PALVIT COACHING CENTRE

Near MC Road, Ganaur, Sonipat , Haryana 9455210392, 8279629269

2023-2024 session
CLASS –11
(CHEMISTRY CLASSES FOR 11, 12, & NEET/IIT JEE)
DPP–2 ATOMIC STRUCTURE JEE MAINS PREVIOUS YEAR QUESTION
JEE MAINS 2002 (c) 10–25 meters (d) 10–33 meters
1. In a hydrogen atom, if energy of an electron in
the ground state is 13.6 eV, then that in the 2nd JEE MAINS 2004
excited state is 8. Which of the quantum numbers is
(a) 1.51 eV (b) 3.4 eV correct for an electron present in 4f orbital ?
(c) 6.04 eV (d) 13.6 eV (a) n = 4, l = 3, m = +4, s = +1/2
(b) n = 3, l = 2, m = –2, s = +1/2
2. Uncertainty in the position of a minute (c) n = 4, l = 3, m = +1, s = +1/2
particle of mass 25g in space is 10-5 m. what is (d) n = 4, l = 4, m = –4, s = –1/2
the uncertainty in its velocity (in ms ) ?
–1

(a) 2.1×10–34 Js (b) 0.5×10–34 Js 9. Consider the ground state of Cr atom

(c) 2.1×10 Js
–28 (d) 0.5×10–34 Js (Z=24).The number of electrons with the
azimuthal quantum numbers 1 =1 and 2 are
3. Which of the following ions has the respectively
maximum magnetic moment. (a) 12 and 4 (b) 16 and 5
(a) Mn+2 (b) Fe+2 (c) 16 and 4 (d) 12 and 5
(c) Ti +2 (d) Cr+2

10. The wavelength of the radiation emitted

4. The number of d-electrons retained in when in a hydrogen atom electron falls from
Fe2+ (At.no. of Fe = 26) ion is infinity to stationary state 1, would be (Rydberg
(a) 4 (b) 5 constant = 1.097 × 107 m-1)
(c) 6 (d) 3 (a) 406 nm (b) 192 nm
(c) 91 nm (d) 9.1 × 10-8 nm
JEE MAINS 2003
5. The orbital angular momentum for an 11. Which one of the following sets of ions
electron revolving in an orbital is given by represents the collection of isoelectronic
!𝑙(𝑙 + 1)h/2𝛑. This momentum for s-electron species? (Atomic nos. : F = 9, Cl = 17, Na = 11, Mg
will be given by = 12, Al = 13, K = 19, Ca = 20, Sc = 21)
(a) K+,Cl-,Mg2+,Sc3+ (b) Na+,Ca2+,Sc3+,F-
(a) Zero (b) h/2𝛑
(c) K ,Ca ,Sc ,Cl
+ 2+ 3+ - (d) Na+,Mg2+,Al3+,Cl-
(c) √2 h/2 𝛑 (d) ½
JEE MAINS 2005
6. In Bohr series of lines of hydrogen
12. In a multi-electron atom, which of the
spectrum, the third line from the red end
following orbitals described by the three
corresponds to which one of the following inter-
quantum numbers will have the same energy in
orbit jumps of the electron for Bohr orbits in an
the absence of magnetic and electric fields?
atom of hydrogen
(a) n = 1, l = 0, m = 0 (b)n = 2, l = 0, m = 0
(a) 5 → 2 (b) 4 →1
(c) n = 2, l = 1, m = 1 (d) n = 3, l = 2, m = 1
(c) 2 →5 (d) 3 →2
(e) n = 3, l = 2, m = 0
(a) (a) and (b) (b) (b) and (c)
7. The de Broglie wavelength of a tennis ball of
(c) (c) and (d) (d) (d) and (e)
mass 60g moving with a velocity of 10 m/s is
approximately. (h = 6.63×10–34Js)
13. Of the following sets which one does NOT
(a) 10–31 meters (b) 10–16 meters
contain isoelectronic species?
(a) BO3–3,CO3–2,NO3– (b) SO3–2, CO3–2, NO3– 21. The ionization enthalpy of hydrogen
(c) CN−, N2, C2–2 (d) PO4–3, SO4-2, ClO4– atom is 1.312 × 106 J mol−1. The energy required
14. Pick out the isoelectronic structure from the to excite the electron in the atom from n = 1 to n
following : (i)CH3+ (ii)H3O+ (iii)NH3 (iv)CH3− = 2 is
(a) (i)and (ii) (b) (iii) and (iv) (a) 8.51 × 105 J mol−1 (b) 6.56 × 105 J mol−1
(c) (i) and (iii) (d) (ii), (iii) and (iv) (c) 7.56 × 105 J mol−1 (d) 9.84 × 105 J mol−1

