Subject : Chemistry Class : XI Topic : Atomic Structure DPP : 01 to 10

DPP : 01
1. Find no. of electrons, protons and neutrons in given atoms/ions –
Atoms/Ions Electron Proton Neutron
4
(A) 2 He
(B) 11 H
(C) 12
6 C
17
(D) 8 O
22
(E) 10 Ne
(F) 7 N 3
14

37
(G) 17 Cl1
23
(H) 11 Na1

2. The total number of electrons in a nitrate ion is :(NO3–)

(A) 31 (B) 62 (C) 32 (D) 63

3. The mass of a neutron is .................... than the mass of a proton.

(A) slightly less (B) slightly more
(C) exactly equal (D) their masses cannot be compared

4. Which of the following are isoelectronic ?

(I) CH3+ (II) H3O+ (III) NH3 (IV) CH3–
(A) I and III (B) III and IV (C) I and II (D) II, III and IV

5. Atom consist of electrons, protons and neutrons. If the mass attributed to neutron were halved and that
attributed to the electrons were doubled, the atomic mass of 6C12 would be approximately :
(A) Same (B) Doubled (C) Halved (D) Reduced by 25%

6. The ratio between the neutrons present in carbon and silicon.

(A) 3 : 7 (B) 3 : 14 (C) 6 : 7 (D) None

7. The ratio of specific charge (e/m) of a proton to that of an -particle is :

(A)1 : 4 (B) 1 : 2 (C) 1 : 1/4 (D) 2 : 1

8. There are 11 protons and 12 neutrons in the nucleus of an atom. Find the atomic number (Z), mass number (A),
number of electrons and the symbol of the element.

9. Which has highest e/m ratio ?

(A) He2+ (B) H+ (C) He+ (D) H

10. Mass of neutron is..................times the mass of electron.

(A) 1840 (B) 1480 (C) 2000 (D) 3000

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 DPP : 02
1. Isotopes are possible due to differene no of
(A) Electrons (B) Protons (C) Neutrons (D) None
2. Which of the following has more electrons than neutrons
(A) C (B) F  (C) O 2 (D) Al 3
3. Compared with an atom of atomic weight 12 and atomic number 6, the atom of atomic weight 13 and atomic number 6
(A) Contains more neutrons (B) Contains more electrons
(C) Contains more protons (D) Is a different element
4. In the nucleus of 20 Ca 40 there are
(A) 40 protons and 20 electrons (B) 20 protons and 40 electrons
(C) 20 protons and 20 neutrons (D) 20 protons and 40 neutrons
5. Which of the following are isoelectronic with one another :
(A) Na+ and Ne (B) K+ and O (C) Ne and O (D) Na+ and K+
6. Order of ratio of volumes of nucleus and atom :
(A) 105 (B) 10–5 (C) 1015 (D) 10–15
7. Radius of nucleus of Fe and Li are in ratio :
(A) 3/28 (B) 1/2 (C) 2 (D) 28/3
COMPERHENSION :

The approximate size of the nucleus can be calculated by using energy conservation theorem in Rutherford’s -
scattering experiment. If an -particle is projected from infinity with speed v, towards the nucleus having z
protons then the -particle which is reflected back or which is deflected by 1800 must have approach closest
to the nucleus. It can be approximated that -particle collides with the nucleus and gets back. Now if we apply
the energy conservation equation at initial point and collision point then :
(Total Energy)initial = (Total Energy)final
(K.E.)i + (P.E.)i = (K.E.)f + (P.E.)f
(P.E.)i = 0, since P.E. of two charge system separated by infinite distance is zero, finally the particle stops and
then starts coming back.
1 Kq q
mv2 + 0 = 0 + 1 2
2 R
1 2e  ze 4Kze 2
 m v 2=K  R= m v 2
2   R  

Thus the radius of nucleus can be calculated using above equation. The nucleus is so small a particle that we
can’t define a sharp boundary for it. Experiments show that the average radius R of a nucleus may be written
as
R = R0(A)1/3
where R0 = 1.2 × 10–15 m
A – mass number ; R – radius of nucleus

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8. If the diameter of two different nuclei are in the ratio 1:2 then their atomic mass number are in the ratio :
(A) 1:2 (B) 8:1 (C) 1:8 (D) 1:4

