Champ Daily Practice Sheet

ATOMIC STRUCTURE (1)

BASIC ATOMIC STRUCTURE

ONLY ONE CORRECT OPTION

1. In the neutral state the element M consists of the isotopes 14 M28 , M29 and
14 M30 in
14
the ratio

60 : 30 : 20 respectively. Correct statements about M in the natural state include that

(A) the atomic weight is between 28.0 and 28.5
(B) atoms of M contains 24 electron each
(C) atoms of M may contains 14,15 or 16 neutrons each
(D) atoms of M contains 16 protons each

1. The ratio of specific charge (charge/ mass) of a proton and an  -particle is

(A) 2 : 1 (B) 1 : 2 (C) 1 : 4 (D) 1 : 1

3. The mass number of an anion, X3  , is 14. If there are ten electrons in the anion, the
number of neutrons in the nucleus of atom, X2 of the element will be
(A) 10 (B) 14 (C) 7 (D) 5

4. Rutherford's alpha particle scattering experiment eventually led to the conclusion that
(A) Mass and energy are related
(B) Electrons occupy space around the nucleus
(C) Neutrons are buried deep in the nucleus
(D)The point of impact with matter can be precisely determined

5. The frequency of an electromagnetic radiation is 2  106 Hz . What is its wavelength in

metres
(Velocity of light = 3  108 ms-1)
(A) 6.0  1014 (B) 1.5  104 (C) 1.5  102 (D) 0.66  102

ONE OR MORE THAN ONE CORRECT OPTION

6. Many atoms have non-integral atomic masses because

(A) they have isotopes
(B) their isotopes have non-integral masses
(C) their isotopes have different masses
(D) the constituent neutrons, protons and electrons combine to give fractional masses

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7. Identify the correct statements
(A) Isotones have number of neutrons
(B) Isobars have same mass number
(C) Isosteres have same number of atoms in the molecules as well as they are isoelectronic
(D) Isodiapher of an atom X can be obtained by α- emission.

8. Identify the correct statements

(A) When alpha particle are sent through a thin metal foil, most of them go straight through
the foil.
(B) If the mass attributed to a neutron were halved and that attributed to the electron were
doubled, the atomic mass of would be reduced approximately by 25%.
(C) According to Dalton’s atomic theory, the smallest particle in which matter can exist, is
called a molecule
(D) Alpha-particle that come closer to nuclei make more collisions.

SUBJECTIVE PROBLEMS

9. (i) Radius of the nucleus is equal to 10-12cm. and that of the atom is equal to 10-8 cm.
What is the fraction of the volume of the atom occupied by nucleus?

(ii) The maximum wavelength of radiation that can ionise a sodium atom is 2414A0. The
ionisation energy of sodium per mole shall be……

10. The nucleus and an atom can be assumed to be spherical .The radius of the nucleus of an
element with mass no. A is given by 1.25  1013  A1/3 cm. The atomic radius of atom is 1Å. If
the mass no .is 64, the fraction of the atomic volume that is occupied by nucleus is :

ANSWER

1. C 2. A 3. C 4. B 5. C
6. ABCD 7. ABCD 8. AB 9. (i) 10-12 (ii) 495.7 kJ/mole
10. 1.25 x 10-13

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 Champ Daily Practice Sheet
ATOMIC STRUCTURE (2)
BOHR’S THEORY
ONLY ONE CORRECT OPTION
1. When a hydrogen atom emits a photon of energy 12.1 eV. Its orbit angular momentum
changes by
(A) h/2 (B) 2h/π (C) h/ (D) h/3π

2. The ratio of the distance between 5th & 3rd shell of H atom to 2nd excited state and ground

state of Li+2 is
(A) 1 : 6 (B) 6 : 1 (C) 16 : 3 (D) 3 : 16
3. Assertion: The transition of electrons n3  n2 in H atom will emit greater energy than n4  n3.

Reasoning: n3 and n2 are closer to nucleus than n4.

