BASCHEM

Reviewer 1st Term AY: 2018-2019

Name: ____________________________ ID: ______________________ Section: _______

1. Which of the following is a qualitative statement? 9. What is the mass % of Fe in Fe4[Fe(CN)6]3?

A. The melting point of lead is 327.5°C. A. 37.27% D. 45.41%
B. A can of soda has a volume of 355 mL. B. 45.47% E. 45.48%
C. 71.46%
C. A necklace is 58.3% gold.
D. The density of ice at 0°C is 0.917 g/mL. 10. The species 3216S2− contains
E. Water is a molecule composed of hydrogen and A. 16 protons and 16 electrons.
oxygen atoms. B. 16 protons and 18 electrons.
C. 18 electrons and 32 neutrons.
2. Which of the following is not a physical property? D. 16 protons and 18 neutrons.
A. Pressure D. Heat capacity E. 18 protons and 16 neutrons.
B. Hardness E. Reactivity 11. The Hall process for the production of aluminum
C. Temperature involves the reaction of aluminum oxide with
3. Which of the following describes a chemical change? elemental carbon to give aluminum metal and
carbon monoxide. If the yield of this reaction is 75%,
A. Ethanol is a clear, colorless liquid.
what mass of aluminum metal can be produced from
B. Ethanol can be produced by the fermentation of the reaction of 1.65  106 g of aluminum oxide with
grapes. 1.50  106 g of carbon?
C. Ethanol evaporates quickly at room temperature. A. 1.6  105 g D. 3.3  105 g
D. Ethanol has a high heat capacity B. 6.6  10 g5
E. 8.7  105 g
E. Ethanol boils when heated. C. 1.7  106 g
4. Sugar, coffee and bismuth are 12. Aluminum hydroxide reacts with nitric acid to form
A. an element, a homogeneous mixture, and a pure aluminum nitrate and water. What mass of water
substance. can be formed by the reaction of 15.0 g of aluminum
hydroxide with excess nitric acid?
B. a pure substance, a heterogeneous mixture, and
A. 1.15 g D. 3.46 g
an element. B. 45.0 g E. 6.14 g
C. a homogeneous mixture, a pure substance, and C. 10.4 g
a homogeneous mixture.
13. What is the wavelength of radiation that has a
D. an element, a pure substance, and a
frequency of 3.4 x 1011 s–1?
homogeneous mixture. A. 8.8 x 10-4 nm D. 8.8 x 105 nm
E. none of these choices. -13
B. 8.8 x 10 nm E. 1.0 x 1011 nm
5. Who is the father of atomic theory? C. 1.0 x 10-9 nm
A. Bohr D. C. J. J. Thomson 14. Which one of the following sets of quantum numbers
B. Rutherford E. Dalton represents an electron with the highest energy?
C. Curie
A. n = 3, l = 2, ml = -2, ms = +1/2
6. What was discovered on the alpha-scattering B. n = 4, l = 1, ml = 0, ms = -1/2
experiment of Rutherford? C. n = 4, l = 0, ml = 0, ms = +1/2
A. Electrons D. Neutrons D. n = 5, l = 0, ml = 0, ms = +1/2
B. Light E. Nucleus
E. n = 4, l = 2, ml = -1, ms = -1/2
C. Quantum
15. Which of the following electronic transitions is
7. The __________ of the reaction is the quantity of
product calculated to form when the entire limiting consistent with a decrease in energy?
reagent reacts. A. From a 5s subshell to a 4d subshell
A. Theoretical yield D. Percent yield B. From a 4f subshell to a 5p subshell
B. Actual yield E. % composition C. From a 6s subshell to a 5d subshell
C. Formula D. From a 5s subshell to a 5p subshell
8. All of the following has amount in grams E. From a 4f subshell to a 6p subshell
approximately less than 100 g EXCEPT
16. What is the maximum number of electrons in an
A. 1.2 moles NH3. D. 1.0 mol H2O.
atom that can have the following set of quantum
B. 0.1 mol I2. E. 1.0 mol C7H16.
C. 1.0 mol SO2. numbers? n = 4 l = 3 ml = –2 ms = +1/2
A. 0 C. 1
B. 2 D. 6
EXAM VERSION 1 1