9. If -particle with speed v0 is projected from infinity and it approches upto r0 distance from the nuclei. Then the
speed of -particle which approches upto 2r0 distance from the nucleus is
v0 v
(A) 2 v 0 (B) (C) 2v0 (D) 0
2 2

10. Radius of a particular nucleus is calculated by the projection of -particle from infinity at a particular speed let
this radius is the true radius. If the radius calculation for the same nucleus is made by -particle with half of the
earlier speed, then the percentage error involved in the radius calculation is :
(A) 75% (B) 100% (C) 300% (D) 400%

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 DPP : 03
1. How many photons of light of 7000 Å wavelength are equivalent to 1 J of energy ?
(A) 3.52 × 1018 (B) 2.0 × 1020 (C) 3.52 × 1022 (D) 1.52 × 1019

2. Find out the number of photons emitted by a 60 watt bulb in one second, if wavelength of an emitted photon is
620 nm.

3. MRI (Megnetic resonance image) body scanner, being used in hospital works a 400 MHz radio frequency.
Wavelength associated with this radio frequency is: (1 MHz = 106 Hz)
(A) 0.75 m (B) 0.75 cm (C) 1.5 m (D) 2 cm

4. Ratio of energies of radiations have wavelength 2000 Å and 4000 Å is :

(A) 1 / 4 (B) 4 (C) 1 / 2 (D) 2

5. Number of photons emitted by a bulb of 40 watt in 1 minute with 50% efficiency will be approximately
( = 6200 Å, hc = 12400 eV Å, 1eV = 1.6 × 10–19 J )
(A) 7.5 × 1020 (B) 3.75 × 1020 (C) 3.75 × 1019 (D) 3.75 × 1021

6. Bond energy of Br2 is 198 kJ mole–1. The minimum wave number of photons required to break this bond is (h
= 6.62 x 10–34 Js, c = 3 x 108 m/s)
(A) 1.458 × 1023 m–1 (B) 1.67 × 106 m–1 (C) 4.86 × 1014 m–1 (D) 1.45 × 107 m–1

7. A certain dye absorbs light of  = 3100 Å and then fluorescence light of 6200 Å. Assuming that under given
conditions 75% of the absorbed energy is re-emitted out as fluorescence, calculate the ratio of number of
quanta emitted out to the number of quanta absorbed.

8. A radio station broadcasts programme over 100 MHz frequency. If distance between receiver and radio
station is 300 km then how much time will signal take to reach the receiver.

9. A gas emits two photons after absorbing a photons of 300 nm. If wavelength of one of these photons is 500 nm
then waveleght of other photon is:

10. If internal part of human eye needs 10–17 J energy to see an object. Then how many photons of green light (
= 495 nm) are needed to provide this energy.

11. How many photons of frequency 300 Hz are required to boil 100 gm water from 40º to 60º. If 4.2 J energy is
required to boil 1g water by 1°C.

12. What change in molar energy in joule would be associated with an atomic transition giving rise to radiation of
1 Hz ? (h = 6.626 × 10–34 J.sec)

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 DPP : 04
1. Work function of a metal plate is defined as
(A) the minimum energy required to eject out an electron from the metal surface
(B) the energy of photon at which maximum energy electron is emitted
(C) the energy of photon at which no electron is emitted
(D) none of these

2. The therehold frequency 0 for a metal is 6 × 1014 s–1. Calculate the kinetic energy of an electron emitted when
radiation of frequency  = 1.1 × 1015 s–1 hits the metal.
(A) 3.3 × 10–21 J (B) 3.3 × 10–19 J (C) 1.3 × 10–21 J (D) 2.3 × 10–20 J

3. When electromagnetic radiation of wavelength 310 nm fall on the surface of Sodium, electrons are emitted with
K.E. = 1.5 eV. Determine the work function (W0) of Sodium.
(A) 1.5 eV (B) 2.5 eV (C) 3.5 eV (D) 2.0 eV

4. The energy required to remove an electron from metal X is E = 3.31 × 10–20 J. Calculate the maximum
wavelength of light that can photoeject an electron from metal X.
(A) 4 m (B) 6 m (C) 7 m (D) 5 m

5. The work function for a metal is 4 eV. To emit a photo-electron of zero velocity from the surface of the
metal, the wavelength of incident light should be :
(A) 2700 Å (B) 1700 Å (C) 5900 Å (D) 3100 Å

6. The dissociation energy of H2 is 150 kJ mol–1. If H2 is exposed to light energy of wavelength

500 nm, what % of light energy will be converted into kinetic energy ?

