ARUN’S CLASSES OF CHEMISTRY

Topic name mock test 2

Date : 30/08/2022 Time :1h No. MCQ 30

1. The 3d – orbitals having electron density in all the three axis (a) (i) 3p, (ii) 4f (b) (i) 3d, (ii) 4d
is (c) (i) 3f, (ii) 4f (d) (i) 3d, (ii) 4f
(a) 3d xy (b) 3d z2 (c) 3d yz (d) 3d zx 12. Few statements are given regarding nodes in the orbitals.
2. An element with mass number 81 contains 31.7% more Mark the statement which is not correct.
neutrons as compared to protons. Find the symbol of the (a) In case of Pz - orbital, xy plane is a nodal plane.
atom. (b) ns- orbital has (n+1) nodes.
(a) 81
34 Se (b) 18
35 Br (c) 18
36 Kr (d) 18
37 Rb (c) The number of angular nodes is given by l.
3. Compare the energies of two radiations E1 with wavelength (d) The total number of nodes is given by (n -1) i.e., sum of l
angular nodes and (n – l – 1 )radial nodes.
800 nm and E 2 with wavelength 400 nm.
13. Effective nuclear charge ( Zeff e )for a nucleus of an atom is
(a) E1 = 2E 2 (b) E1 = E 2
defined as.
1 (a) Shielding of the outermost shell electrons from the nucleus
(c) E 2 = 2E1 (d) E 2 = − E1
2 by the innermost shell electrons
4. A 100 watt bulb emits monochromatic light of wavelength (b) The net positive charge experienced by electron from the
400 nm. Calculate the number of photons emitted per second nucleus
by the bulb. (c) The attractive force experienced by the nucleus from
20 −1 −20 −1
(a) 3 × 10 s (b) 2 × 10 s electron
(c) 2 × 10 s
20 −1
(d) 1 × 10 s
−20 −1 (d) Screening of positive charge on nucleus by innermost
shell electrons.
5. What is the maximum number of emission lines when the
excited electron of a hydrogen atom in n = 6 drops to ground 14. How many electrons in an atom have the following quantum
state? numbers?
(a) 6 (b) 15 (c) 30 (d) 10 n = 4, ms = - ½
6. Bohr’s theory can also be applied to the ions like. (a) 32 (b) 18 (c) 8 (d) 16
+ 2+ 3+
(a) He (b) Li (c) Be (d) All of these. 15. In how many elements the last electron will have the
7. What is the velocity of electron present in first Bohr orbit of following set of quantum numbers, n = 3 and l = 1?
hydrogen atom? (a) 2 (b) 8 (c) 6 (d) 10
5 6
(a) 2.18 × 10 m/s (b) 2.18 × 10 m/s
16. Select the correct order(s) of acidic/basic strength :
−18 −9
(c) 2.18 × 10 m/s (d) 2.18 × 10 m/s (a) NaOH<Mg(OH)2< Al(OH)3 ; basic strength
8. If the radius of first Bohr orbit is x pm, then the radius of the(b) H2S > H2Se >H2Te ; acidic strength
third would be (c) H2SO3<H2SO4 ; acidic strength
(a) (3 × x)pm (b) (6 × x)pm (d) Both (b) and (c)
1  17. Values of IE1, IE2 and IE3 of an element are 9.3, 18.2 and
(c)  × x  pm (d) (9 × x)pm 553.8 eV. What information(s) do these data convey?
2  (a) The element has two electrons in the valence shell.
9. The third line of the balmer series in the emission spectrum of (b) The element belongs to 14th group of Modern periodic
the hydrogen atom is due to the transition from the. table.
(a) Fourth Bohr orbit to the first Bohr orbit (c) Both (a) and (b)
(b) Fifth Bohr orbit to the second Bohr orbit (d) None of these
(c) Sixth Bohr orbit to the third Bohr orbit 18. The ionization energy of hydrogen atom is 13.6 eV. The third
(d) Seventh Bohr orbit to the third Bohr orbit. ionization energy of lithium would be –
(a) 13.6 eV (b) 27.2 eV (c) 40.8 eV (d) 122.4 eV
10. An electron is in one of the 3d – orbitals. What are the
possible values of n, l and m for this electron? 19. Which one of the following is smallest in size ?
(a) n = 3, l = 0, m l = 0 (a) N 3 − (b) O 2 − (c) F − (d) Na +
20. Fill in the blanks by picking the correct option.
(b) n = 3, l = 1, m l = - 1, 0, +1, There are _______ groups and _____ periods in the extended
(c) n = 3, l = 2, m l = - 2, -1,0,+1,+2 form of periodic table. The group, all members of which are
in gaseous state under ordinary conditions is _____ group.
(d) n = 3, l = 3, m l = - 3, -2, -1, 0, +1, +2, +3 Most electropositive elements belong to ______ group.
11. Describe the orbital with following quantum numbers: (a) 16, 8, 17, 2 (b) 18, 7, 18, 1
(i) n = 3, l = 2 (ii) n = 4, l = 3 (c) 8, 7, 0, 2 (d) 16, 8, 18, 1
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21. Electronic configuration of few elements are given below (b)Alkali A noble gas Alkaline earth
mark the incorrect match. metal metal
(a) 1s 2 2s 2 2p5 - Most electronegative element