17. Concerning the electron configuration of fluorine, Refrigerant-10 in HVACR is an organic compound
1s22s22p5 which of the following represents the core with the chemical formula CCl4. When its Lewis
electrons only? structure is drawn, it will show that there are four
single __________ bonds connecting the four Cl
A. 1s2 D. 1s22s2
atoms to the central C atom, giving a __________
B. 1s22s22p5 E. 2s22p5 shape as predicted by VSEPR theory.
5
C. 2p A. nonpolar covalent, trigonal pyramidal
18. Which one of the following pairs are isoelectronic? B. nonpolar covalent, tetrahedral
C. polar covalent, trigonal pyramidal
A. Mn2+ and Ar D. Zn2+ and Cu2+
+ +
D. polar covalent, tetrahedral
B. Na and K E. Cl– and S E. polar covalent, linear
C. K+ and Cl–
19. What kind of chemical bond will form between two 25. Consider the following bonds: H-F; H-O; H-N; and H-
C. If these bonds will be arranged in increasing
oxygen atoms?
polarity (with most polar bond last), what would be
A. ionic bond their sequence?
B. metallic bond A. H-C < H-F < H-N < H-O
C. coordinate covalent bond B. D. H-O < H-N < H-F < H-C
D. polar covalent bond C. H-C < H-N < H-O < H-F
E. nonpolar covalent bond D. H-F < H-C < H-O < H-N
20. When does covalent bonding take place? E. H-N < H-O < H-C < H-F
A. It takes place when an atom loses electrons to 26. Choose two elements that would likely form an
another atom. ionic bond: Li, Si, F, Ne
B. It takes place when atoms share electrons with A. Li and Si D. Si and F
one another. B. Ne and Si E. Li and F
C. It takes place when the attraction between C. F and Ne
atoms is strong.
D. It takes place when atoms collide with one 27. What volume of CH4 at 0 ⁰C and 1 atm contains the
another. same number of molecules as 0.50 L of N2 measured
E. It takes place when atoms attain stability. at 27 ⁰C and 1.50 atm?
A. 0.37 L D. 0.46 L
21. How does ionic bonding take place? B. 0.68 L E. 0.50 L
A. Two non-metallic elements of different kinds C. 0.82 L
form strong forces of attraction.
32. Which of the following has the most molecules?
B. Two non-metallic elements of different kinds
A. 1.00 L of CH4 at 0°C and 1.00 atm
form weak forces of attraction.
B. 1.00 L of N2 at 0°C and 1.00 atm
C. Two non-metallic element of the same kind form
C. 1.00 L of O2 at 20°C and 1.00 atm
strong forces of attraction.
D. 1.00 L of CO2 at 50°C and 1.25 atm
D. A non-metallic element like fluorine is attracted
E. 1.00 L of CO at 0°C and 1.25 atm
to a metallic element like sodium.
E. A metallic element like sodium transfers an 33. At what temperature will a sample of nitrogen gas
electron to a non-metallic element like fluorine. with a volume of 328 mL at 15C and 748 mmHg
occupy a volume of 0.898 L at a pressure of 642 mm
22. What kind of particle is produced after covalent Hg? Assume the amount of the nitrogen gas does not
bonding? change.
A. atom D. molecule A. 676C D. 404C
B. cation E. anion B. 396C E. 274C
C. electron C. 123C
23. How is the bond in Br2 different from the bond in 34. Calculate the number of moles of gas contained in a
MgF2? 10.0 L tank at 22C and 105 atm.
A. The bond in Br2 is ionic while the bond in MgF2 is A. 1.71  10–3 mol D. 0.0231 mol
nonpolar covalent. B. 1.03 mol E. 43.4 mol
B. The bond in Br2 is ionic while the bond in MgF2 is C. 582 mol
polar covalent.
C. The bond in Br2 is nonpolar covalent while the 35. Calculate the grams of SO2 gas present at STP in a 5.9
bond in MgF2 is ionic. L container.
D. The bond in Br2 is polar covalent while the bond A. 0.24 g D. 0.26 g
in MgF2 is ionic. B. 15 g E. 17 g
E. There is no bond difference between the two. C. 64 g