COMPERHENSION :
In the photoelectric effect, an incoming photon brings a definite quantity of energy, h. It collide with an electron
close to the surface of the metal target, and transfers its energy to it. The minimum energy required to eject a
photo electron called work function (). The difference between the work function () and the incident energy
(h) appears as the kinetic energy of the ejected electron. K Max = h( – 0) where is the threshold frequency
1
K.Emax = mu2 = h – h0 Where u is the speed of the ejected electrons
2

7. If work function of potassium metal is 2.5 eV then calculate the maximum wavelength of incident light which
can cause ejection of photoelectron from pottassium metal ?
(A) 496 nm (B) 4960 nm (C) 3960 nm (D) 396 nm

8. If incident light of wavelength 310 nm is irradiated on metal (work function = 3eV) then find out the kinetic
energy of ejected photoelectron :
(A) 2 eV (B) 1 eV (C) 4 eV (D) 3 eV
9. Choose the correct statement regarding photoelectric effect :
(A) If frequency of incident light is doubled, then K.E. of ejected photoelectrons will also be doubled.
(B) Work function of the metal will be doubled if the frequency of incident light is doubled.
(C) Work function of a metal is a constant and is the characteristic of a metal.
(D) The speed of an ejected electron will never vary with the frequency of incident light.

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 DPP : 05

1. For which of the following species, Bohr model is not valid :

(A) He+ (B) H (C) Li2+ (D) H+

2. If the radius of the first Bohr orbit of the H atom is r, then for the Li2+ ion it will be :
(A) 3r (B) 9r (C) r/3 (D) r/9

3. In a certain electronic transition in the hydrogen atom from an initial state i to a final state f, the difference in the
orbit radius (ri  rf) is seven times the Bohr radius. Identify the transition.
(A) 4  1 (B) 4  2 (C) 4  3 (D) 3  1

4. If radius of second stationary orbit (in Bohr's atom) is R. Then radius of third orbit will be
(A) R/3 (B) 9R (C) R/9 (D) 2.25R

5. The ratio of radius of two different orbits in a H-atom is 4 : 9, then the ratio of the frequency of revolution of
electron in these orbits is :
(A) 2 : 3 (B) 27 : 8 (C) 3 : 2 (D) 8 : 27

6. The velocity of electron in the ground state of H atom is 2.185 × 108 cm/sec. The velocity of electron in the
second orbit of Li2+ ion in cm/sec would be
(A) 3.276 × 108 (B) 2.185 × 108 (C) 4.91 × 108 (D) 1.638 × 108

7. According to Bohr’s theory, the ratio of electrostatic force of attraction acting on electron in 3rd orbit of He+ ion
x
3
and 2nd orbit of Li2+ ion is  2  , then the value of x is :
 
(A) 7 (B) –6 (C) 6 (D) –7
8. The potential energy of the electron present in the ground state of Li2+ ion is represented by:
3e 2 3e 3e 2 3e 2
(A)  4  0 r
(B)  4  r (C)  4  0 r 2
(D)  4  0 r
0

9. The energy levels for ZA+(z – 1) can be given by:

(A) En for A(+z1) = Z2 x En for H (B) En for A(+z1) = Z x En for H
(C) En for A (+z1) 2
= 1/Z x En for H (D) En for A(+z1) = 1/Z x En for H

10. The radii of two of the first four Bohr’s orbits of the hydrogen atom are in the ratio 1 : 4. The energy difference
between them may be:
(A) Either 12.09 eV or 3.4 eV (B) Either 2.55eV or 10.2 eV
(C) Either 13.6 eV or 3.4 eV (D) Either 3.4eV or 0.85 eV

2h
11. If the angular momentum of an electron in a Bohr orbit is , then the value of potential energy of electron

present in He+ ion is :
(A) – 13.6 eV (B) – 3.4 eV (C) – 6.8 eV (D) – 27.2 eV.

