Physical Chemistry Date : ……………..

Time : 10 Min

–19
1. The energy absorbed by each molecule (A2) of a substance is 4.4 × 10 J and both energy per

molecule is 4.0 × 10–19 J. The kinetic energy of the molecule per atom will be :

(A) 2.0 × 10–20 J (B) 2.2 × 10–19 J (C) 2.0 × 10–19 J (D) 4.0 × 10–20 J

2. The difference in angular momentum associated with the electron in two successive orbits of hydrogen

atom is :

(A) h/ (B) h/2 (C) h/2 (D) (n – 1)h/2



3. The expression for Bohr’s radius of an atom is

n2 h 2 n2 h 2 n2 h 2 n2 h 2
(A) r  2 4 2 (B) r  2 2 (C) r  2 2 2 (D) r  2 2 2 2
4 kme z 4 kmze 4 kme z 4 km e z

4. If r1 is the radius of the first orbit of hydrogen atom, then the radii of second, third and fourth orbits in

terms of r1 are :

(A) r12, r13, r14 (B) 8r1, 27r1, 64r1 (C) 4r1, 9r1 16r1 (D) 2r1, 6r1, 8r1

5. The ratio of radii of second orbits of He+, Li2+ and Be3+ is :

(A) 1 : 2 : 3 (B) 6 : 4 : 3 (C) 3 : 4 : 6 (D) none of these

+2
6. The radius of hydrogen atom is 0.53 Å. The radius of 3Li is of :

(A) 1.27 Å (B) 0.17 Å (C) 0.57 Å (D) 0.99 Å

7. The electronic velocity in the fourth Bohr’s orbit of hydrogen atom is u. The velocity of the electron in

the first orbit of same atom would be :

(A) u/4 (B) 16u (C) u/16 (D) 4u

8. If the speed of electron in second orbit of He+ is "v", then the speed of electron in first Bohr orbit of

hydrogen atom will be :

(A) x/2 (B) 2x (C) x (D) 4x

Physical Chemistry Date : …………….. Time : 10 Min

1. Of the following, which statement(s) regarding Bohr theory is/are wrong :

(A) Kinetic energy of an electron is half of the magnitude of its potential energy.

(B) Kinetic energy of an electron is negative of total energy of electron.

(C) Energy of electron decreases with increase in the value of the orbit number.

(D) The ionization energy of H-atom in the first excited state is negative of one fourth of the energy of

an electron in the ground state.

2. The kinetic energy of an electron in a H-like species is :

(A) Directly proportional to n2 (where n = orbit number)

(B) Inversely proportional to Z2 (where Z = Atomic number)

(C) Both (A) & (B)

(D) None of these

3. In an atom, two electrons move around the nucleus in circular orbits of radii R and 4R. The ratio of the

time taken by them to complete one revolution is : (Assume Bohr's model to be valid)

(A) 1 : 4 (B) 4 : 1 (C) 1 : 8 (D) 8 : 7

(+z–1)
4. The energy level for ZA can be given by :
(+z –1) 2 (+z –1)
(A) En for A = Z × En for H (B) En for A = Z × En for H
(+z –1) 1 1
(C) En for A = × En for H (D) En for A
(+z –1)
= × En for H
Z2 Z

5. In hydrogen atom, energy of second excited state is –1.51 eV. Then, KE of same orbit of hydrogen

atom is:

(A) + 3.4 eV (B) + 1.51 eV (C) – 13.6 eV (D) + 13.6 eV

6. The energy of the fourth Bohr orbit of the hydrogen atom is –82 kJ mol–1; hence the energy of second

Bohr orbit would be

(A) –1312 kJ mol–1 (B) –328 kJ mol–1 (C) –41 kJ mol–1 (D) –164 kJ mol–1

7. The ratio of the difference in energy of electron between the first and second Bohr’s orbit to that

between second and third Bohr’s orbit is :

(A) 1/3 (B) 27/5 (C) 9/4 (D) 4/9

Physical Chemistry Date : …………….. Time : 10 Min

* Marked Questions are having one or more than one correct option.

1. If the binding energy of 3rd orbit of a H-like species is 13.6 eV, then the species must be :
(A) Be3+ (B) Li+ (C) He+ (D) None of these

2. If the wavelength of photon emitted from an electron jump n = 4 to n = 2 in a H-like species is 1216 Å,
then the species is :
(A) H-atom (B) He+ ion (C) Li2+ ion (D) Be3+ ion

3. If the I excitation potential of a hypothetical H-like atom is 10.2x V, then the value of II excitation energy
is about :
(A) 13.6x eV (B) 12.09x eV (C) –10.2x eV (D) 40.5x eV

4. The highest excited state that an unexcited hydrogen atom sample can reach when it is bombarded
with photons of 12.2 eV, will be :
(A) n = 4 (B) n = 2 (C) n = 3 (D) No transition will occur.

5. Considering Bohr model to be valid, the time period of revolution of electron revolving in nth orbit in aH-
np
like species (atomic number = Z) is proportional to . Find the value of (p + q) :
Zq
(A) 4 (B) – 5 (C) – 4 (D) 5

6. If the binding energy of first excited state of a hydrogen like sample is 54.4 eV, then determine the
atomic number Z of the H-like species :
(A) 1 (B) 2 (C) 3 (D) 4

7. Suppose that a hypothetical H-like atom gives a red, green, blue and violet line in spectrum. Which
jump, according to figure, would give off the violet spectral line :

(A) 3  1 (B) 2  1 (C) 4  1 (D) 3  2

8.* Which of the following is/are correct according to Bohr model for H-like species (atomic number = Z):
Z
(A) Velocity of electron in nth orbit 
n
Z 2
(B) Frequency of revolution of electron in nth orbit 
n 3

n
(C) de-Broglie wavelength of electron revolving in nth orbit 
Z
n 2
(D) | Energy | of electron in nth orbit 
Z2
Physical Chemistry Date : …………….. Time : 10 Min

1. Paschen series for H-atom lies in region of electromagnetic spectrum :

(A) Visible (B) Ultra-violet (C) Infra red (D) Cannot be predicted

–1
2. The longest  for the Lyman series for H is : (Given RH = 109678 cm )

(A) 1215 Å (B) 1315 Å (C) 1415 Å (D) 1515 Å

–1
3. The shortest for the Brakett series for H is : (Given RH = 109678 cm )

(A) 1459 Å (B) 4052 Å (C) 4052 nm (D) 1459 nm

4. The wavelength of a spectral line for an electronic transition is inversly related to :

(A) No. of electrons undergoing transition

(B) The nuclear charge of the atom

(C) The velocity of an electron undergoing transition

(D) The difference in the energy levels involved in the transition

5. Line spectrum is characteristic of :

(A) Molecule (B) Atom (C) Both (D) None of these

6. Different lines in Lyman series of hydrogen spectrum lie in :

(A) UV (B) Visible (C) IR (D) None of these

7. The spectral lines corresponding to the radiation emitted by an electron jumping from 6th, 5th and 4th

orbits to second orbit belong to :

(A) Lyman series (B) Balmer series

(C) Paschen series (D) Pfund series

8. The speed of the electron in the 1st orbit of the hydrogen atom in the ground state is (c is the velocity of

light):

c (B) (C) (D)

(A)
1.37 1370 13.7 137

9. Which one of following explains light both as a stream of particles and as wave motion ?
h
(A) Diffraction (B)   (C) Interference (D) Photoelectric effect
p