24. Carbon tetrachloride, also known by many other

names: tetrachloromethane, carbon tet in the
cleaning industry, Halon-104 in firefighting, and
2
36. The rate law of a reaction is: rate = k [D][X]0. The 42. Methyl orange is an indicator used in acid-base
unit of the rate constant is titrations.
A. M/ s C. M-1 s-1 H-MeOr (aq) H+ (aq) + MeOr-(aq)
-1
B. s D. M-2 s-1 (red) (yellow)
What will be the color of a mixture of distilled water
37. Which of the following is true for a zero-order
and methyl orange if large amount of NaOH is
reaction?
added to it?
A. The rate constant is equal to zero.
A. Orange C. Yellow orange
B. The activation energy is equal to zero.
B. Yellow D. Red
C. The rate of reaction is independent of the
reactant concentration. 43. What is the equilibrium constant expression for the
D. The half-life is equal to 1/k reaction given below?
4 NH3(g) + 5 O2(g) 4 NO(g) + 6 H2O(g)
38. At a certain temperature the following data were
A.
collected for the reaction:
2 NO + ½ Cl2  2 NOCl

[NO] (M) [Cl2] (M) rate of formation of B.

NOCl (M/s)
0.22 0.064 0.96
0.66 0.064 8.6 C.
0.22 0.32 4.8

The rate law for this reaction is D.

A. rate = k [NO]2[Cl2]1/2
B. rate = k [NO]2[Cl2]5
C. rate = k [NO]2[Cl2]
D. rate = k [NO] [Cl2]2 44. Consider the equilibrium reaction
For numbers 40 and 41: 2N2(g) + O2(g) 2N2O(g)
The conversion of a hypothetical compound  to  In a particular experiment, the equilibrium
in the gas phase is believed to proceed via a first concentration of N2 is 0.048 M, of O2, 0.093 M, and
order reaction with a rate constant of 6.7 x 10-4 / of N2O, 6.55 × 10-21 M. What is the value of the
sec at 620C. ( →  ) equilibrium constant Kc?
A. 1.5 × 10-18
39. If the concentration of  was 0.25 M, what is its B. 2.0 × 10-37
concentration after 8.8 minutes? C. 2.2 × 10-36
A. 0.18 M C. 0.348 M D. 3.1 × 10-17
B. 5.68 M D. 0.491 M E. 5.0 × 1036
40. The half-life of this reaction is 45. Consider the endothermic reaction
A. 17 min C. 5.6 × 10-6 min C(s) + CO2(g) 2CO(g)
B. 30 min D. 23 min If such a system at equilibrium is heated, equilibrium
41. The rate law for the reaction will _____, because _____.
2NO2 + O3 → N2O5 + O2 is rate = k[NO2][O3]. A. be unchanged; temperature has no effect on
Which one of the following mechanisms is consistent equilibrium
with this rate law? B. shift to the left; increased temperature favors
an exothermic reaction
A. NO2 + NO2 → N2O4 (fast) C. shift to the right; increased temperature favors
N2O4 + O3 → N2O5 + O2 (slow) an exothermic reaction
D. shift to the right; increased temperature favors
B. NO2 + O3 → NO5 (fast) an endothermic reaction
5
NO5 + NO5 → N2O5 + /2O2 (slow) E. shift to the left; increased temperature
favors an endothermic reaction
C. NO2 + O3 → NO3 + O2 (slow) 46. Which is the conjugate base of HSO4-?
NO3 + NO2 → N2O5 (fast) A. H2SO4 D. SO42-
B. H2SO3 E. HSO3-
D. NO2 + NO2 → N2O2 + O2 (slow) C. SO32-
N2O2 + O3 → N2O5 (fast)
47. What is the pH of 1.80 ×10-5 M HI solution?
A. 1.80 D. 9.26
B. 4.74 E. 12.20
C. 5.00

