PART 1 6.

Of the choices below, which one is not

an ionic compound?
1. If a sample of matter is uniform a. PCl5
throughout and cannot be separated b. MoCl6
into other substances by physical c. RbCl
means, it is _______. d. PbCl2
a. a compound e. NaCl
b. either a compound or an element
c. a homogenous mixture 7. Boron has two naturally occurring
d. a heterogenous mixture isotopes, 10B with an atomic mass of
e. an element 10.0129370 amu and 11B with an
atomic mass of 11.0093054 amu. The
2. What volume of 10.0 M H2SO4 is atomic mass of boron is 10.81 (from
required to prepare 4.0 L of 0.50 M the periodic table). The percent
H2SO4? abundances of the boron isotopes are
a. 0.2 L __________% 10B and __________%
b. 0.4 L 11 B
c. 0.5 L a. 81.0, 19.0
d. 1 L b. 9.9, 90.1
e. 4 L c. 49.0, 51.0
d. 20.0, 80.0
3. A solution of silver nitrate is mixed with e. 1.0, 99.0
a solution of potassium fluoride. If a
precipitate forms, the precipitate is 8. 550 nm electromagnetic radiation is in
a. Silver fluoride what region of the electromagnetic
b. Potassium nitrate spectrum?
c. Potassium fluorate a. Ultraviolet
d. Nitric fluoride b. Visible
e. No precipitate is formed c. Infrared
d. Microwave
4. If 5.0 mol of both hydrochloric acid and e. X-ray
sodium sulfide are mixed and reacted
according to the equation below, how 9. Which of the following choices is false
many moles of hydrogen sulfide (H2S) regarding the wave amplitude of
are produced? electromagnetic radiation? (circle all
that apply)
a. 1 mol a. For visible light, a larger wave
b. 1.25 mol amplitude correlates with a
c. 2.5 mol brighter light
d. 3 mol b. A larger wave amplitude
e. 5 mol correlates with higher energy
photons
5. Which of the following is not a physical c. A larger wave amplitude
process correlates with a larger number of
a. distillation photons
b. filtration d. A larger wave amplitude
c. chromatography correlates with a longer
d. evaporation wavelength
e. none of the above
 e. A larger wave amplitude b. P
correlates with increased wave c. N
speed d. B
e. Be

16. Order the elements S, Cl, and F in

10. Which of the following compounds will
terms of increasing atomic radii.
not undergo an acid-base
a. S, Cl, F
(neutralization) reaction with HClO4
b. Cl, F, S
a. NaOH
c. F, S, Cl
b. Sr(OH)2
d. F, Cl, S
c. NH3
e. S, F, C
d. Na2CO3
e. H2SO4
17. Which of the following statements
11. If the ∆H° for the reaction, 2 Mg (s) + 2 is true?
Cl2 (g) → 2 MgCl2 (s), is -1283.6 kJ, a. Electrons are never found in an
what is the standard enthalpy of antibonding MO.
formation of magnesium chloride? b. Antibonding MOs have electron
a. 0 kJ/mol density mainly outside the space
b. -320.9 kJ/mol between the two nuclei.
c. -641.8 kJ/mol
c. None of the above is true
d. 1283.6 kJ/mol
d. Two of the above statements are
e. -1283.6 kJ/mol
true
12. Which of the following pairs of
atoms/ions is isoelectronic? 18. Which of the following is not a
–2
a. O , S –2 homogenous mixture
b. Na, Na +1 a. air
–1
c. Br , Kr b. copper
d. Cu, Zn c. brass
e. none of these d. 1 M NaCl
13. Which of the following quantum e. all of the above are homogenous
number sets describes a 4f orbital?
a. n=2, l=0, ml = 0 19. What mass of CaCl2 is required to
b. n=3, l=1, ml = -1 prepare 500mL of a 0.2 M solution of
c. n=3, l=2, ml = -1 CaCl2?
d. n=4, l=2, ml = +1 a. 0.2 g
e. n=4, l=3, ml = +2 b. 0.1 g
c. 22.2 g
14. Which element below has the largest d. 11.1 g
atomic radius? e. none of the above
a. S
b. P 20. You determine the mass of a sample
c. N by taking the following measurements:
d. B 30.014 g, 30.010 g, 30.001 g, 30.021
e. F g. Given the choices below, what is the
best way to report the mass?