(A) If both assertion and reason are true and reason is the correct explanation of assertion
(B) If both assertion and reason are true but reason is not the correct explanation of
assertion
(C) If assertion is true but reason is false
(D) If both assertion and reason are false
4. An atom is comprising of electrons and nucleons (protons + neutrons). In the Bohr's model,
electrostatic force of attraction between nuclear charge (Ze) and electron of charge e is
balanced by the centripetal force acting towards the centre of atom. If 0 be the permittivity

of vacuum and r be the radius of orbit in which electron is revolving. The velocity of electron
of H atom is:
e 40rm 40rm
(A) v  (B) v  e  40rm (C) v  (D) v 
40rm e e2

5. An α–particle of momentum P is bombarded on the nucleus, the distance of the closest

approach is r. If the momentum of α–particle is made 6 times, the distance of the closest
approach beomes:
(A) 4r (B) 2r (C) 16r (D) r/36
ONE OR MORE THAN ONE CORRECT OPTION
6. Identify the correct statements
(A) The separation energy of the electron present in the shell n = 3 is 1.51 eV. The energy
in the first excited state is -3.4eV (approx).

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 (B) The radius or hydrogen atom in its ground state is 5.3 x 10 -11m. After observing energy
electron jump to higher energy state having radius of 21.2 x 10 -11 m. The principal
quantum number, n of the final state of the atom is 2
(C) The potential energy of the electron in the L-shell of the hydrogen atom = - 6.8eV
(D) The maximum energy is possessed by an electron of an atom when it is present at
infinite distance from the nucleus

7. Which one of the following is/are correct for the Bohr model of hydrogen atom
Ze2 mv 2
(A)  (B) angular momentum is quantized
r2 r
2
(C) angular momentum of an orbit = n (D) none of the above
h
8. Energy levels A, B, C of a certain atom corresponds to increasing values of energy i.e.,
EA< EB < EC., If 1, 2 and 3 are the wavelength of radiations corresponding to the
transitions C to B, B to A and C to A respectively, which of the following statement is/are
incorrect :

1 2
(A) 3 = 1 + 2 (B) 3  (C) 1 + 2 + 3 = 0 (D) 32  12  22
1   2

SUBJECTIVE PROBLEMS

9. Supposing the energy (in arbitrary units) of the energy levels in the hydrogen atom is given
as under:

Energy level K L M N
n 1 2 3 4 n=
Energy -864 a.u. zero

the excitation energy needed to raise the electron from M level to n =  would be ……..

10. An electron in a Bohr orbit of hydrogen atom in quantum level n 2 has an angular

momentum of 2.11 x 10-34 kgm2 sec-1. If this electron drops from this level to the next

lower level, find the wavelength of this spectral line.(given RH = 109679 cm-1)

ANSWER
1. C 2. B 3. B 4. A 5. D
6. ABCD 7. AB 8. AC 9. 96 10. 1215.67 A0

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 Champ Daily Practice Sheet
ATOMIC STRUCTURE (3)
BOHR’S THEORY II HYDROGEN SPECTRUM
ONLY ONE CORRECT OPTION
1. How many spectral lines will be obtained by the various transitions when an electron comes
from 4th excited state to its ground state?
(A) 20 (B) 5 (C) 4 (D) 10

2. The value of:[2p(energy)  1s(energy)] for H-atom would be :

(A) 10.2 eV (B) 13.6 eV (C) 3.4 eV (D) None of these

3. If the series limit (n =  to n = 1) of wavelength of the Lyman series for the hydrogen atoms
is 912Å, then the series limit of wavelength for the Balmer series of the hydrogen atom is:
(A) 912 Å (B) 912 × 2 Å (C) 912 × 4 Å (D) 912/2 Å
4. If electron of each hydrogen atom is excited by giving 8.4eV energy, then the number of
spectral lines emitted is equal to:
(A) 4 (B) 2
(C) 3 (D) no spectral line will obtain
5. In Bohr series of lines of hydrogen spectrum, the third line from the red end corresponds to
which one of the following inter-orbit jumps of the electron for Bohr orbits in an atom of
hydrogen?
(A) 2 5 (B) 3  2 (C) 5  2 (D) 4  1

ONE OR MORE THAN ONE OPTION CORRECT

6. Spectral series of H-atom given vmin and vmax depending on the types of transition. Which
is/are correct matching
Series vmax vmin
(A) Lyman RH 3RH/4
(B) Balmer RH/4 5RH/36
(C) Paschen RH / 9 7RH / 144
(D) Brackett RH / 16 9RH / 400

7. Which of the following statement about Rydberg’s constant (RH) is/are correct?
(A) It’s numerical value is 1.09678  105 cm-1
(B) It depends on Planck’s constant (h)
(C) It depends on permittivity of open space (0)
(D) It’s unit can be meter.