3
48. What is the pH of 0.0010 M KOH solution? 56. Consider a solution initially containing 0.500 mol
A. 1.00 D. 3.00 ammonia (NH3) and 0.300 mol of ammonium ion
B. 5.00 E. 9.00 (NH4+). How many moles of ammonia and how many
C. 11.00 moles of ammonium ion are present after addition
of 40 mL of 0.800M NaOH to this solution?
49. For nitrous acid, HNO2, Ka = 4.5 x 10-4. What is the
A. 0.532 mol NH3, 0.268 mol NH4+
equilibrium constant for the following reaction?
B. 0.532 mol NH3, 0.332mol NH4+
NO2- + H2O HNO2 + OH-
C. 0.468 mol NH3, 0.268 mol NH4+
A. 2.2 × 10-11 D. 2.2 × 103
-18 D. 0.700 mol NH3, 0.100 mol NH4+
B. 4.5 × 10 E. 4.5 × 10-10
-4 E. None of the above
C. 4.5 × 10
57. The oxidation number of sulphur in Na2SO4 is
50. What is the [H3O+] of a solution of HNO3 whose pH is
A. 2-
4.5?
B. 0
A. 0.65 M D. 4.5 × 10-4 M
B. 4.5 × 10-5 M E. 3.2 × 10-5 M C. 2+
C. 3.2 × 104 M D. 4+
E. 6+
51. What is the pH of a 0.25 M benzoic acid?
(Ka= 6.3 × 10-5) 58. Redox reactions are
A. 0.6 D. 4.2 A. Transfer of protons from reducing agent to
B. 2.4 E. 4.8 oxidizing agent
C. 3.6 B. Transfer of protons from oxidizing agent to
reducing agent
52. A 1.0 M solution of a weak acid has a pH of 3.0. What
is the pKa of the acid? C. Transfer of electrons from reducing agent to
A. 1.0 D. 9.0 oxidizing agent
B. 3.0 E. 12.0 D. Transfer of electrons from oxidizing agent to
C. 6.0 reducing agent
A student wishes to prepare a buffer with pH 9.00. 59. Which of the following is a redox reaction:
Which of the following pair is most appropriate for A. H3O+(aq) + NH3 (aq)  NH4+ (aq) + H2O
the student to use?
B. 2Na (s) + Cl2 (g)  2 NaCl (s)
A. C2H3O2 – C2H3O2— (Ka = 1.8 × 10-5)
C. Pb2+(aq) + 2Br-(aq)  PbBr2 (s)
B. H2PO4— – HPO42— (Ka = 6.3 × 10-8)
C. NH4Cl – NH3 (Ka = 5.6 × 10-10) D. AgNO3 (aq) + NaCl (aq)  AgCl (s) + NaNO3 (aq)
D. HCO3— – CO32— (Ka = 4.7 × 10-11) E. NaOH (aq) + HI (aq)  NaI (aq) + H2O

54. Consider an aqueous solution saturated with AgBr 60. In the complete combustion of octane, C8H18 :
-13
(Ksp= 5.0 × 10 ). What is the solubility (S) of this C8H18 (l) + 12.5 O2 (g)  8 CO2 (g) + 9 H2O (l)
salt? the oxidizing agent is
A. 3.6 × 10-5M C. 3.1 × 10-9M A. C8H18
-7
B. 7.1 × 10 M D. 4.2 × 10-11M B. O2
C. CO2
55. To simulate the pH of blood, which is 7.4, an D. H2O
undergraduate researcher in a biology lab produced
a buffer solution by dissolving sodium dihydrogen
phosphate (NaH2PO4, Ka = 6.2 x 10-8) and sodium
hydrogen phosphate (Na2HPO4) together in an
aqueous solution. What mole ratio of
Na2HPO4/NaH2PO4 did she need to use?
A. 1.2 D. 1.0
B. 1.6 E. 0.96
C. 0.90