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1.Which of the following does not define solubility?

A. the concentration of solute in a saturated solution


B. the moles of solute dissolved in a given volume of solution
C. the maximum mass of solute that can dissolve in a given volume of solution
D. the minimum moles of solute needed to produce one litre of a saturated solution
2.To determine the solubility of a solute in water, a solution must be prepared
that is
A. saturated. B. unsaturated. C. concentrated. D. supersaturated.
2. Which among the following is an example of a solid solution?
(a) Copper dissolved in gold (b) Ethanol dissolved in water
(c) Glucose dissolved in water (d) Sodium chloride dissolved in water
6. Which of the following does not dissolve in benzene?
(a) Naphthalene (b) Toluene (c) C 6H12O6 (d) All of the above
8. How does the solubility of gasses in a liquid vary with increase in
temperature?
(a) Increases with temperature (b) Decreases with temperature
(c) First increases and then decreases (d) No effect
10. Choose the correct example for a non-ideal solution?
(a) Benzene + Toluene (b) Hexane + Heptane
(c) Chlorobenzene + Bromobenzene (d) Ethanol + Hexane
12. Which condition holds for a non-ideal solution?
(a) Change in volume is zero (b) Change in volume is non-zero
(c) Change in enthalpy is zero (d) None of the above
14. How is Henry’s constant dependent on temperature?
(a) Directly proportional (b) Inversely proportional
(c) Varies exponentially (d) None of the above
17.The pair of miscible liquids among the following is
(a) Oil and water (b) Kerosene and water
(c) Vegetable oil and corn syrup (d) Ethanol and water
2. Which of the following concentration terms is / are independent of
temperature
a) molality b) molarity c) mole fraction d) (a) and (c)
20.Consider the three statements below. Which statement(s) is(are) true?
1. Hydration is a special case of solvation in which the solvent is water.
2. The oxygen end of water molecules is attracted toward Ca 2+ ions.
3. The hydrogen end of water molecules is attracted toward Cl - ions.
(a) 1 only (b) 2 only
(c) 3 only (d) 1, 2, and 3
21.Consider the following pairs of liquids. Which pairs are miscible?
1. benzene, C6H6, and hexane, C6H12
2. water and methanol, CH3OH
3. water and hexane
(a) 1, 2 only (b) 2 only (c) 1 only (d) 1, 2, 3

4.What is the molality of a solution labeled "8.6% glucose (C6H12O6) by weight?"


(Note: If the question does not give the solvent, assume it is water.)
(a) 0.26 m (b) 0.34 m (c) 0.44 m (d) 0.52 m

5.Calculate the mole fraction of C2H5OH in a solution that contains 46 grams of


ethanol, C2H5OH, and 64 grams of methanol, CH3OH.
(a) 1/3 (b) 0.42 (c) ½ (d) 2/3
6.Which observation(s) reflect(s) colligative properties?
(I) A 0.5 m NaBr solution has a higher vapor pressure than a 0.5 m
BaCl2 solution.
(II) A 0.5 m NaOH solution freezes at a lower temperature than pure water.
(III) Pure water freezes at a higher temperature than pure methanol.
(a) only I (b) only II (c) only III (d) I and II
7.The vapor pressure of pure water at 85 C is 434 torr. What is the vapor pressure at
o

85oC of a solution prepared from 100 mL of water (density 1.00 g/mL) and 150 g of
diglyme, C6H14O3, a nonvolatile substance?
(a) 361 torr (b) 390 torr (c) 425 torr (d) 388 torr
8.The vapor pressure of a solution containing a nonvolatile solute is directly
proportional to the
(a) molality of the solvent.
(b) osmotic pressure of the solute.
(c) molarity of the solvent.
(d) mole fraction of solvent.
3. Stomach acid, a dilute solution of HCl can be neutralised by reaction with Aluminium
hydroxide

Al (OH)3 + 3HCl (aq) → AlCl3 + 3 H2O

How many millilitres of 0.1 M Al(OH)3 solution are needed to neutralise 21 mL of 0.1 M
HCl ?

a) 14 mL b) 7 mL c) 21 mL d) none of these

8. P1 and P2 are the vapour pressures of pure liquid components, 1 and 2


respectively of an ideal binary solution if x1 represents the mole fraction of
component 1, the total pressure of the solution formed by 1 and 2 will be

a) P1 + x1 (P2 – P1) b) P2 – x1 (P2 + P1)


c) P1 – x2 (P1 – P2) d) P1 + x2 (P1 – P2)

9. Osometic pressure (p) of a solution is given by the relation

a) π = nRT b) πV = nRT c) πRT = n d) none of these

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