1 The binding energy of the electron in the lowest orbit of the hydrogen atom is 13.6 eV.

The energies
required in eV to remove an electron from three lowest orbits of the hydrogen atom are :
(A) 13.6, 6.8, 8.4 eV (B) 13.6, 10.2, 3.4 eV (C) 13.6, 27.2, 40.8 eV (D) 13.6, 3.4, 1.5 eV.

2. The ratio of nucleons in O16 and O18 is :

(A) 8/9 (B) 4/5 (C) 9/8 (D) 1

3. The ratio of the radius difference between 4th and 3rd orbit of H-atom and that of Li2+ ion is :
(A) 1 : 1 (B) 3 : 1 (C) 3 : 4 (D) 9 : 1

4. The velocity of an e– in excited state of H-atom is 1.093 ×106 m/s. What is the circumference of this orbit ?
(A) 3.32 × 10–10 m (B) 6.64 × 10–10 m (C) 13.30 × 10–8 cm (D) 13.28 × 10–6 cm

5. Column-I and Column-II contains four entries each. Entries of Column-I are to be matched with some
entries of Column-II. One or more than one entries of Column-I may have the matching with the same
entries of Column-II.
Column-I Column-II
(A) No. of orbitals in the n shell
th
(p) 2(2 + 1)
(B) Max. no. of electrons in a subshell (q) n
(C) No. of subshells in nth shell (r) 2 +1
(D) No. of orbitals in a subshell (s) n2
(A) (A) - (p) ; (B) - (s) ; (C) - (q) ; (D) - (r) (B) (A) - (s) ; (B) - (p) ; (C) - (r) ; (D) - (q)
(C) (A) - (s) ; (B) - (p) ; (C) - (q) ; (D) - (r) (D) (A) - (s) ; (B) - (q) ; (C) - (p) ; (D) - (r)
6. STATEMENT-1 : An orbital cannot have more than two electrons and they must have opposite spins.
STATEMENT-2 : No two electrons in an atom can have same set of all the four quantum numbers as per
Pauli’s exclusion principle.
(A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.
(B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1.
(C) Statement-1 is True, Statement-2 is False.
(D) Statement-1 is False, Statement-2 is True.

7. Among the following representations of excited states of atoms which is impossible ?

(A) 1s1 2s1 (B) [Ne]3s23p34s1 (C) 1s22s22p43s2 (D) [Ne]3s23p64s33d2
8. The e/m ratio is maximum for :
(A) D+ (B) He+ (C) H+ (D) He2+
9. The positive charge of an atom is
(A) Spread all over the atom (B) Distributed around the nucleus
(C) Concentrated at the nucleus (D) All of these
10. Which of the following sets of quantum numbers describes the electron which can be removed most easily
from a potassium atom in its ground state ?
1 1
(A) n = 3,  = 1, m = 1, ms = – (B) n = 2,  = 1, m = 0, ms = –
2 2

1 1
(C) n = 4,  = 0, m = 1, ms = + (D) n = 4,  = 0, m = 0, ms = +
2 2