4

1
(A) (B) 1
2
(C) 2 (D) 4

Section-B
Multi choice multi correct
Q11. Let f(x) be a non-zero function, whose all successive derivatives exist and are non-zero. If
f(x), f(x) and f(x) are in G.P. and f(0) = f(0) = 1, then
(A) f(x) > 0  x  R (B) f(x) > 0  x  R
(C) f(0) = 1 (D) f(x)  1  x  R

Q12. f(x) = cos( |x| +[x] ), then

(A) f is continuous at x = 1/2 (B) f is continuous at x = 0
(C) f is differentiable in ( -1, 0) (D) f is differentiable in (0, 1) .
-1 2
Q13. Let f(x) = sec ([1+sin x]) ([.] denotes the greatest integer function). Then set of points,
where f(x) is not continuous is
 n    
(A)  , n  I (B) (2n  1) , n  I
2   2 
  
(C) (2n  1) , n  I (D) None
 2 
2x
x  
Q14. If lim   2   e 2 , then
x   x x 
(A)  = 1 (B)  = 2
(C)  = any real constant (D)  = 1 or 2 only

Q15.

max x ,x 2 , x  2
Let f  x   

 8  2 x , 2  x  4
then
(A) f is continuos at every point in the interval  4, 4 
(B) Number of points in the interval  4, 4  where f is not differentiable is 5
(C) Number of points in the interval  4, 4  where f is discontinuous is zero.
(D) Number of points in  4,4  where f is not differentiable is 4

Ranchi (Lalpur) :7th Floor, Hari Om Towers, (Opp. Women’s College, Arts Block), Circular Road, Ranchi, Ph : 0651- 2563187/88/89/90.
Ranchi (SOP, Doranda): Samriddhi Complex, Ground Floor, Near St. Xavier’s School, South Office Para Doranda, Ranchi.
Jamshedpur : Om Plaza, 3rd Floor, Thakurbari Road, Aam Bagan, Sakchi, Jamshedpur
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