15. Which of the following statements in AIEEE 2009

relation to the hydrogen atom is correct ? 22. In an atom, an electron is moving with a
(a) 3s orbital is lower in energy than speed of 600 m/s with an accuracy of 0.005%.
3p orbital Certainty with which the position of the electron
(b) 3p orbital is lower in energy than can be located is (h = 6.6 × 10-34 kgm2s-1, mass of
3d orbital electron, em = 9.1 × 10-31 kg)
(c) 3s and 3p orbitals are of lower energy (a) 5.10 × 10-3 m (b) 1.92 × 10-3 m
than 3d orbital (c) 3.84 × 10-3 m (d) 1.52 × 10-4 m
(d) 3s, 3p and 3d orbitals all have the same
energy AIEEE 2010
23. Calculate the wavelength (in nanometer)
AIEEE 2006 associated with a proton moving at 1.0 x103
16. According to Bohr's theory, the angular ms−1 (Mass of proton = 1.67 × 10-27 kg and h =
momentum of an electron in 5th orbit is 6.63 × 10-34 Js) :
(a) 10 h/π (b) 2.5 h/π (a) 0.40 nm (b) 2.5 nm
(c) 25 h/π (d) 1.0 h/π (c) 14.0 nm (d) 0.32 nm

17. Uncertainty in the position of an electron 24. The energy required to break one mole of Cl–
(mass = 9.1 × 10-31 kg) moving with a velocity Cl bonds in Cl2 is 242 kJ mol–1. The longest
300 ms-1, accurate upto 0.001% will be (h = wavelength of light capable of breaking a single
6.63 × 10-34 Js) Cl – Cl bond is (c = 3 x 108 ms–1 and NA = 6.02 x
(a) 1.92 × 10-2 m (b) 3.84 × 10-2 m 1023 mol–1)
(c) 19.2 × 10-2 m (d) 5.76 × 10-2 m (a) 594 nm (b) 640 nm
(c) 700 nm (d) 494 nm
18. The “spin-only” magnetic moment [in units
of Bohr magneton] of Ni2+ in aqueous solution 25. Ionisation energy of He+ is 19.6 x 10–18 J
would be (Atomic number of Ni = 28) atom . The energy of the first stationary state
–1
(a) 2.84 (b) 4.9 (n = 1) of Li2+is
(c) 0 (d) 1.73 (a) 4.41 x 10–16 J atom–1
(b) -4.41 x 10–17 J atom–1
19. Which of the following sets of ions (c) -2.2 x 10–15 J atom–1
represents a collection of isoelectronic species? (d) 8.82 x 10–17 J atom–1
(a) N3-, O2-, F-, S2- (b) Li+, Na+, Mg2+, Ca2+
(c) K , Cl , Ca , Sc
+ - 2+ 3+ (d) Ba2+, Sr2+, K+, Ca2+ AIEEE 2011
26. A gas absorbs a photon of 355 nm and
AIEEE 2007 emits at two wavelengths. It one of the
20. Which of the following sets of emissions is at 680 nm, the other is at
quantum numbers represents the highest (a) 743 (b) 518
energy of an atom ? (c) 1035 (d) 325 nm
(a) n=3, 1=2, m=l, s=+l/2
(b) n=3, 1=2, m=l, s=+l/2 AIEEE 2012
(c) n=4, 1=0, m=0, s=+l/2 27. The electrons identified by quantum
(d) n=3, 1=0, m=0, s= +1/2 numbers n and l (a) n = 4, l = 1, (b) n = 4, l = 0
(c) n = 3, l = 2, d) n = 3, l = 1 can be placed in
AIEEE 2008 order of increasing energy as
(a) c < d < b < a (b) d < b < c < a 34. According to Bohr's atomic theory :
(c) b < d < a < c (d) a < c < b < d (A) Kinetic energy of electron is ∝ Z2/n2.
AIEEE 2013 (B) The product of velocity (v) of electron and
28. Energy of an electron is given principal quantum number (n), ′vn′∝ Z2.
by E=−2.178×10−18J(Z2/n2). Wavelength of light (C) Frequency of revolution of electron in an
required to excite an electron in an hydrogen orbit is ∝ Z3/n3.
atom from level n = 1 to n = 2 will be (h = 6.62 × (D) Coulombic force of attraction on the
10−34 Js and c = 3.0 × 108 ms−1) electron is ∝Z3/n4.
(a) 2.816 × 10−7 m (b) 6.500 × 10−7 m Choose the most appropriate answer from the
(c) 8.500 × 10−7 m (d) 1.214 × 10−7 m options given below :
(a) (A), (C) and (D) only (b) (A) only
AIEEE 2014 (c) (C) only (d) (A) and (D) only
29. The correct set of four quantum numbers for
the valence elections of rubidium atom (Z= 37) JEE Main 2021 25th February Morning Slot
is: 35. The plots of radial distribution functions for
(a) 5, 1, 1, + ½ (b) 5, 1, 0, + 1/2 various orbitals of hydrogen atom against 'r' are
(c) 5, 0, 0, + ½ (d) 5, 0, 1, + 1/2 given below :