15. Which element below has the highest a. 30.001-30.021 g
electronegativity? b. 30.0115 g
a. C c. 30.012 g
 d. 30.01 g b. In both techniques, the volume
e. 30.0 g remains constant
c. in both techniques, work is zero
d. in both techniques, a compound
21. The combustion of triethylene glycol is is always burned in excess
shown below. When the reaction is oxygen
balanced with integer coefficients, e. in both techniques, heat flows are
what is the coefficient in front of O2? measured through temperature
changes
a. 6
26. which of the following statement is
b. 12
false regarding electromagnetic
c. 15
radiation?
d. 14
a. electromagnetic radiation is a
e. none of the above
form of energy transmission
b. visible light is a type of
22. Of the choices below, which one is an
electromagnetic radiation
ionic compound?
c. wavelength and frequency
a. N2
are inversely proportional
b. NO2
d. electromagnetic radiation only
c. NF3
exist at certain, discrete
d. NH3
wavelengths
e. NH4Cl
e. for electromagnetic radiation,
higher frequency corresponds
23. The formula of a salt is XCl2. The X-ion
to higher energy
in this salt has 28 electrons. The metal
X is?
27. The heat of formation of lead (II)
a. Zn
carbonate is -699 kJ/mol. Which
b. Cu
equation below best represents this
c. Fe
process?
d. Co
a. 𝑃𝑏( ) + 𝐶( ) + 𝑂 ( ) → 𝑃𝑏𝐶𝑂 ( )
e. Ni
b. 𝑃𝑏( ) + 𝐶( ) + 𝑂 ( ) → 𝑃𝑏𝐶𝑂 ( )
24. Silver has two naturally occurring c. 2𝑃𝑏( ) + 𝐶( ) + 3𝑂 ( ) → 2𝑃𝑏𝐶𝑂 ( )
isotopes 107Ag (106.90509 amu) and d. 𝑃𝑏𝐶𝑂 ( ) → 𝑃𝑏( ) + 𝐶( ) + 𝑂 ( )
109Ag (108.90475 amu). The average
e. 2𝑃𝑏𝐶𝑂 ( ) → 2𝑃𝑏( ) + 𝐶( ) + 3𝑂 ( )
atomic mass of silver is 107.8682 amu.
The fractional abundance of 107Ag is:
a. 0.3817 28. Which of the following properties would
b. 0.7578 not influence the conductivity of a
c. 0.2422 solution
d. 0.5184 a. the concentration of the ions
e. 0.9047 present
b. the number of ions present
25. Which of the following is true regarding c. the molar conductivity of the ions
bomb calorimetry and constant present
pressure calorimetry? d. the size of the container
a. Bomb calorimetry and constant e. all of the above influence solution
pressure calorimetry are the same conductivity
technique
29. Electrons in helium atoms transition 33. Order the ions Na+1, Mg+2, and Al+3
from the 5th to the 2nd energy shell. If in terms of increasing ionic radii.
you observe the electromagnetic a. Na+1, Mg+2, Al+3
radiation that results, what would you b. Mg+2, Al+3, Na+1
observe? c. Al+3, Na+1, Mg+2
a. An emission spectrum with one d. Al+3, Mg+2, Na+1
line e. Na+1, Al+3, Mg+2
b. A continuous spectrum
c. An absorption spectrum with 34. Which of the following quantum
multiple “dark” lines number sets describes a 4d orbital?
