TOPIC WISE REVIEW TEST-I-AS

SINGLE CORRECT CHOICE TYPE

S3
S2
S1

1.
2
4 r R
2

r
The radial probability of finding an electron at spherical surface S1, S2 & S3 are in order
(A) S1 = S2 = S3 (B) S1 > S2 > S3 (C) S1 < S2 > S3 (D) S1 < S3 > S2
2. –K'r 4 3 2
For any orbital (r) = K· e (r + K1r + K2r ). Select true statement
(A) Orbital should be " 5s" (B) Orbital should be " 5d"
(C) Angular wave function should be independent on (,)
(D) Curve of 2(r) vs 'r' has maximum value at origin.
3. Consider the following nuclear reactions involving X & Y.
X  Y + 42 He
Y  8O18 + 1H1
If both neutrons as well as protons in both the sides are conserved in nuclear reaction then moles
of neutrons in 4.6 gm of X
(A) 2.4 NA (B) 2.4 (C) 4.6 (D) 0.2 NA
4. The given diagram shows points P1, P2 P3 & P4 in 1s orbital.

P3
P2
P1

P4

1s orbital
The correct order of increasing radial probability at these point are
(A) P1 = P2= P4 > P3 (B) P1 = P3 < P2 = P4
(C) P1 = P3 > P2 = P4 (D) P1 = P2 = P4 < P3
5. A H-like species emitted a photon corresponding to the first line of Lyman series. The photon liberated
a photoelectron from He+ in ground state. The deBroglie wavelength of the photoelectron is
2 Å. Calculate the atomic number of H-like specie.
(A) 12 (B) 9 (C) 3 (D) 4

TOPICE WISE REVIEW TEST 1-AS

6. Maximum and minimum multiplicity for d4 electronic configuration can be
(A) 5, 2 (B) 5, 1 (C) 5, 0 (D) 5, 5
7. Select the correct option(s).
(A) If in 1 litre vessel N2 and CO2 are at same pressure and temperature then they have equal number
of atoms.
(B) Electrons present in 3s orbital can have only following series of quantum number (n, l, m, s)
3, 0, 0, 1/2.
(C) Moles of any gas in 10 litre container at 8.21 atm & 300 K is equal to 3.33 .
(D) Number of neutrons present in 1 mole of NH4+ are 7.

8. Assuming Heisenberg Uncertainity Principle to be true what could be the minimum uncertainty in
de-broglie wavelength of a moving electron accelerated by Potential Difference of 6 V whose uncertainty
7
in position is n.m.
22
(A) 6.25 Å (B) 6 Å (C) 0.625 Å (D) 0.3125 Å

9. Give the correct order of initials True (T) or False (F) for following statements.
(I) If electron has zero magnetic quantum number, then it must be present in s orbital.
(II) A d orbital can accommodate maximum 10 electrons only.
(III) In orbital diagram, Pauli’s exclusion principle is violated.
1
(IV) Minimum number of electrons having s =  in phosphorus is 9.
2
(A) FTFT (B) TFTF (C) FFFF (D) TTTT
10. Choose the correct statement from the following :
(A) Zeff on ‘d’ electron of Sc2+ is 18
(B) Zeff values on an electron present in 4s and 4p orbital of an atom are identical.
(C) Zeff values on an electron present in 3s and 4s orbital of an atom are identical.
(D) the screening constant value on one electron in H– ion is 0.35.

R(r) R(r) R(r)

11. r r r

(X) (Y) (Z)

Identify corresponding atomic orbitals for graphs X, Y and Z respectively.