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8. Bohr's model can explain:
(A) The spectrum of hydrogen atom only
(B) The spectrum of atom or ion containing one electron only
(C) The spectrum of hydrogen molecule
(D) The solar spectrum

SUBJECTIVE PROBLEMS

9. Find the quantum number ‘n’ corresponding to the excited state of He + ion if on transition to
the ground state that ion emits two photons in succession with wavelengths 108.5 and
80.4 nm.

10. The dissociation of O2 into two normal atoms requres 498 kJ mol-1. Oxygen also

undergoes photochemical dissociation into the one normal oxygen atom and one excited
atom having 1.967 eV more energy than normal atom. What is the maximum wavelength
effective for photochemical dissociation of O2?

ANSWER

1. D 2. A 3. C 4. D 5. C
6. ABCD 7. ABC 8. B 9. 5 10. 1740.6 A0

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 Champ Daily Practice Sheet
ATOMIC STRUCTURE (4)
DE-BROGLIE’S HYPOTHESIS AND HEISENBERG’S UNCERTAINITY PRINCIPLE

ONLY ONE CORRECT OPTION

1. If the velocity of hydrogen molecule is 5  10 4 cm sec 1 , then its de-Broglie wavelength is

(A) 2 Å (B) 4 Å (C) 8 Å (D) 100 Å

2. Calculate de-Broglie wavelength of an electron travelling at 1% of the speed of light

(A) 2.73  1024 (B) 2.42  1010 (C) 242.2  1010 (D) None of these

3. Uncertainty in position of a 0.25 kg particle is 105 m. Uncertainty of velocity is

(h  6.6  1034 Js)
29
(A) 1.2  10 (B) 2.1 10
34
(C) 1.6  1020 (D) 1.7  109

4. The uncertainty in momentum of an electron is 1 105 kgm / s . The uncertainity in its

position will be (h  6.63  1034 Js)

(A) 5.28  1030 m (B) 5.25  1028 m (C) 1.05  1026 m (D) 2.715  1030 m

5. An α–particle is accelerated through a potential difference of V volts. The de–Broglie's

wavelength associated with it is:

150 0 0.286 0.101 0.983

(A) A (B) A0 (C) A0 (D) A0
V V V V

ONE OR MORE THAN ONE CORRECT OPTION

6. If the following matter waves travel with equal velocity, the shorter wavelength than electron
is that of a/an
(A) deuterium (B) proton (C) neutron (D) α-particle

7. Out of the following options in which case is the velocity of electron greater thant 1.5 × 106 m/s.
(A) An electron moving in the first Bohr radius of hydrogen atom.
(B) The electron which is accelerated from initial at rest position by an accelerating Potential
of 3.4 V.
(C) The electron having de Broglie wavelength of 0Å.
(D) The electron with maximum kinetic energy emitted from a metal whose threshold
wavelength is 124 nm and is subjected to electromagnetic radiations having wavelength
400 nm.

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8. The wave mechanical model of atom is based upon
(A) de Broglie concept of dual character of matter
(B) Heisenberg’s uncertainty principle
(C) Schrodinger wave equation
(D) Bohr’s Theory

SUBJECTIVE PROBLEMS

9. (i) What is the speed and de Broglie wavelength of an electron that has been
accelerated by a potential difference of 300 V?
(ii) Calculate the uncertainity in velocity of a cricket ball (mass = 0.15 kg) if its
uncertainity in position is of the order 1 A0.

10. The de-Broglie wavelength of electron of He+ ion in an orbit is 3.329 A0 If the photon
emitted upon de-excitation of this He+ ion into ground state is made to hit H-atom in its
ground state so as to liberate electron from it, what will be the de-Broglie’s wavelength of
photoelectron ?