d. An absorption spectrum with a a. n=4, l=2, ml= 0
single “dark” line b. n=2, l=4, ml=-1
e. White light c. n=3, l=2, ml= -1
d. n=3, l=1, ml= +1
30. Consider the following four cases: e. n=4, l=1, ml= 2
i. A chemical process in which heat
is absorbed 35. Which compound below has the
ii. A change in which Q=30 J and W largest lattice energy
= 44J a. KCl
iii. A process in which a system does b. LiCl
work in its surroundings with no c. KI
change in Q d. NaI
iv. A process in which work is done e. LiF
on a system and an equal amount
of heat is withdrawn 36. Which molecule/ion below has the
In how many of these cases does the largest dipole?
internal energy of the system decrease? a. CO2
b. SiH4
a. 0 c. SO2
b. 1 d. BF4-1
c. 2 e. F2
d. 3
e. 4
For questions 37-40
31. Which ion with a +2 charge has the
electron configuration 1s2 2s2 2p6 3s2 Choices are:
3p6 3d10?
a. 3s
a. K
b. 2p
b. Si
c. 4d
c. Zn
d. 1s
d. Ca
e. Ge
37. What has the lowest energy
38. What has one planar or angular node
32. Which of the following elements has
39. What has 2 total nodes
the lowest first ionization energy?
40. What is one of a set of 5 degenerate
a. Be
orbitals
b. Mg
c. Ca
41. Of the following species, ________
d. S
has the largest radius.
e. Si
a. Rb+
 b. Sr2+ 47. A solid is a state of matter that has
c. Br- a(n)
d. Kr a. indefinite volume and an indefinite
e. Ar shape.
b. definite volume and a definite
42. Of the following atoms, which has the shape.
largest first ionization energy? c. definite volume and an indefinite
shape.
a. K d. indefinite volume and a definite
b. Rb shape.
c. Sr
d. Ca 48. In which state of matter are particles
e. Ba packed tightly together in fixed
positions?
43. Which of the following kinds of a. Gas
electromagnetic radiation has the b. Solid
highest energy per photon? c. Liquid
a. visible light d. Compound
b. ultraviolet light
c. infrared light 49. The state of matter in which particles
d. microwaves are arranged in either a crystalline or
e. radio waves an amorphous form is
a. liquid.
44. Which of the following ionic b. gas.
compounds possesses the smallest c. solid.
magnitude lattice energy? d. fluid.
a. NaF
b. NaCl 50. Particles of a liquid
c. NaBr a. are tightly packed together and
d. NaI stay in a fixed position.
e. CsI b. have no viscosity.
c. decrease in volume with
45. Which of the following sets of quantum increasing temperature.
numbers (n, l, ml, ms) describes the d. are free to move in a container but
highest energy electron of potassium remain in close contact with one
in its ground state? another.
a. 4, 0, 0, +½
b. 3, 0, 0, +½ 51. The surface of water can act like a sort
c. 3, 2, -2, -½ of skin due to a property of liquids
d. 4, 3, +3, +½ called
e. 4, 2, -2, -½ a. viscosity.
b. surface tension.
46. Which of the following bonds is most c. condensation.
ionic? d. evaporation.
a. H—Cl
b. F—Cl 52. In which state of matter do the
c. O—Cl particles spread apart and fill all the
d. Cs—Cl space available to them?
e. Li—Cl a. Crystal
b. Liquid
 c. Gas
d. Solid
53. The change from liquid to solid, or the
reverse of melting, is called
a. condensation.
b. boiling.
c. sublimation.
d. freezing.
54. The freezing point of water is the same
as its
a. melting point.
b. boiling point.
c. sublimation point.
d. evaporation point.
55. What is vaporization?
a. a gas becoming a liquid
b. a liquid becoming a solid
c. a gas becoming a solid
d. a liquid becoming a gas
56. Which state of matter undergoes
changes in volume most easily?
a. Solid
b. Liquid
c. Gas
d. Frozen
57. The greater the speed of gas particles
in a container, the
a. fewer collisions there will be.
b. lower the temperature.
c. greater the pressure.
d. lower the pressure.
58. During the process of sublimation,
a. solid turns directly into a gas.
b. a solid turns into a liquid.
c. a gas turns directly into a solid.
d. a liquid turns into a gas.