(A) 1s, 3s, 3p (B) 3p, 3s, 1s (C) 3d, 3s, 1s (D) 1s, 3s, 3d
MORE THAN ONE CORRECT OPTION
12. In a sample of hydrogen atoms, electrons are excited to the 4th orbit by means of some electromagnetic
radiations. No electrons are present in any other energy level. How many maximum spectral lines will
form in the following cases, when the electrons will de-excite to the ground state?
TOPICE WISE REVIEW TEST 1-AS
 (A) The sample contains only one atom then the maximum no. of spectral lines will be 3
(B) The sample contains only two atom then the maximum no. of spectral lines will be 4
(C) The sample contains only four atom then the maximum no. of spectral lines will be 6
(D) The sample contains infinite atom then the maximum no. of spectral lines will be 10
13. Choose the correct statement among the following
(A) Radial distribution function (  2 ·4r 2dr ) give probability at a particular distance along
one chosen direction
(B)  2 ( r ) give probability density at a particular distance over a spherical surface
(C) For 's' orbitals  ( r )  ()  ()   ( x , y, z ) is independent of  and 
(D) '2p' orbital with quantum numbers. n = 2,  = 1, m = 0, also shows angular dependence
14. Correct statement(s) regarding 3Py orbital is/are
(A) Angular part of wave function is independent of angles ( and )
(B) No. of maxima when a curve is plotted between 4r2R2(r) vs r are '2'
(C) 'xz' plane acts as nodal plane
(D) Magnetic quantum number must be '–1'
15. Choose the incorrect statement(s):
(A) Increasing order of wavelength is
Micro waves > Radio waves > IR waves > visible waves > UV waves
(B) The order of Bohr radius is (rn : where n is orbit number for a given atom)
r 1 < r2 < r3 < r4
(C) The order of total energy is (En : where n is orbit number for a given atom)
E1 > E2 > E3 > E4
(D) The order of velocity of electron in H, He+, Li+, Be3+ species in second Bohr orbit is
Be3+ > Li+2 > He+ > H
16. Select the correct curve(s):
If v = velocity of electron in Bohr's orbit
r = Radius of electron in Bohr's orbit
P.E. = Potential energy of electron in Bohr's orbit
K.E. = Kinetic energy of electron in Bohr's orbit.

(A) (B) (C) (D)

17. Which is / are correct statement.

(A) The difference in angular momentum associated with the electron present in consecutive orbits of
h
H-atom is (n–1)
2
(B) Energy difference between energy levels will be changed if, P.E. at infinity assigned value other than
zero.
(C) Frequency of spectral line in a H-atom is in the order of (2  1) < (3  1) < (4  1)
(D) On moving away from the nucleus, kinetic energy of electron decreases.
TOPICE WISE REVIEW TEST 1-AS
COMPREHENSION-1
Alpha particles capture free moving electrons having wavelength 0.5 nm & form excited H-like species.In
this excited state electron has circumference, 4 times the wavelength of electron. Bohr's quantisation
rule is applicable.
18. Find the energy of photon emitted in this process.
(A) 9.4 eV (B) 122.4 eV (C) 54.4 eV (D) None of these
19. The number of maximum possible spectral lines obtained in Lyman series, when electron makes transition
to ground state.
(A) 3 (B) 6 (C) 1 (D) None of these
20. Now the electron make transition to ground state & emits a photon having energy equal to 6th line of
Balmer series of some other H-like specie having atomic number "Z", then the value of "Z" is
(A) 6 (B) 4 (C) 5 (D) None of these
21. Photons of equal energy were allowed to strike on two different gas samples. H-atoms in one sample
is in some excited state with a principal quantum number ‘n’ and H-atoms in other sample is in ground
state. The photonic beams totally ionise the H-atoms in both samples. If the difference in the kinetic
energy of the ejected electrons in the two different cases is 10.2 eV. Then the principal quantum
number ‘n’ of the excited state is
(A) 5 (B) 2 (C) 3 (D) 4