AIEEE 2015
30. Which of the following is the energy of a
possible excited state of a possible excited state
of hydrogen?
(a) +13.6 eV (b) -6.89 eV
(c) -3.4 (d) +6.8 eV

JEE Main 2016 (Offline)

31. A stream of electrons from a heated filament
was passed between two charged plates kept at
a potential difference V esu. If e and m are
charge and mass of an electron, respectively,
then the value of h / λ (where λ is wavelength
associated with electron wave) is given by :
The correct plot for 3s orbital is :
(a) 2meV (b) √𝑚𝑒𝑉
(a) (B) (b) (A)
(c) √2𝑚𝑒𝑉 (d) meV (c) (C) (d) (D)
JEE Main 2016 9th April Morning Slot JEE Main 2021 25th February Morning Slot
32. The total number of orbitals associated 36. In which of the following pairs, the outer
with the principal quantum number 5 is : most electronic configuration will be the same?
(a) 5 (b) 10 (a) Cr+ and Mn2+ (b) Ni2+ and Cu+
(c) 20 (d) 25 (c) V2+ and Cr+ (d) Fe2+ and Co+
JEE Main 2020 5th September Evening Slot JEE Main 2021 26th February Morning Shift
33. The correct statement about probability 37. The orbital having two radial as well as two
density (except at infinite distance from angular nodes is :
nucleus) is : (a) 3p (b) 5d
(a) It can be zero for 1s orbital (c) 4d (d) 4f
(b) It can be zero for 3p orbital
(c) It can never be zero for 2s orbital JEE Main 2021 26th February Evening
(d) It can negative for 2p orbital
38. Which of the following forms of
hydrogen emits low energy β- particles?
JEE Main 2021 24th February Evening Slot
(a) Tritium (b) Proton H+ JEE Main 2021 (Online) 20th July Evening
(c) Protium (d) Deuterium 44. Outermost electronic configuration of a
JEE Main 2021 (Online) 17th March Morning group 13 element, E, is 4s2, 4p1. The electronic
39. What is the spin-only magnetic moment configuration of an element of p-block period-
value (BM) of a divalent metal ion with atomic five placed diagonally to element, E is :
number 25, in its aqueous solution? (a) [Kr]3d104s24p2 (b) [Ar]3d104s24p2
(a) Zero (b) 5.26 (c) [Xe]5d 6s 6p
10 2 2 (d)[Kr]4d105s25p2
(c) 5.0 (d) 5.92
JEE Main 2021 (Online) 25th July Evening
JEE Main 2021 18th March Morning Shift 45. The spin only magnetic moments (in BM) for
40. The ionic radius of Na+ ions is 1.02 oA. free Ti3+, V2+ and Sc3+ions respectively are
The ionic radii (in oA) of Mg2+ and Al3+, (At.No. Sc : 21, Ti : 22, V : 23)
respectively, are (a) 3.87, 1.73, 0 (b) 1.73, 3.87, 0
(a) 1.05 and 0.99 (b) 0.72 and 0.54 (c) 1.73, 0, 3.87 (d) 0, 3.87, 1.73
(c) 0.85 and 0.99 (d) 0.68 and 0.72
JEE Main 2021 (Online) 27th July Morning
JEE Main 2021 18th March Morning Shift 46. Given below are two statements :
41. A certain orbital has no angular nodes and Statement I : Rutherford's gold foil experiment
two radial nodes. The orbital is : cannot explain the line spectrum of hydrogen
(a) 2s (b) 3s atom.
(c) 3p (d) 2p Statement II : Bohr's model of hydrogen atom
contradicts Heisenberg' uncertainty principle.
JEE Main 2021 18th March Evening Shift In the light of the above statements, choose the
42. Given below are two statements : most appropriate answer from the options
Statement I : Bohr's theory accounts for the given below :
stability and line spectrum of Li+ ion. (a) Statement I is false but statement II is true.
Statement II : Bohr's theory was unable to (b) Statement I is true but statement II is false.
explain the splitting of spectral lines in the (c) Both statement I and statement II are false.
presence of a magnetic field. (d) Both statement I and statement II are true.
In the light of the above statements, choose the
most appropriate answer from the options JEE Main 2021 (Online) 27th July Evening
given below : 47. If the Thomson model of the atom was
(a) Statement I is false but statement II is true. correct, then the result of Rutherford's gold foil
(b) Both statement I and statement II are true. experiment would have been :
(c) Statement I is true but statement II is false. (a) All of the α-particles pass through the gold
(d) Both statement I and statement II are false. foil without decrease in speed.
(b) α-particles are deflected over a wide range
JEE Main 2021 (Online) 18th March Evening of angles.
43. Given below are two statements : (c) All α-particles get bounced back by 180∘