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12. The ratio of the difference in energy between the first and second Bohr orbit to that between the second and
third Bohr orbit in a H-like species is
1 1 4 27
(A) (B) (C) (D)
2 3 9 5

13. The kinetic energy of an electron in a particular orbit in H atom is 3.4 eV. The angular momentum of electron in
this orbit is :
h h 3h 2h
(A) 2
(B) 
(C) 2
(D) 

14. The ratio of (E2 – E1) to (E4 – E3) for He+ ion is approximately equal to (where En is the energy of nth orbit)
(A) 10 (B) 15 (C) 17 (D) 12

15. En = total energy, n = angular momentum, Kn = K.E. , Vn = P.E.

Tn = time period, rn = radius of nth orbit
Column () Column ()
–y 1
(A) En  rn /z, then y is (p)
2
(B) n  nx ,then x is (q) – 2
En
(C) V (r) – 3
n

zt
(D) Tn  , t & m are respectively (s) 1
nm

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 DPP : 06

1. If the binding energy of 2nd excited state of a hypothetical atom is 12 eV, then :
(A) I excitation potential = 81 V (B) II Excitation energy = 96 eV
(C) Ionisation potential = 192 V (D) Binding energy of 2nd state = 27 eV

2. The IP1 of H is 13.6 V. It is exposed to electromagnetic waves of 1028 Å and gives out induced
radiations. Find the wavelength of these induced radiations.
3. Wave number of a spectral line for a given transition is x cm–1 for He+, then its value for Be3+
(isoelectronic of He+) for same transition is :
x
(A) x cm–1 (B) 4x cm–1 (C) cm–1 (D) 2x cm–1
4

4. The ionisation energy of He+ is 19.6 × 10–18 J per ion. Calculate the energy of the first stationary state of Li2+.

5. For the Hydrogen spectrum, last line of the Lyman series has frequency 1 , last line of Lyman series of
He+ ion has frequency  2 and 1st line of Lyman series of He+ ion has frequency  3 then
(A) 4 1 =  2 +  3 (B) 1 = 4  2 +  3 (C)  2 =  3 – 1 (D)  2 = 1 +  3

6. Wavelength of radiations emitted when an electron jumps from a state A to C is 2000 Å and it is 6000 Å when
the electron jumps from state B to state C. Wavelength of the radiations emitted when an electron jumps from
state A to B will be
(A) 2000 Å (B) 3000 Å (C) 4000 Å (D) 6000 Å

3RC
7. A photon of frequency cannot be emitted from which of the following transitions :
4
(Given : R = Rydberg's constant, C = speed of light)
(A) 5  1 transition in a sample of H– atom. (B) 6  1 transition in a sample of He+ ion.
(C) 7  3 transition in a sample of Li2+ ion. (D) 8  3 transition in a sample of He+ ion.

Passage :
The only electron in the hydrogen atom resides under ordinary conditions on the first orbit. When energy is
supplied, the electron moves to higher energy orbit depending on the amount of energy absorbed. When this
electron returns to any of the lower orbits, it emits energy. Lyman series is formed when the electron returns to
the lowest orbit while Balmer series is formed when the electron returns to second orbit. Similarly, Paschen,
Brackett and Pfund series are formed when electron returns to the third, fourth and fifth orbits from higher
energy orbits respectively (as shown in figure)

n(n  1)
Maximum number of lines produced when an electron jumps from nth level to ground level is equal to .
2
For example, in the case of n = 4, number of lines produced is 6. (4  3, 4  2, 4  1, 3  2, 3  1, 2  1).
When an electron returns from n2 to n1 state, the number of lines in the spectrum will be equal to

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 (n2  n1 )(n2  n1  1)
2
If the electron comes back from energy level having energy E2 to energy level having energy E1, then the
difference may be expressed in terms of energy of photon as :
hc
E2 – E1 = E ,   , E = h ( - frequency)
E
Since h and c are constants, E corresponds to definite energy; thus each transition from one energy level to
another will produce a light of definite wavelength. This is actually observed as a line in the spectrum of
hydrogen atom.
 1 1
Wave number of line is given by the formula   RZ 2  2  2  .
 n1 n2 
where R is Rydberg constant (R = 1.1 × 107 m–1)
(i) First line of a series : It is called ‘line of longest wavelength’ or ‘line of lowest energy’.
(ii) Series limit or last line of a series : It is the line of shortest wavelength or line of highest energy.

