Name ................................................

TUITION EXAM
Batch.................... Roll No. ...............

Class - XII
25-06-2023

24V
TP/TUITION Solutions
Time: 1 Hr. Mark: 100

1. ______ obeys Raoult’s law in all stages of concentration

A) A non-ideal solution B) An ideal solution
C) A real solution D) Both A and C
2. Calculate the osmotic pressure of 0.1A glucose solution at 270C (R= 0.082)
A) 246 atm B) 24.6 atm C) 0.246 atm D) 2.46 atm
3. Which among the following gas will greatly deviate from Henry’s law in water?
A) H2 B) N2 C) CH4 D) CO2
4. Molefraction of a component A in the mixture AB

nB nA nB nA  nB
A) x A  n  n B) x A  n  n C) x A  n D) x A  nB
A B A B A

5. Among the following, lowest vapour pressure is excerted by:

A) Rectified spirit B) Absolute alcohol C) Mercury D) Water
6. Example of a solid solution is:
A) Camphor in Nitrogen gas B) Ethanol dissolved in water
C) Oxygen dissolved in water D) Solution of hydrogen in palladium
7. Which of the following pairs will exhibit negative deviation?
A) CCl4 + C6H6 B) H2O + CH3OH
C) H2O + C2H5OH D) CHCl3 + C6H6
8. The percentage of dissociation of Ca(NO3)2 in dilute aqueous solution is 70%. The Van’t Hoff factor is
A) 2 B) 2.2 C) 2.4 D) 2.8
9. The sum of the molefractions of all the components in a solution is always:
A) equal to zero B) equal to one C) greater than one D) less than one
10. An example of a solution having liquid in gas is
A) Sugar solution B) Dry air C) Au-Hg D) Moist air
11. Which of the following has molarity = normality?
A) NaOH B) HCl C) H3PO2 D) All
12. Henry’s law is not applicable for the dissolution of NH3(g) in water because
A) The process is endothermic B) NH3 is less polar than water
C) Solubility of NH3 in water is very small D) NH3 reacts with solvent water
13. The vapour pressure of a solution of nonvolatile solute in volatile solvent is proportional to
A) molefraction of solute B) total volume of solution
C) mass of solute D) molefraction of solvent
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14. For a solution of acetone and chloroform

A) Vmixing  0 B) Vmixing  0 C) Vmixing  0 D) Vmixing  0

15. A solution contains 95% ethanol by weight, the mole fraction of ethanol will be
A) 0.881 B) 0.99 C) 0.118 D) 0.71
16. 5.85 g NaCl is dissolved in water and solution made up to 500 ml. The molarity of the solution is:
A) 0.1 B) 0.2 C) 1 D) 0.117
17. Which pair from the following will not form an ideal solution?

A) C6H6 + C6H5CH3 B) H 2O  C4 H 9OH

C) C 2 H 5 Br  C 2 H 5 I D) C6 H14  C 7 H16
18. Formation of a solution from two components can be considered as
i) Pure solvent separated solvent molecules, H1

ii) Pure solvent separated solute molecules, H 2

iii) Separated solvent and solute molecules solution, H 3 solution so formed will be ideal if

A) Hsoln  H3  H1 H 2 B) Hsoln  H1  H2  H3

C) Hsoln  H1  H2  H3 D) Hsoln  H1  H2 H3

19. Equal volume of 0.1 M urea and 0.1 M glucose are mixed. The mixture will have
A) Lower osmotic pressure B) Same osmotic pressure
C) Higher osmotic pressure D) None of these
20. The vapour pressure curves of the same solute in the same solvent are shown. The curves are parallel to
each other and do not intersect. The concentration of solutions are in order of :

A) I < II < III B) I = II = III C) I > II > III D) I > III > II

21. The total vapour pressure of a mixture of 1 mol of volatile component A  P10  100 mm Hg  and 3 mol

of volatile component B  P2 0  80 mm Hg  is 90 mmHg. For such case :

