F.M. : 50 DATE : 05.08.

2020

Time : 𝟐 hours Chapter : ATOMIC STRUCTURE

ANSWER THE FOLLOWING QUESTIONS

SECTION – A
Multiple Choice Question : [20]

1. The energy of hydrogen atom in its ground state is –13.6 eV. The energy of the level corresponding to 𝑛 = 5
(a) –0.54 eV (b) –5.40 eV
(c) –0.85 eV (d) –2.72 eV

2. Which of the following ions has the maximum number of unpaired d-electrons?
(a) Zn2+ (b) Fe2+
(c) Ni3+ (d) Cu+

3. The value 𝑙 and 𝑚 for the last electron in the 𝐶𝑙 − ion are
(a) 1 and 2 (b) 2 and +1
(c) 3 and –1 (d) 1 and –1

4. Which electronic level would allow the hydrogen atom to absorb a photon but not to emit a photon?
(a) 3𝑠 (b) 2𝑝
(c) 2𝑠 (d) 1𝑠

5. Which of the following sets of quantum numbers represents an impossible arrangement

𝑛 𝑙 𝑚𝑙 𝑠
1
(a) 3 2 −2 2
1
(b) 4 0 0 2
1
(c) 3 2 −3
2
1
(d) 5 3 0
2

6. Which of the following has the maximum number of unpaired electron (atomic number of Fe 26)?
(a) Fe (b) Fe (II)
(c) Fe (III) (d) Fe (IV)

7. An electron in a hydrogen atom in its ground state absorbs energy equal to ionisation energy of Li2+. The
wavelength of the emitted electron is
(a) 3.32 × 10−10 m (b) 1.17 Å
−9
(c) 2.32 × 10 nm (d) 3.33 pm

8. If radius of second stationary orbit (in Bohr’s atom) is 𝑅. Then radius of third orbit will be
(a) 𝑅/3 (b) 9𝑅
(c) 𝑅/9 (d) 2.25 R

9. In a hydrogen atom, in transition of electron, a photon of energy 2.55 eV is emitted. Then the change in
wavelength of the electron is
(a) 3.32 Å (b) 6.64 Å
(c) 9.97 Å (d) None of these

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A. LAKSHMAN :: What’s app Number . : 9091669866 :: Subject : CHEMISTRY (XI & XII, ALL BOARD, NEET-UG, JEE-MAIN & ADVANCE)
10. In which orbit of the hydrogen atom is the speed of the electron maximum?
(a) 𝑛 = 2 (b) 𝑛 = 1
(c) 𝑛 = 3 (d) 𝑛 = 4

11. Correct set of four quantum numbers for the valence (outermost) electron of Ca
(a) 4, 0, 0, + 1/2 (b) 5, 1, 0, + 1/2
(c) 4, 1, 1, + 1/2 (d) 6, 0, 0, + 1/2

12. The ratio of energy of the electron in ground state of hydrogen to the electron in first excited state of Be3+ is
(a) 4 : 1 (b) 1 : 4
(c) 1 : 8 (d) 8 : 1.

13. The difference in angular momentum associated with the electron in two successive orbits of hydrogen atoms
is
ℎ ℎ
(a) 𝜋 (b) 2𝜋
ℎ (𝑛−1)ℎ
(c) 2
(d) 2𝜋

14. The shortest 𝜆 for the Lyman series of hydrogen atom is … (Given: RH = 109678 cm–1)
(a) 911.7 Å (b) 700 Å
(c) 600 Å (d) 811 Å

15. If 𝑚 = magnetic quantum number and 𝑙 = azimuthal quantum number, then

(a) 𝑚 = 𝑙 + 2 (b) 𝑚 = 2𝑙 2 + 1
𝑚−1
(c) 𝑙 = 2 (d) 𝑙 = 2𝑚 + 1

16. In Bohr’s model of the hydrogen atom, the ratio between the period of revolution of an electron in the orbit of
𝑛 = 1 to the period of the revolution of the electron in the orbit 𝑛 = 2 is
(a) 1 : 2 (b) 2 : 1
(c) 1 : 4 (d) 1 : 8

