PINNAACLE CLASSES

26. What is the mole fraction of the solute in a 1.00 32. The Van’t Hoff factor for acompound which
aqueous solution? undergoes dissociation in one solvent and
association in other solvent is respectively
(a) 1.770 (b) 0.0354
(c) 0.0177 (d) 0.177 (a) less than one and greater than one
(b) less than one and less than one
27. The boiling point of 0.2 mol solution of in (c) greater than one and less than one
(d) greater than one and greater than one.
water is greater than equimolal solution of in
water. Which one of the following statements is
33. A 0.1 molal aqueous solution of a weak acid is
true in this case?

(a) Molecular mass of is less than the 30% ionized. for water is , the
freezing point of the solution will be
molecular mass of
(b) is undergoing dissociation in water while (a) (b)
undergoes no change. (c) (d)
(c) is undergoing dissociation in water.
(d) Molecular mass of is greater than the 34. 200 of an aqueous solution of a protein
molecular mass of Y.
contains its 1.26 . The osmotic pressure of this

28. Which of them is not equal to zero for an ideal solution at 300 is found to be bar.
solution?
The molar mass of protein will be bar
(a) (b)

(c) (d)
(a) 51022 (b) 122044
29. Of the following 0.10 aqueous solutions, which
one will exhibit the largest freezing point (c) 31011 (d) 61038
depression?
35. An aqueous solution is 1.00 molal in . Which
(a) KC1 (b) change will cause the vapour pressure of the
solution to increase?
(c) (d)
30. Which condition is not satisfied by an ideal (a) Addition of
solution?
(b) Addition of
(a) (b) (c) Addition of 1.00 molal KI
(d) Addition of water
(c) Obeyance to Raoult’s Law (d)
31. The freezing point depression constant for water is 36. A 0.0020 aqueous solution of an ionic

. If 5.00 is dissolved in 45.0 compound freezes at

, the freezing point is changed by . . Number of moles of ions which 1 mol

of ionic compound produces on being dissolved in
Calculate the van’t Hoff factor for
water will be
(a) 2.05 (b) 2.63
(c) 3.11 (d) 0.381 (a) 3 (b) 4
(c) 1 (d) 2
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 PINNAACLE CLASSES

37. Concentrated aqueous sulphuric acid is 98% 41. Gadolinium belongs to series. Its atomic
number is 64. Which of the following is the correct
by mass and has a density of 1.80 . electronic configuration of gadolinium7.
Volume of acid required to make one litre of 0.1
(a) (b)
solution is
(c) (d)
(a) 16.65 (b) 22.20 42. Assuming complete ionisation, same moles of
which of the following compounds will require the
(c) 5.55 (d) 11.10 (2007)
least amount of acidified for complete
oxidation?.
(a) (b) (c) (d)
43. Which of the following processes does not involve
oxidation of iron?.
(a) Formation of from Fe.

(b) Liberation of from steam by iron at high

temperature.
38. Match the catalyst with the process:
Catalyst Process (c) Rusting of iron sheets.

(d)Decolourisation of blue solution by iron.

(p) The oxidation of
(i) ethyne to ethanal 44. Because of lanthanoid contraction, which of the
(q) Polymerisation of following pairs of elements have nearly same
(ii) alkynes atomic radii?. (Numbers in the parenthesis are
atomic numbers)
(iii) (r) Oxidation of in
the manufacture of (a) and (b) andTa(73)
(c)Ti(22)and Zr ( 40 )(d) Zr (40)and Nb(41)
(iv) Nickel complexes (s) Polymerisation of
ethylene 45. The reaction of aqueous with in
Which of the following is the correct option?. acidic conditions gives
(a) and (b) and
(a)
(c) and (d) .
(b) 46. How many of the following show variable oxidation
states in their compounds ?
(c)
47. Determine total number of unpaired electrons in
(d) following ions
39. Which one of the following ions exhibits d‐d Ti3+, V3+, Cr3+, Cr2+, Mn3+, Mn2+, Fe3+, Fe2+, Co2+,
transition and paramagnetism as well?
Ni2+, Cu2+
(a) (b) 48. How many of given statements are true for
lanthanums ?
(c) (d)
40. Name the gas that can readily decolourise acidified (1) The common oxidation state of all
lanthanides is +3.
solution.
(2) All lantanides belongs to group III of
(a) (b) modern periodic table.
(3) All lanthanides belongs to seventh period of
(c) (d)
periodic table.
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 PINNAACLE CLASSES

(4) The radius for all lanthanides cations(M+3)

decrease from Ce+3 to Lu+3.
(5) The basic character of hydroxide increases
on moving from Ce(OH)3 to Lu(OH)3.
(6) All lanthanides are metals.
(7) The reducing power of lanthanides
decreases from Ce to Lu.
(8) Lanthanides reacts with cold water to
liberate H2.
49. C 6 H 6 freezes at 5.5 °C. The temperature at which
a solution of 10g of C 4 H 6in of freeze is ____°C.
(The molal freezing point depression constant of
C 6 H 6 is) 5.12°C/m)
50. A solute a dimerizes in water. The boiling point of a
2 molar solution of A is 100.52∘ C . The
percentage association of A is¿¿
(Round off to the Nearest integer)
[Use : K b for water ¿ 0.52 Kkg mol−1
Boiling point of water ¿ 100∘ C ]

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