Statement I : Bohr's theory accounts for the (d) α-particles pass through the gold foil
stability and line spectrum of Li+ ion. deflected by small angles and with reduced
Statement II : Bohr's theory was unable to speed.
explain the splitting of spectral lines in the
presence of a magnetic field. JEE Main 2021 (Online) 26th August Morning
In the light of the above statements, choose the 48. Given below are two statements.
most appropriate answer from the options Statement I : According to Bohr's model of an
given below : atom, qualitatively the magnitude of velocity of
(a) Statement I is false but statement II is true. electron increases with decrease in positive
(b) Both statement I and statement II are true. charges on the nucleus as there is no strong hold
(c) Statement I is true but statement II is false. on the electron by the nucleus.
(d) Both statement I and statement II are false.
Statement II : According to Bohr's model of an (a) 1 and 2 (b) 3 and 2
atom, qualitatively the magnitude of velocity of (c) 1 and 0 (d) 2 and 1
electron increases with decrease in principal JEE Main 2022 (Online) 26th June Morning
quantum number. 54. If the radius of the 3rd Bohr's orbit of
In the light of the above statements, choose the hydrogen atom is r3 and the radius of 4th Bohr's
most appropriate answer from the options orbit is r4. Then :
given below : (a) r4=(9/16)r3 (b) r4=(16/9)r3
(a) Both Statement I and Statement II are false (c) r4=(3/4)r3 (d) r4=(4/3)r3
(b) Both Statement I and Statement II are true
(c) Statement I is false but Statement II is true JEE Main 2022 (Online) 28th June Evening
(d) Statement I is true but Statement II is false 55. Consider the following statements :
(A) The principal quantum number 'n' is a
JEE Main 2022 (Online) 24th June Morning positive integer with values of 'n' = 1, 2, 3..
49. Consider the following pairs of electrons (B) The azimuthal quantum number 'l' for a
(A) (a) n = 3, 1 = 1, m1 = 1, ms = + 1/2 given 'n' (principal quantum number) can have
(b) n = 3, 1 = 2, m1 = 1, ms = + 1/2 values as 'l' = 0, 1, 2, ...... n
(B) (a) n = 3, 1 = 2, m1 = −2, ms = −1/2 (C) Magnetic orbital quantum number 'ml' for a
(b) n = 3, 1 = 2, m1 = −1, ms = −1/2 particular 'l' (azimuthal quantum number) has
(C) (a) n = 4, 1 = 2, m1 = 2, ms = + 1/2 (2l + 1) values.
(b) n = 3, 1 = 2, m1 = 2, ms = + 1/2 (D) ± 1/2 are the two possible orientations of
The pairs of electrons present in degenerate electron spin.
orbitals is/are : (E) For l = 5, there will be a total of 9 orbital
(a) Only (A) (b) Only (B) Which of the above statements are correct?
(c) Only (C) (d) (B) and (C) (a) (A), (B) and (C)
(b) (A), (C), (D) and (E)
JEE Main 2022 (Online) 24th June Evening (c) (A), (C) and (D)
50. The energy of one mole of photons of (d) (A), (B), (C) and (D)
radiation of wavelength 300 nm is (Given : h =
6.63 ×10−34 Js, NA = 6.02 × 1023 mol−1, c = JEE Main 2022 29th June Morning shift
3 × 108 m s−1) 56. Which of the following statements are
(a) 235 kJ mol−1 (b) 325 kJ mol−1 correct?
(c) 399 kJ mol−1 (d) 435 kJ mol−1 (A) The electronic configuration of Cr is [Ar]
3d5 4s1.
JEE Main 2022 (Online) 25th June Morning (B) The magnetic quantum number may have a
51. The pair, in which ions are isoelectronic with negative value.
AI3+ is : (C) In the ground state of an atom, the orbitals
(a) Br− and Be2+ (b) Cl− and Li+ are filled in order of their increasing energies.
(c) S2− and K+ (d) O2− and Mg2+ (D) The total number of nodes are given by n -2.
Choose the most appropriate answer from the
JEE Main 2022 (Online) 25th June Evening options given below :
52. The minimum energy that must be (a) (A), (C) & (D) only (b) (A) and (B) only
possessed by photons in order to produce the (c) (A) and (C) only (d) (A), (B) & (C)
photoelectric effect with platinum metal is :
[Given : The threshold frequency of platinum is JEE Main 2022 (Online) 29th June Evening
1.3 × 1015 s−1 and h = 6.6 × 10−34 J s.] 57. Which of the following is the correct plot for
(a) 3.21 × 10−14 J (b) 6.24 × 10−16 J the probability density ψ2 (r) as a function of
(c) 8.58 × 10−19 J (d) 9.76 × 10−20 J distance 'r' of the electron from the nucleus for
2s orbital?
JEE Main 2022 (Online) 26th June Evening
53. The number of radial and angular nodes in
4d orbital are, respectively
 (c) B < D < A < C (d) B < A < C < D