ANSWER

1. B 2. B 3. B 4. A 5. C
6. ABCD 7. ABC 8. ABC
9. (i) 1.028 v 107 ms-1, 7.08 x 10-11 m (ii) 3.51 x 10-24 m sec-1 10. 2.351 A0

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 Champ Daily Practice Sheet
ATOMIC STRUCTURE (5)
PHOTO ELECTRIC EFFECT AND SCHRODINGER’S WAVE EQUATION
ONLY ONE CORRECT OPTION

1. When a certain photoelectric substance was irradiated with a light of frequency 4.0 × 1015 Hz,
the photoelectrons emitted had thrice the kinetic energy as did photo electrons emitted
when the same substance was irradiated with light of frequency 2.0 × 10 15 Hz. The
threshold frequency of the photoelectric substance is:
(A) 2.0 × 1015Hz (B) 1.0 × 1016 Hz (C) 1.0 × 1015 Hz (D) 1.5 × 1015 Hz

2. The number of radial nodes of 3s, 3p and 3d electrons are respectively

(A) 0, 1, 2 (B) 2, 1, 0 (C) 1, 3, 5 (D) 3, 2, 0

3. The maximum probability of finding an electron in the dxy orbital is

(A) along the x-axis (B) along the y-axis
(C) at an angle of 45° from the x and y axes (D) at an angle of 90°

4. Which of the following radial distribution graphs corresponds for orbital with n = 4, l = 2
2 2
4 r 
2 2
4 r 
(A) (B)
ra0 ar 0
2 2
4 r 
2 2
(C) (D) 4 r

ra0
a
r0

5. In a photoelectric experiment, when frequency of electromagnetic radiation by which a

metal surface is irradiated is doubled, then
(A) Kinetic energy of photoelectron will be doubled
(B) Number of photoelectron emitted will be doubled
(C) Kinetic energy will increase
(D) Kinetic energy will decrease
ONE OR MORE THAN ONE CORRECT OPTION
6. Which of the following statement is(are) true in the context of photoelectric effect?
(A) The kinetic energy of ejected electrons is independent of the photon intensity ofradiation.
(B) The threshold frequency is same for all metals.
(C) The number of photoelectrons ejected depends on the frequency of the incident radiation
(D) The kinetic energy of the emitted electrons depends on the frequency of the incident radiation.

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7. In a photoelectric experiment, kinetic energy of photoelectrons was plotted against the
frequency of incident radiation (), as shown in the figure. Which of the following statements
is (are) correct?
(A) The threshold frequency is .
(B) The slope of this line is equal to Plank’s constant.
(C) As the frequency of incident wavelength increases beyond threshold frequency, kinetic
energy of photoelectrons increases.
(D) It is impossible to obtain such a graph.
8. Identify the correct statements

(A)  2 represent the probability of finding an electron.

(B) The number of angular nodes in 3s orbital is zero
(C) The number of nodal planes in a 2Px orbitals is one.

The 
(D) represents 1 radial node.
graph
a0

SUBJECTIVE PROBLEMS
9. (i) Photoelectric emission requires a threshold frequency of 0. For a certain metal
l1= 2200 Å and l2 = 1900Å produce electrons with maximum kinetic energy KE 1

and KE2. If KE2 = 2KE1 calculate the corresponding wavelength (l0).

(ii) Light of wavelength 470 nm falls on the suface of potassium metal, electrons are

emitted with a velocity 6.4x104 m/s.

(a) What is the kinetic energy of emitted electron?
(b) What is the minimum amount of energy required to remove an electron from K
atom?
10. (i) The schrodinger wave equation for hydrogen atoms is
3/2
 1  r  r /a
 2s 
1
4  2 
1/2   
2   e 0 
 a0   a0 
where a0 is Bohr’s radius. Let the radial node in 2s be at r0. Then find r0 in terms of a0.
(ii) Total number of antinodes in the radial probability distribution vs distance curve for
5pz orbital is…
ANSWER
1. C 2. B 3. C 4. C 5. C
6. AD 7. BC 8. ABCD

9. (i) = 2612.5 Å, n0= 1.1483 x 1015 Hz (ii) (a) 1.86 x 10-21 J, (b) 4.2 x 10-19 J
10. (i) r0 = 2a0 (ii) 4

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