17. The outermost electronic configuration of the most electronegative element is

(a) 𝑛𝑠 2 𝑛𝑝3 (b) 𝑛𝑠 2 𝑛𝑝4
2 5
(c) 𝑛𝑠 𝑛𝑝 (d) 𝑛𝑠 2 𝑛𝑝6

18. If the Aufbau principle is not followed and subshells of a shell are progressively filled according to their energy,
which of the following elements is paramagnetic?
(a) Mg (b) Ca
(c) Ni (d) Zn

19. Find the total number of species having magnetic moment value of 2.84 B.M. from following species:
Fe2+, Cr, Cr3+, Ti2+, Mn2+, V3+
(a) 2 (b) 3
(c) 4 (d) 5

20. Which of the following orbital is non-directional?

(a) 𝑠 (b) 𝑝
(c) 𝑑 (d) All of these

SECTION – B

21. A photon of wavelength 4 × 10−7 m strikes on metal surface, the work function of the metal being 2.13 eV.
Calculate
(a) the energy of the photon (eV),
(b) the kinetic energy of the emission, and
(c) the velocity of the photoelectron (1 eV= 1.6 × 10−19 J). [3] 2
A. LAKSHMAN :: What’s app Number . : 9091669866 :: Subject : CHEMISTRY (XI & XII, ALL BOARD, NEET-UG, JEE-MAIN & ADVANCE)
22. How many electrons may enter the orbital denoted by
(a) 2𝑝,
(b) 1𝑠,
(c) 3𝑝 ,
(d) 3𝑑 [2]

23. A neutral atom of an element has 2𝐾, 8𝐿, 9𝑀 and 2𝑁 electrons. Find out the following:
(a) Atomic no.,
(b) Total no. of s-electrons,
(c) Total no. of 𝑝-electrons,
(d) Total no. of 𝑑-electrons,
(e) Valency of element,
(f) No. of unpaired electrons. [3]

24. Write the electronic configuration of 𝐹𝑒 2+ , 𝑀𝑛4+ , 𝑁 3− and 𝑂2− ion [2]

25. What is the wavelength of light emitted when the electron in a hydrogen atom undergoes transition from an energy
level with 𝑛 = 4 to an energy level with 𝑛 = 2 ? [2]

26. What is the maximum number of emission lines when the excited electron of a 𝐻-atom in 𝑛 = 6 drops to the
ground state ? [2]

27. (a) The energy associated with the first orbit in the hydrogen atom is −2.17 × 10−18 J/atom. What is the
energy associated with fifth orbit?
(b) Calculate the radius of Bohr’s fifth orbit in hydrogen atom.
[2]

28. The mass of an electron is 9.1 × 10−31 kg. If its K.E. is 3.0 × 10−25 J. Calculate the wavelength. [2]

29. (a) An atomic orbital has 𝑛 = 3. What are the possible values of 𝑙 and 𝑚𝑙 ?
(b) List the quantum numbers (𝑚𝑙 and 𝑙) of electrons for 3𝑑-orbitals
(c) Which of the following orbitals are possible ?
1𝑝 , 2𝑠, 2𝑝 and 3𝑓 [3]

30. How many electrons in an atom may have the following quantum numbers ?
1
(a) 𝑛 = 4 , 𝑚𝑠 = − 2
(b) 𝑛 = 3 ,𝑙 = 0 [2]

31. Show that the circumference of the Bohr orbit for the hydrogen atom is an integral multiple of the de Broglie
wavelength associated with the electron revolving around the orbit. [2]

32. Neon gas is generally used in the sign boards. If the emits strongly at 616 nm, calculate
(a) the frequency of emission,
(b) distance travelled by this radiation in 30 s.
(c) energy of quantum and
(d) number of quanta present if it produces 2 J of energy. [2]

33. The work function for caesium atom is 1.9 eV. Calculate
(a) the threshold wavelength and
(b) the threshold frequency of the radiation.
If the caesium element is irradiated with wavelength 500 nm, calculate the kinetic energy and velocity of the
ejected photoelectrons. [3]

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A. LAKSHMAN :: What’s app Number . : 9091669866 :: Subject : CHEMISTRY (XI & XII, ALL BOARD, NEET-UG, JEE-MAIN & ADVANCE)