JEE Main 2022 (Online) 27th July Evening

(a) (b) 62. The correct decreasing order of energy for
the orbitals having, following set of quantum
numbers :
(A) n = 3, l = 0, m = 0 (B) n = 4, l = 0, m = 0
(C) n = 3, l = 1, m = 0 (D) n = 3, l = 2, m = 1 is :
(a) D > B > C > A (b) B > D >C > A
(c) C > B > D > A (d) B > C > D > A
(c) (d)
JEE Main 2022 (Online) 28th July Morning
63. Identify the incorrect statement from the
JEE Main 2022 (Online) 30th June Morning
58. The number of radial nodes and total following.
(a) A circular path around the nucleus in which
number of nodes in 4p orbital respectively are :
(a) 2 and 3 (b) 2 and 2 electron revolves is proposed as Bohr’ orbit.
(b) An orbital is the one electron wave function
(c) 3 and 4 (d) 4 and 4
in an atom.
JEE Main 2022 (Online) 25th July Morning (c) The existence of Bohr’s orbit is supported by
hydrogen spectrum.
59. Which of the following sets of quantum
(d) Atomic orbital is characterised by the
numbers is not allowed?
quantum numbers n and l only
(a) n = 3, l = 2, m1 = 0, s = +1/2
(b) n = 3, l = 2, m1 = –2, s = +1/2
(c) n = 3, l = 3, m1 = –3, s = –1/2 JEE Main 2022 (Online) 28th July Evening
64. Given below are two statements: One is
(d) n = 3, l = 0, m1 = 0, s = –1/2
labelled as Assertion A and the other is labelled
JEE Main 2022 (Online) 27th July Morning as Reason R
Assertion A : Zero orbital overlap is an out of
60. Given below are two statements. One is
phase overlap.
labelled as Assertion A and the 2s other is
Reason R : It results due to different orientation
labelled as Reason R.
/ direction of approach of orbitals.
Assertion A: Energy of 2s orbital of hydrogen
atom is greater than that of orbital of lithium. In the light of the above statements, choose the
correct answer from the options given below
Reason R: Energies of the orbitals in the same
(a) both A and R are true and reason is correct
subshell decrease with increase in the atomic
number. explanation of A
(b) both A and R are true and reason is not
In the light of the above statements, choose the
correct answer from the options given below. correct explanation of A
(c) A is true and R is false
(a) both A and R are true and reason is correct
(d) A is false and R is true
explanation of A
(b) both A and R are true and reason is not
JEE Main 2022 (Online) 29th July Evening
correct explanation of A
65. Given below are the quantum numbers for
(c) A is true and R is false
4 electrons.
(d) A is false and R is true
A. n = 3, l = 2, m1 = 1, s = +1/2
JEE Main 2022 (Online) 27th July Evening B. n = 4, l = 1, m1 = 0, s = +1/2
C. n = 4, l = 2, m1 = –2, s = –1/2
61. Outermost electronic configurations of four
D. n = 3, l = 1, m1 = –1, s = +1/2
elements A, B, C, D are given below :
(A) 3s2 (B) 3s23p1 The correct order of increasing energy is
(a) D < B < A < C (b) D < A < B < C
(C) 3s23p3 (D) 3s23p4
The correct order of first ionization enthalpy for (c) B < D < A < C (d) B < D < C < A
them is :
JEE Main 2023 24th January Morning Shift
(a) A < B < C < D (b) B < A < D < C
66. It is observed that characteristic X-ray
spectra of elements show regularity. When JEE Main 2023 30th January Evening Shift
frequency to the power "n" i.e. vn of X-rays 72. Maximum number of electrons that can be
emitted is plotted against atomic number "Z", accommodated in shell with n = 4 are:
following graph is obtained. (a) 50 (b) 32
(c) 72 (d) 16