COMPREHENSION-2
The only electron in the hydrogen atom resides under ordinary conditions on the first orbit. When
energy is supplied, the electron moves to higher energy orbit depending on the amount of energy
absorbed. When this electron returns to any of the lower orbits, it emits energy. Lyman series is formed
when the electron returns to the lowest orbit while Balmer series is formed when the electron returns to
second orbit. Similarly, Paschen, Brackett and Pfund series are formed when electron returns to the
third, fourth and fifth orbits from higher energy orbits respectively.
Maximum number of lines produced when an electron jumps from nth level to ground level is equal
n ( n  1)
to . For example, in the case of n = 4 , number of lines produced is 6. (4  3, 4  2, 4 
2
1, 3  2 , 3  1, 2  1). When an electron returns from n2 to n1 state, the number of lines in the
spectrum will be equal to
(n 2  n1 )(n 2  n1  1)
2
If the electron comes back from energy level having energy E2 to energy level having energy E1, then
the difference may be expressed in terms of energy of photon as:
hc
E2 – E1 = E ,  =
E
Since h and c are constants, E corresponds to definite energy; thus each transition from one energy
level to another will produce a light of definite wavelength. This is actually observed as a line in the
spectrum of hydrogen atom.
 1 1 
Wave number of line is given by the formula   R  2  2  .
n 
 1 n2 
where R is a Rydberg's constant ( R = 1.1 × 107 m–1)

TOPICE WISE REVIEW TEST 1-AS

22. The energy photon emitted corresponding to transition n = 3 to n = 1 is [h = 6 ×10–34 J-sec.]
(A) 1.76 ×10–18 J (B) 1.98 ×10–18 J (C) 1.76 ×10–17 J (D) None of these
23. th
In a collection of H-atom, electrons make transition from 5 excited state to 2nd excited state then
maximum number of different types of photons observed are
(A) 3 (B) 4 (C) 6 (D) 15
24. The difference in the wavelength of the 1st line of Lyman series and 2nd line of Balmer series in a
hydrogen atom is
9 4 88
(A) (B) (C) (D) None
2R R 15R
25. The wave number of electromagnetic radiation emitted during the transition of electron in between two
levels of Li2+ ion whose principal quantum numbers sum is 4 and difference is 2 is
8
(A) 3.5 R (B) 4 R (C) 8 R (D) R
9
Assertion and Reason :
26. It is a data sufficiency problem in which it is to be decided on the basis of given statements
whether the given question can be answered or not. No matter whether the answer is yes or
no.
Question : Is the orbital of hydrogen atom 3px?
1  / 2 r
Statement-1: The radial function of the orbital is R(r) = ( 4   )  e , =
9 6 a 30 / 2 2
Statement-2: The orbital has 1 radial node & 0 angular node.
(A) Statement (1) alone is sufficient. (B) Statement (2) alone is sufficient
(C) Both together is sufficient. (D) Neither is sufficient

27. Statement-1 : Emitted radiations will fall in visible range when an electron jump from
higher level to n = 2 in Li+2 ion.
Statement-2 : Balmer series radiations belong to visible range in all H-atoms.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for
statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.
MATRIX MATCH TYPE QUESTIONS
28. Column I Column II

(A) Angular wave function () of this orbital (P)

changes with change in  & .

(B) For this orbital, as distance from nucleus (Q)

increases, radial probability of finding electron
may increase or decrease
r

TOPICE WISE REVIEW TEST 1-AS

 (C) Probability density of finding electron at nucleus (R)
depends upon principal quantum number for
orbitals having azimuthal quantum number same
as that of given orbital.
r

(S)

r
29. Column I & column II contain data on Schrondinger Wave–Mechanical model, where symbols have
their usual meanings.Match the columns.
Column I Column II (Type of orbital)

(A) (P) 4s

(B) (Q) 5px

(C) (,) = K (independent of &) (R) 3s

(D) atleast one angular node is present (S) 6dxy

30. Column-I Column-I

(A) Electron moving in 2nd orbit in He+ ion (P) Radius of orbit in which
electron is moving is 0.529 Å

(B) Electron moving in 3rd orbit in H-atom (Q) Total energy of electron is
(–)13.6 × 9eV
(C) Electron moving in 1st orbit in Li+2 ion (R) Velocity of electron is
2.188  106
m/sec
3
(D) Electron moving in 2nd orbit is Be+3 ion (S) De-broglie wavelength of
150
electron is Å
13.6