8. In a hydrogen like sample, electrons are in a particular excited state. If electrons make transition upto 1st
excited state, then it produces maximum 15 different types of spectral lines, then electrons were in
(A) 5th state (B) 6th state (C) 7th state (D) 8th state

9. The difference between the wave number of 1st line of Balmer series and last line of Paschen series for
Li2+ ion is
R 5R R
(A) (B) (C) 4R (D)
36 36 4

10. In a single isolated atom of hydrogen, electrons make transition from 4th excited state to ground state
producing maximum possible number of wavelengths. If the 2nd lowest energy of these lines is used to
further excite an already excited sample of Li2+ ion, then transition will be
(A) 12  15 (B) 9  12 (C) 6  9 (D) 3  6

11. Column – I Column – II

Name of series Series limit for H atom ( max )
(A) Lyman series (p) R/36
(B) Balmer series (q) R
(C) Pfund series (r) R/4
(D) Hymphry series (s) R/25

16 x
12. The largest wavelength in Paschen series of Li+2 is 9
. The largest wavelength of Balmer series in He+ is :
5x
(A) x (B) 1.2 x (C) 1.4 x (D) 9

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 DPP : 07
1. An energy of 40.8 eV is required to excite a hydrogen like specie from 1st Bohr orbit to second.
Which is/are correct statement(s) :
(A) Atomic number of H-like specie is 2
(B) Ionisation energy of H-like specie is 122.4 eV
(C) Kinetic energy of electron in 1st orbit is – 54.4 eV
(D) Energy of second orbit is –13.6 eV

2. Statement-1 : In Li2+ sample, an electron make transition from higher state to n = 2. Then the photon observed
will fall in the visible range.
Statement-2 : Line falling in n = 2 is Balmer series line, which may belong to visible range in H-atom.
(A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.
(B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1
(C) Statement-1 is True, Statement-2 is False
(D) Statement-1 is False, Statement-2 is True

Comprehension
In H–spectrum, we get several spectral lines in different region like UV, visible and IR. The wavelengths of
different spectral ines in a particular series are different and can be calculated by using Rydberg’s formula.
1 1 1
=  = RZ2  n 2  n 2 
  1 2

7 –1
where, R = 1.1 x 10 m
In a particular series lines are very close to each other. In addition to this the energy gap between two energy levels
are going is decrease from lower energy level to higher energy levels (as the values of n1 and n2 increases).

3. A sample of H–like ion is in a particular excited state n2. The electron in it makes back transition upto a lower
excited state n1 producing a maximum of 10 different spectral lines. The change in angular momentum of electron
h
corresponding to maximum frequency line is expressed as y J-s, then the value of y is.
4
(A) 2 (B) 4 (C) 8 (D) 6

4. In a sample of H–atom, electron makes transition from lower state n1 to higher state n2 by absorbing photons
emitted by another sample of Li2+ ions from 12  3 transition. The electron in H–atom then makes back
transition from state n2 to ground state by emitting all posible photons, then the number of lines in infrared region
in emission spectrum of H–atom sample is :
(A) 3 (B) 2 (C) 1 (D) 0

5. What would be the maximum number of emission lines for atomic hydrogen that you would expect to see
with the naked eye if the only electronic energy levels involved are those as shown in the Figure?

(A) 4 (B) 6 (C) 5 (D) 15

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6. List-I List-II
(A) n = 6  n = 3 (In H-atom) (p) 10 lines in the spectrum
(B) n = 7  n = 3 (In H-atom) (q) Spectral lines in visible region
(C) n = 5  n = 2 (In H-atom) (r) 6 lines in the spectrum
(D) n = 6  n = 2 (In H-atom) (s) Spectral lines in infrared region

7. Column (I) Column (II)

(A) Binding energy of 5th excited state Li++ sample (p) 10.2 V
(B) st excitation potential of H-atom (q) 3.4 eV
(C) 2nd excitation potential of He+ (r) 13.6 eV
(D) I.E. of H-atom (s) 48.4 V

8. In a hydrogen like sample, electron is in 2nd excited state. The binding energy of 4th state of this sample is
13.6 eV, then :
(A) A 25 eV photon can set free the electron from the second excited state of this sample.
(B) 3 different types of photon will be observed if electrons make transition up to ground state from the
second excited state
(C) If 23 eV photon is used, then K.E. of the ejected electron is 1 eV.
(D) 2nd line of Balmer series of this sample has same energy value as that of 1st excitation energy of H-atom.