A) there is a positive deviation from Raoult’s law

B) boiling point has been lowered
C) force of attraction between A and B is smaller than that between A and A or between B and B
D) all the above statements are correct
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22. Osmosis result from

A) Increase in entropy in semi permeable
B) decrease in internal energy of less diluted solution
C) decrease in internal energy of less diluted solution
D) decrease in entropy of more diluted solution
23. A binary liquid solution is prepared by mixing n-heptane and ethanol. Which one of the following statements
is correct regarding the behaviour of the solution ?
A) The solution is non-ideal, showing -ve deviation from Raoult’s Law
B) The solution is non-ideal, showing +ve deviation from Raoult’s Law
C) n-heptane shows +ve deviation while ethanol shows -ve deviation from Raoult’s Law.
D) The solution formed is an ideal solution
24. PA and PB are the vapour pressure of pure liquid components, A and B, respectively of an ideal binary
solution. If XA represents the mole fraction of component A, the total pressure of the solution will be

A) PA  XA  PB  PA  B) PA  XA  PA  PB 

C) PB  XA  PB  PA  D) PB  XA  PA  PB 

25. Which of the following statement is correct if the intermolecular forces in liquids A, B and C are in the order
A<B<C?
A) B evaporates more readily than A B) B evaporates less readily than C
C) A and B evaporates at the same rate D) A evaporates more readily than C
26. Choose the correct statement with respect to the vapour pressure of a liquid among the following :
A) Increases linearly with increasing temperature
B) Increases non-linearly with increasing temperature
C) Decreases linearly with increasing temperature
D) Decreases non-linearly with increasing temperature
27. Determination of the molar mass of acetic acid in benzene using freezing point depression is affected by :
A) Partial ionization B) Dissociation C) Complex formation D) Association
28. (i) A 0.5 m NaBr solution has a higher vapour pressure than a 0.5 m BaCl2 solution at the same temperature
(ii) Pure water freezes at the higher temperature than pure methanol
(iii) A 0.1 m NaOH solution freezes at a lower temperature than pure water
Choose the correct answer from the codes given below
A) (i), (ii) and (iii) B) (i) and (ii) C) (ii) and (iii) D) (i) and (iii)
29. If  is the degree of dissociation of Na2SO4, the vant Hoff’s factor (i) used for calculating the molecular
mass is
A) 1  B) 1  C) 1  2 D) 1  2
30. In countries nearer to polar region, the roads are sprinkled with CaCl2. This is
A) to minimise the snow present on roads
B) to minimise pollution
C) to minimise the accumulation of dust on the road
D) to minimise the wear and tear of the roads
Name ................................................
TUITION EXAM
Batch.................... Roll No. ...............

Class - XII
25-06-2023

24V
TP/TUITION Solutions
Time: 1 Hr. Mark: 100
1. B
2. D
3. D
4. B
5. C
6. D
7. D

8. C   70%  0.7 ; i  1   n  1    1   3  1  0.7   2.4

9. B
10. D
11. D
12. D
13. D
14. C

95 / 46
15. A 95% ethanol means 95 g ethanol in 100g solvent X2   0.881
95 / 46  5 / 18
16. B
17. B
18. B
19. B
20. A Elevation in boiling point concentration of a solution. Thus, the order of concentration of solution is
I < II < III.

21. D pideal  p0A xA  p0B xB

1 3
 100   80   85 mm Hg
4 4

pactual  90 mm Hg
22. D
23. B

24. D P  PAXA  PBXB  PAXA  PB 1  XA   PAXA  PB  PBXA  PB  XA  PA  PB 

25. D
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26. B If we plot a graph between the vapour pressure and the temperature. We would get a curve that
rises faster as T increases, giving a curved line

27. D Acetic acid contain carboxyl group -COOH which can form H-bonding so acetic acid dimerises.

28. D Colligative properties depends upon the number of particles. Since methanol is non electrolyte hence
cannot be considered.

Na 2SO 4  2Na   SO 42

29. C Mol.before dissociation 1 0 0
Mol.after dissociation 1  2 1

i  1    2    1  2
30. A