(b) 1s 2 2s 2 2p3 - An element belonging to 3rd period (c) Alkaline alkali metal A noble gas
earth metal
and 5th group
(c) 1s 2 2s 2 2p 6 3s 2 - A d – block element 3p 6 3d8 4s 2 (d) Alkali Alkaline A noble gas
(d) 1s 2 2s 2 2p 6 3s3 3p 6 - An element from 18th group metal earth metal
22. Indicate the wrong statement on the basis of the periodic 27. First and second ionisation enthalpies (in kJ/mol) of few
table. elements are given below.
(a) The most electronegative element in the periodic table is
Element I E1 I E2
fluorine.
(b) Scandium is the first transition element and belongs to (i) 520 7300
fourth period. (ii) 900 1760
(c) There are three transition series in the periodic table each (iii) 1680 3380
containing 10 elements. (iv) 2082 3963
(d) Along a period halogens have maximum negative electron Which of the above elements will form halides with formula
gain enthalpy.
MX 2 ?
23. What is the decreasing order of basicity of hydroxides of the
alkaline earth metals? (a) (i) and (ii) (b) (i) and (iii)
(a) Be(OH) 2 > Mg(OH) 2 > Sr(OH) 2 > Ba(OH) 2 (c) (ii) and (iii) (d) (i) and (iv)
28. The electronic states X and Y of an atom are depicted below:
(b) Mg(OH) 2 > Be(OH) 2 > Ba(OH) 2 > Sr(OH) 2 2 2 6 1
X :1s 2s 2p 3s
(c) Ba(OH) 2 > Sr(OH) 2 > Mg(OH) > Be(OH) 2
Y :1s 2 2s 2 2P 6 3s 2 3p6 4s1
(d) Sr(OH) 2 > Be(OH) 2 > Mg(OH) 2 > Ba(OH) 2
Which of the following statements is not correct?
24. Which of the following statements is not correct about the
(a) X represents an alkali metal.
electron gain enthalpy?
(a) In general, the electron gain enthalpy becomes less (b) Energy is required to change X into Y.
negative in going from top to bottom in a group (c) Y represents ground state of the element.
(b) the electron gain enthalpy becomes less negative in a (d) Less energy is required to remove an electron from X than
period from left to right. from Y.
(c) The elements having stable configuration like noble gases 29. What are the two radii shown as ‘a’ and ‘b’ in the figure
known as?
have large positive electron gain enthalpies.
(d) Electron gain enthalpy of O or F is less than that of
succeeding element.
25. Beryllium has higher ionisation enthalpy than boron. This can
be explained as, (a) a = Atomic radius, b = Molecular radius
(a) Beryllium has higher size than boron hance its ionisation (b) a = Covalent radius, b = van der Waals’ radius
enthalpy is higher (c) a = Ionic radius, b = Covalent radius
(b) Penetration of 2p – electrons to the nucleus is more than (d) a = Covalent radius, b = Atomic radius
the 2s – electrons 30. The electronic configuration of gadolinium (atomic number
(c) It is easier to remove electron from 2p – orbital as 64 ) is
compared to 2s – orbital due to more penetration of s – (a) [Xe]4f 3 5d 5 6s 2 (b) [Xe]4f 7 5d 2 6s1
electrons
(c) [Xe]4f 7 5d1 6s 2 (d) [Xe]4f 8 5d 6 6s 2
(d) Ionisation energy increases in a period.
26. Few elements are matched with their successive ionisation
energies. Identify the elements.
Element IE1 (kJ/mol) IE 2 (kJ/mol)
X 2372 5251
Y 520 7297
Z 900 1758

X Y Z
(a) A noble Alkali metal Alkaline earth
gas metal

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