9. In He+ ion sample electrons make transition from 5th excited state to 2nd state only, all different types of
photons are observed. Then change in angular momentum of electrons producing 3rd highest energy photon is
how much times of angular momentum of electron in first orbit.

10. Suppose a hypothetical atom produces a blue, yellow, red and violet line in emission spectrum. match the
above lines with their corresponding possible electronic transition :
Colour of spectral lines Possible corresponding transitions
(i) Blue (p) 6  3
(ii) Yellow (q) 2  1
(iii) Red (r) 5  2
(iv) Violet (s) 4  3
(A) (i)  r , (ii)  p , (iii)  s , (iv)  q (B) (i)  r , (ii)  s , (iii)  q, (iv)  p
(C) (i)  p , (ii)  r , (iii)  s , (iv)  q (D) (i)  p , (ii)  r , (iii)  q, (iv)  s

11. An -particle has initial kinetic energy of 50 eV and it is accelerated through the potential difference of 150
volt. If a proton has initial kinetic energy of 25 eV and it is accelerated through the potential difference of 25
volt then find the ratio of the wavelength associated with the proton and the -particle as nearest integer.

12. Zeeman effect refers to the :

(A) Splitting up of the lines in an emission spectrum in a magnetic field
(B) Splitting up to the lines in an emission spectrum in the presence of an external electrostatic field
(C) Emission of electrons from metals when light falls upon them
(D) Random scattering of light by colloidal particles

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 DPP : 08
1. Determine the de-Broglie wavelength associated with an electron in the 3rd Bohr's orbit of He+ ion?
(A) 10 Å (B) 2 Å (C) 5 Å (D) 1 Å

2. If numerical value of mass and velocity are equal then de-Broglie wavelength in terms of K.E. is :
mh h
(A) (B) (C) both are correct (D) none is correct.
2K.E. 2K.E.

3. In which of the following transition, change in De Brogli wavelength is maximum-

(A) n = 8  n = 6 (B) n = 5  n = 4 (C) n = 3  n = 2 (D) n = 2  n = 1

Comprehension :
The French physicist Louis de Broglie in 1924 postulated that matter, like radiation, should exhibit a dual
behaviour. He proposed the following relationship between the wavelength  of a material particle, its linear
h h
momentum p and planck constant h.  = p =
m
The de Broglie relation implies that the wavelength of a particle should decrease as its velocity increases. It also
implies that for a given velocity heavier particles should have shorter wavelength than lighter particles.
The waves associated with particles in motion are called matter waves or de Broglie waves. These waves differ
from the electromagnetic waves as they
(i) have lower velocities
(ii) have no electrical and magnetic fields and
(iii) are not emitted by the particle under consideration.
The experimental confirmation of the de Broglies relation was obtained when Davisson and Germer, in 1927,
observed that a beam of electrons is diffracted by a nickel crystal. As diffraction is a characteristic prop-
erty of waves, hence the beam of electron behaves as a wave, as proposed by de broglie.

4. If proton, electron and -particle are moving with same kinetic energy then the order of their de-Broglie’s
wavelength.
(A )P > e >  (B)  > P > e (C)  < P < e (D) e = P < 

5. For the same value of de-broglie wavelength of electron as in second orbit of H, the value of orbit number for
He+ ion will be :
(A) 4 (B) 3 (C) 2 (D) 1

6. De-Broglie wavelength of an electron travelling with speed equal to 1% of the speed of light
(A) 400 pm (B) 120 pm (C) 242 pm (D) 375 pm

7. A small ball of mass 6.62 gm is moving with the velocity 100 m/s then the wavelength associated with the ball is :

(A) 10–36 m (B) 10–33 m (C) 10–31 m (D) can't be calculated

8. If uncertainty in momentum is twice the uncertainty in position of an electron, then uncertainty in velocity of
h
electron is : [ = ]
2
1 h 1 1
(A)  (B) (C) h (D) 
2m 4m 4m m

9. Alveoli are the tiny sacs of air in the lungs whose average diameter is 50 pm. Consider an oxygen molecule
trapped within a sac. Calculate uncertainty in the velocity of oxygen molecule ?
(A) 1.98 × 10–2 ms–1 (B) 19.8 ms–1 (C) 198 × 10–4 ms–1 (D) 19.8 × 10–6ms–1