TOPICE WISE REVIEW TEST 1-AS

 REVIEW TEST - 1 AS - ANSWERS
SINGLE CORRECT CHOICE TYPE
1. C
2. B
3. B
4. C
5. C
6. B
7. C
8. C
9. C
10. B
11. B
MORE THAN ONE CORRECT OPTION
12. A, B, C 13. C,D 14. B,C 15. A,C 16. B,C,D 17. C,D
COMPREHENSION-1
18. B 19. C 20. B 21. B
COMPREHENSION-2
22. A 23. C 24. B 25. C
ASSERTION RESION
26. B 27. D
MATRIX MATCH TYPE QUESTIONS
28. (A) Q,R (B) P,Q,R,S (C) P,S
29. (A) P, (B) P,Q,S, (C) P, R (D) Q, S 30. (A) S, (B) R, (C) Q, (D) P

TOPICE WISE REVIEW TEST 1-AS

 REVIEW TEST - 1 AS - SOLUTIONS
SINGLE CORRECT CHOICE TYPE
1. (r) = K· e–K'r [r2(r2 + K1r + K2)]
(r) = K· e–K'r r2 (r2 + K1r + K2)
Radial nodes = 2
n––1=2
for  = 2
n=5 i.e. 5d ]

150
5. =
V

150
2=
V
150
V= = 37.5
4
K.E. of photoelectron = 37.5 eV
 Amount of energy required to liberated electron = 54.5 eV
Total energy of photon = 54.4 + 37.5 = 91.9 eV
Also 10.2 z2 = 91.9 (as for H atom energy of first line of Lyman series = 10.2 eV )
z= 3 ]
6. For maximum multiplicity of d4 electronic configuration arrangement of electrons :
+½ +½ +½ +½
s = ½+½+½+½
4 2
d
m= 2×2+1=5
For minimum multiplicity of d4 electronic configuration arrangement of electrons.

+½–½+½–½
s=+½–½+½–½
0
or m = 0+1 = 1

]
s=+½–½+½–½
0
m = 0+1 = 1

7. (A) Pressure  mole ; mole = NA molecules

(B) 3s orbital n  m s
3 0 0 1/2
3 0 0 –1/2
(C) Number of moles = = =
(D) Number of neutrons present in 1 mol. NH4+ = [7 + 0] × NA = 7 NA ]
9. I F
II F
III F
AS Page # 8 TOPICE WISE REVIEW TEST 1-AS
 IV F
1s2 2s2 2p6 3s2 3p3

+½ +½ +½
1 electron in each
orbital has s = – ½
therefore minimum number
of es— (s = –½) = 6
10. (1s) (2s 2p) (3s 3p) (3d) (4s 4p)......
(A) Sc2+ then Zeff = Z – 
= 21 – 
(1s)2 (2s 2p)8 (3s 3p)8 3d1
 = 18
(B) 4s and 4p are present in same group therefore zeff will be same.
(C) 3s and 4s are present in different group therefore they have different Zeff values.
(D) H–  1s2 for ‘1s’ the factor is 0.30. ]
11. In which of the following pairs do the two species resemble each other most closely in chemical properties?
MORE THAN ONE CORRECT OPTION
12. A, B, C 13. C,D 14. B,C 15. A,C 16. B,C,D 17. C,D
COMPREHENSION-1
18. B 19. C 20. B 21. B
COMPREHENSION-2
22. A 23. C 24. B 25. C
ASSERTION RESION
26. B 27. D
MATRIX MATCH TYPE QUESTIONS
28. (A) Q,R (B) P,Q,R,S (C) P,S
28. (C) for s-orbital radial probability density at nucleus is not zero. The value of radial probability density
at nucleus depends upon principal quantum number for s-orbital. ]
29. (A) P, (B) P,Q,S, (C) P, R (D) Q, S 30. (A) S, (B) R, (C) Q, (D) P

TOPICE WISE REVIEW TEST 1-AS