JEE Main 2023 (Online) 31st January

73. Which transition in the hydrogen spectrum
would have the same wavelength as the Balmer
type transition from n=4 to n=
2 of He+2 spectrum
(a) n= 3 to n = 4 (a) n= 2 to n = 1
The value of 'n' is : (a) n= 1 to n = 2 (a) n= 1 to n = 3
(a) 1 (b) ½
(c) 2 (d) 3 JEE Main 2023 31st January Evening Shift
74. Arrange the following orbitals in decreasing
JEE Main 2023 24th January Morning Shift order of energy.
67. The magnetic moment of a transition metal A. n= 3, l = 0, m = 0
compound has been calculated to be 3.87 B.M. B. n= 4, l = 0, m = 0
The metal ion is C. n= 3, l = 1, m = 0
(a) Ti+2 (b) V+2 D. n= 3, l = 2, m = 1
(c) Cr+2 (d) Mn+2 The correct option for the order is :
(a) B > D > C > A (b) A > C >B > D
JEE Main 2023 24th January Evening Shift (c) D > B > A > C (d) D > B > C > A
68. The number of s-electrons present in an ion
with 55 protons in its unipositive state is JEE Main 2023 1st February Evening
(a) 10 (b) 9 75. Which one of the following sets of ions
(c) 12 (d) 8 represents a collection of isoelectronic species?
(a) N–3 , O–2, F– , S–2
JEE Main 2023 (Online) 25th January (b) Ba+2 , Sr+2, K+, Ca+2
69. The radius of the second orbit of Li+2 is x . (c) Li+, Na+, Mg+2, Ca+2
The expected radius of the orbit of Be+3 is (d) K+ , Cl–, Ca+2, Sc+3
(a) 16x/27 (b) 4x/9
(c) 9x/4 (d) 27x/16 JEE Main 2023 (Online) 6th April Evening
76. If the radius of the first orbit of hydrogen
JEE Main 2023 29th January Morning Shift atom is ao , then de Broglie's wavelength of
70. The shortest wavelength of hydrogen atom electron in 3rd orbit is
in Lyman series is . The longest wavelength is (a) 𝜋ao3/6 (b) 3 𝜋ao
Balmer series of He+ is (c) 6 𝜋ao (d) 𝜋ao3/3
(a) 36λ/5 (b) 5/9λ JEE Main 2023 (Online) 11th April Morning
(c) 9λ/5 (d) 5λ/9 77. Given below are two statements : one is
labelled as Assertion A and the other is labelled
JEE Main 2023 30th January Evening Shift as Reason R :
71. The wave function of 2s is given by Assertion A: In the photoelectric effect, the
electrons are ejected from the metal surface as
soon as the beam of light of frequency greater
than threshold frequency strikes the surface.
At r = ro , radial node is formed. Thus, ro in
Reason R: When the photon of any energy
terms of ao
strikes an electron in the atom, transfer of
(a) r0 = a0 (b) r0 = 4a0
(c) r0 = 2a0 (d) r0 = a0/2
energy from the photon to the electron takes (d) 1/27th times this value
place.
In the light of the above statements, choose the JEE Main 2023 (Online) 15th April Morning
most appropriate answer from the options 79. Given below are two statements:
given below : Statement I : According to Bohr's model of
(a) both A and R are true and reason is correct hydrogen atom, the angular momentum of an
explanation of A electron in a given stationary state is
(b) both A and R are true and reason is not quantised.
correct explanation of A Statement II : The concept of electron in
(c) A is true and R is false Bohr's orbit, violates the Heisenberg
(d) A is false and R is true uncertainty principle.
In the light of the above statements, choose the
JEE Main 2023 (Online) 13th April Morning most appropriate answer from the options
78. The energy of an electron in the first Bohr given below:
orbit of hydrogen atom is –2.18x 10-18 J . Its (a) Both Statement I and Statement II are false
energy in the third Bohr orbit is ____________. (b) Both Statement I and Statement II are true
(a) one third of this value (c) Statement I is false but Statement II is true
(b) three times this value (d) Statement I is true but Statement II is false
(c) 1/9th times this value

ANSWER KEY
DPP–2 ATOMIC STRUCTURE

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A C A C A A D C D C C D B D D B A A C B
21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40
D B A D B A B D C C C D B D D A B A D B
41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
B A A D B D D C B C D C A B C D B A C A
61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80
B A D A B B B A D C C B B D D C C C B
Integral type questions
JEE Main 2021 (Online) 24th February
1. A proton and a Li3+ nucleus are accelerated by the same potential. If λLi and λp denote the de Broglie
wavelengths of Li3+ and proton respectively, then the value of λLi/λp is x × 10-1. The value of x is ______.
(Rounded off to the nearest integer) [Mass of Li3+ = 8.3 mass of proton]

JEE Main 2021, 26th February Evening

2. A ball weighing 10 g is moving with a velocity of 90 ms−1. If the uncertainty in its velocity is 5%,
then the uncertainty in its position is ___ × 10−33 m. (Rounded off to the nearest integer) [Given : h =
6.63 × 10−34 Js

JEE Main 2021 (Online) 16th March Morning 3. When light of wavelength 248 nm falls on a metal of
threshold energy 3.0 eV, the de-Broglie wavelength of emitted electrons is _______Å. (Round off to the
Nearest Integer).

JEE Main 2021 (Online) 16th March Evening 4. The number of orbitals with n = 5, m1 = +2 is
___________. (Round off to the Nearest Integer).

JEE Main 2021 (Online) 17th March Morning 5. A certain orbital has n = 4 and mL = −3. The number
of radial nodes in this orbital is ____________. (Round off to the Nearest Integer).