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10. Uncertainity in the position of an electron (mass 9.1  10–31 kg) moving with a velocity 300 ms–1, accurate upto

0.01% will be : ( 2m = 5.8  10–5)
e
(A) 1.92 m (B) 0.576 m (C) 0.384 m (D) 0.192 m

11. An electron is accelerated from rest and it has wavelength of 1.41 Å. By how much amount should potential be
dropped so that wavelength associated with electron becomes 1.73 Å :
(A) 25 V (B) 50 V (C) 75 V (D) 12.5 V

12. Calculate ratio of de-Broglie wavelength for a proton and -particle if their K.E. are same.

13. Calculate ratio of wavelength for an proton and -particle if they are accelerated through same potential V :

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 DPP : 9

1. Which of the following orbital does not make sense?

(A) 3d (B) 3f (C) 5p (D) 7s.
2. The maximum number of electrons in s, p and d-subshells are :
(A) 2 in each (B) 2, 6 and 6 (C) 2, 6 and 10 (D) 2, 6 and 12.
3 The total number of subshells in nth main energy level are :
(A) n2 (B) 2n2 (C) (n–1) (D) n.
4. Any p-orbital can accommodate up to :
(A) four electrons (B) two electrons with parallel spin
(C) six electrons (D) two electrons with opposite spin.
5. Which d -orbital does not have four lobes?
(A) d x 2 – y 2 (B) dxy (C) dyz (D) dz2
Comprehension :
Azimuthal quantum number (l) : It describes the shape of electron cloud and the number of subshells in a shell.
* It can have values from 0 to (n – 1)
* value of  0 1 2 3
subshell s p d f
* Number of orbitals in a subshell = 2 + 1
* Orbital angular momentum L =   (  1)
Magnetic quantum number (m) : It describes the orientations of the subshells. It can have values from –l to + l including
zero, i.e., total (2l + 1) values. Each value corresponds to an orbital. s-subshell has one orbital, p-subshell three
orbitals (px, py and pz), d-subshell five orbitals (dxy , dyz , dzx , d x 2  y 2 , dz 2 ) and f-subshell has seven orbitals.
Spin quantum number (s) : It describes the spin of the electron. It has values +1/2 and –1/2 signifying clockwise
spinning and anticlockwise rotation of electron about its own axis.
h 1
Spin of the electron produces angular momentum equal to S = s(s  1) where s = + .
2 2
n n
Total spin of an atom =  or  , where n is the number of unpaired electron.
2 2
The magnetic moment of an atom, s = n (n  2 ) B.M.

6. A d-block element has total spin value of +3 or –3, then the magnetic moment of the element is
approximately:
(A) 2.83 B.M. (B) 3.87 B.M. (C) 5.9 B.M. (D) 6.93 B.M.
x
7. Magnetic moment of 25 Mn is 15 B.M then the value of x is :
(A) 1 (B) 2 (C) 3 (D) 4

8. Magnetic moment of 26Fe2+ ion is same as

(A) 26Fe (B) 24Cr2+ (C) 28Ni4+ (D) All of these
h
9. Orbital angular momentum of an electron is 3 , then the number of orientations of this orbital in space are

(A) 3 (B) 5 (C) 7 (D) 9

10. The correct order of the magnetic moment of [25Mn, 24Cr, 26Fe] is :
(A) Cr < Mn < Fe (B) Cr > Mn > Fe
(C) Cr = Mn > Fe (D) Cr = Mn < Fe

11. The correct order of the magnetic moment of [25Mn4+, 24Cr3+, 26Fe3+] is :
(A) Fe3+ > Cr+3 = Mn4+ (B) Fe3+ > Cr3+ > Mn4+
(C) Cr3+ = Mn4+ > Fe3+ (D) Fe3+ > Mn+4 > Cr3+
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 DPP : 10

1. If magnetic moment of Xn+ (Z = 26) is 24 BM than number of unpaired e- and n -

(A) 4,2 (B) 2,4 (C) 3,1 (D) 0,2

2. If magnetic moments of V (Z = 23), Cr (Z = 24), Mn (Z = 25) are x, y, z respectively, then &

(A) x = y = z (B) x < y < z (C) x < z < y (D) z < y < x

3. In the electionic configuration of Mn(Z = 25) -

(A) Number of electrons having n +  = 4 is 5 (B) Number of electrons having m = 0 is 13
(C) magnetic moment is 1.73 BM (D) Mn is related to IIIrd period

4. If magnetic moment of Mna+ is 4.9 BM, then a = ? (Z = 25)

(A) 3 (B) 4 (C) 2 (D) 5

5. Which combination of quantum numbers for 4f is correct-

1 1
(A) n = 3,  = 2, m = –2, s = + (B) n = 4,  = 4, m = –4, s = –
2 2
1 1
(C) n = 4,  = 3, m = +1, s = + (D) n = 4,  = 3, m = +4, s = +
2 2

6. In the following electronic configuration, some rules have been violated :

I : Hund II : Pauli's exclusion III : Aufbau

(A) I and II (B) I and III (C) II and III (D) I, II and III

7. Which of the following has two unpaired electrons ?

(A) Si, Mg (B) S, Mg (C) S, Si (D) S, Fe.

8. A neutral atom of an element has 2K, 8L, 9M and 2N electrons. Find out the following :
(i) Atomic number (ii) Total number of s electrons
(iii) Total number of p electrons (iv) Total number of d electrons
(v) Number of unpaired electrons

9. Which of the following statement (s) is/are true.

2 h
I Orbital angular momentum is for the last valence electron of Cl atom.
2
II For the last valence shell electron of Ti3+ ion, the value of n = 3 and value of  = 2 are possible.
3
III Total spin of electrons for the Cr3+ ion is ± 2
.
IV Spin magnetic moment of alkaline earth metals are greater that of alkali metals.

(A) I, II and III (B) II and III Only (C) I and IV only (D) All are correct

10. Which of the following configuration corresponds to a pseudo-inert gas configuration ?

(A) ns2 np6 (B) ns2np6nd10 (C) (n – 1)d10 ns2 np6 (D) None of these.

11. Which of the following ion has a pseudo-inert gas configuration ?

(A) Ag+ (B) Cd2+ (C) Zn2+ (D) Fe3+

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 ANSWERS

DPP : 01

1. (A) 2,2,2 (B) 1,1,0 (C) 6,6,6 (D) 8,8,9 (E) 10,10,12 (F) 10,7,7
(G) 18,17,20 (H) 10,11,12
2. C 3. B 4. D 5. D 6. A
23
7. D 8. 11, 23, 11, 11 Na 9. B 10. A
DPP : 02
1. C 2. C 3. A 4. C 5. A 6. D 7. C
8. C 9. B 10. C
DPP : 03
1. A 2. 1.8714 × 1020 3. A 4. D 5. D 6. B
-3
7. 1.5 8. 10 9. 750nm 10. 25 11. 4.24 × 1034 12. –10
4 × 10 J
DPP : 04
1. A 2. B 3. B 4. B 5. D 6. 37.35% 7. A
8. B 9. C
DPP : 05
1. D 2. C 3. C 4. D 5. B 6. A 7. D
8. D 9. A 10. B 11. C 12. D 13. B 14. B
15. (A)  S ; (B)  S ; (C)  P ; (D)  Q, R

DPP : 06
1. A, B, D 2. 1028 Å, 1216 Å, 6568 Å 3. B 4. 4.41 × 10–17 J.
5. D 6. B 7. D 8. C 9. D 10. B
11. (A)  Q ; (B)  R ; (C)  S ; (D)  P

DPP : 07
1. A,D 2. D 3. C 4. C 5. A
6. (A)  RS ; (B)  PS ; (C)  QR ; (D)  PQ 7. (A)  Q ; (B)  P ; (C)  S ; (D)  R
8. A, B 9. 2 10. A 11. 5 12. A
DPP : 08

1. C 2. C 3. A 4. C 5. A 6. C 7. B
8. D 9. B 10. D 11. A 12. 2 13. 2 2
DPP : 09

1. B 2. C 3. D 4. D 5. D 6. D 7. D
8. D 9. C 10. B 11. A

DPP : 10

1. A 2 C 3. B 4. A 5. C 6. C 7. C
8. 21, 8, 12, 1, 1 9. A 10. B 11. ABC

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