JEE Main 2021 (Online) 17th March Evening

6. In the ground state of atomic Fe(Z = 26), the spin-only magnetic moment is ____________ × 10−1 BM.
(Round off to the Nearest Integer). [Given : √3 = 1.73, √2 = 1.41 ]

JEE Main 2021 (Online) 20th July Morning

7. The Azimuthal quantum number for the valence electrons of Ga+ion is __0_________. (Atomic number
of Ga = 31)

JEE Main 2021 (Online) 22th July Evening

8. Number of electrons that Vanadium (Z = 23) has in p-orbitals is equal to ________

JEE Main 2021 (Online) 25th July Morning

9. A source of monochromatic radiation of wavelength 400 nm provides 1000 J of energy in 10 seconds.
When this radiation falls on the surface of sodium, x × 1020 electrons are ejected per second. Assume
that wavelength 400 nm is sufficient for ejection of electron from the surface of sodium metal. The value
of x is_______. (Nearest integer) (h = 6.626 × 10−34 Js)

JEE Main 2021 (Online) 25th July Evening

10. An accelerated electron has a speed of 5 × 106 ms−1 with an uncertainty of 0.02%. The uncertainty
in finding its location while in motion is x × 10−9 m. The value of x is ________. (Nearest integer) [Use mass
of electron = 9.1 × 10−31 kg, h =6.63 × 10−34 Js, π = 3.14]

JEE Main 2021 (Online) 26th August Evening

11. A metal surface is exposed to 500 nm radiation. The threshold frequency of the metal for
photoelectric current is 4.3 × 1014 Hz. The velocity of ejected electron is ______ × 105 ms−1(Nearest
integer) [Use : h = 6.63 × 10−34 Js, me = 9.0 × 10−31 kg]

JEE Main 2021 (Online) 27th August Morning

12. The kinetic energy of an electron in the second Bohr orbit of a hydrogen atom is equal to h2/xma02.
The value of 10x is ______. (a0 is radius of Bohr's orbit) (Nearest integer) [Given : π = 3.14]
JEE Main 2021 (Online) 27th August Evening
13. The number of photons emitted by a monochromatic (single frequency) infrared range finder of
power 1 mW and wavelength of 1000 nm, in 0.1 second is x × 1013. The value of x is _______. (Nearest
integer) (h = 6.63 × 10−34 Js, c = 3.00 × 108 ms−1)

JEE Main 2021 (Online) 31st August Morning

14. Ge(Z = 32) in its ground state electronic configuration has x completely filled orbitals with ml = 0.
The value of x is ________.

JEE Main 2021 (Online) 31st August Evening

15. The value of magnetic quantum number of the outermost electron of Zn+ ion is _______.

JEE Main 2021 (Online) 1st September

16. A 50 watt bulb emits monochromatic red light of wavelength of 795 nm. The number of photons
emitted per second by the bulb is x ×1020. The value of x is _______. [Given : h = 6.63 × 10−34 Js and c =
3.0 × 108 ms−1]

JEE Main 2022 (Online) 25th June Morning

17. The longest wavelength of light that can be used for the ionisation of lithium atom (Li) in its ground
state is x × 10−8 m. The value of x is ___________. (Nearest Integer).
(Given : Energy of the electron in the first shell of the hydrogen atom is −2.2 × 10−18 J ; h = 6.63 × 10−34 Js
and c = 3 × 108 ms−1)

JEE Main 2022 (Online) 27th June Morning

18. If the uncertainty in velocity and position of a minute particle in space are, 2.4 × 10−26 (m s−1) and
10−7 (m) respectively. The mass of the particle in g is ____________. (Nearest integer)
(Given : h = 6.626 × 10−34 Js)

JEE Main 2022 (Online) 28th June Morning

19. If the work function of a metal is 6.63 × 10−19J, the maximum wavelength of the photon required to
remove a photoelectron from the metal is ____________ nm. (Nearest integer)
[Given : h = 6.63 × 10−34 J s, and c = 3 × 108 m s−1]
ANSWER KEY
Integral type questions
1 2 3 4 5 6 7 8 9 10
2 1 9 3 0 49 0 12 2 58
11 12 13 14 15 16 17 18 19
5 3155 50 7 0 2 4 22 300