59. In which of the following pairs of
characteristics of an element are the
temperatures the same?
a. boiling point and freezing point
b. condensation point and melting
point
c. freezing point and condensation
point
d. melting point and freezing point
60. Which of the following will occur as the
speed of the molecules in a substance
increases?
a. The substance will become cooler.
b. The substance will begin to take
up less space.
c. The force of attraction between
the molecules will decrease.
d. The force of attraction that draws
objects to Earth will increase.
61. Figure 5 shows how the temperature of
a substance changed as it was heated.
Which segment of the graph indicates
that the substance was undergoing a
change of state?
a. A
b. B
c. C
d. D
62. An uncovered pot of soup is simmering
on a stove, and there are water
droplets on the wall above the back of
the stove. What sequence can you
infer has occurred?
a. melting, then boiling
b. freezing, then thawing
c. vaporization, then condensation
d. condensation, then vaporization
63. According to Boyle’s law, when the
pressure of a gas increases at
constant temperature, its volume
a. increases.
b. stays constant.
c. decreases.
d. increases, then decreases.
64. When the temperature of a gas
decreases at constant volume, its
a. pressure increases.
b. mass increases.
c. pressure decreases.
d. particles move faster.
65. According to Charles’s law, when the d. Freezing
temperature of a gas increases at
constant pressure, its 71. Which of the following is NOT true for
a. volume increases. the Group 1A elements?
b. mass increases. a. Most of them are soft, silvery
c. volume decreases. corrosive metals.
d. particles move more slowly. b. Their atomic radii increases with
increasing molecular weight.
66. Which of the following examples c. They are named the alkaline earth
involves an exothermic change? metals.
a. ice melting on a warm day d. They are excellent conductors of
b. water boiling in a tea kettle heat and electricity.
c. gaseous water particles coming e. They exhibit a +1 oxidation state
together to form fog in compounds.
d. air in a bicycle tire gaining
pressure after a long ride 72. Which element group is the most
reactive of all the metallic elements?
67. Boyle's law states that for a fixed a. alkali metals
amount of gas at a constant b. alkaline earth metals
a. pressure, the volume increases as c. coinage metals
the temperature decreases. d. transition metals
b. temperature, the volume e. Group 2B metals
increases as the pressure
increases. 73. In a surprisingly large number of their
c. temperature, the volume properties beryllium resembles
decreases as the pressure aluminum, and boron resembles
increases. silicon. Such a relationship is called:
d. pressure, the volume decreases a. Amphoterism
as the temperature increases. b. an allotropic relationship
c. a diagonal relationship
68. When a person wearing glasses enters d. the periodic law
a warm house after being outside on a e. an isoelectronic series
cold day, their glasses fog up because
of 74. Which of the following properties of the
a. Vaporization alkaline earth metals decreases with
b. Condensation increasing atomic weight?
c. Sublimation a. ionic radii
d. Melting b. ionization energy
c. atomic radii
69. Which of the following is an d. activity
endothermic change? e. atomic number
a. melting
b. freezing 75. Of the following oxides, the most basic
c. condensation is:
d. all of the above a. MgO
b. Na2O
70. The opposite of vaporization is called c. P2O3
a. condensation. d. BeO
b. sublimation. e. SO2
c. evaporation.
76. A 300 g sample of CaCO3 was heated d. Mn3+
until 10.0 L of CO2 was collected at e. V3+
°
50.0 C and 742 torr. What percentage
of the CaCO3 had decomposed? 82. Which of the following ion sis written
a. 6.84% correctly?
b. 9.10% a. Chlorine ion
c. 12.3% b. Potassium ion
d. 15.8% c. Oxygen ion
e. 20.6% d. Calcide ion
e. Sulfur ion
f. None of these
83. In the compound iron (III) chloride,
77. What mass of lithium nitride could be
what is the charge on the iron ion?
formed from 104 g of lithium and
a. +4
excess nitrogen gas?
b. -4
a. 35 g
c. +2
b. 60 g
d. +3
c. 105 g
d. 140 g
84. When naming an ion, of a transition
e. 174 g
metal that has more than one common
ionic charge, the numerical value of
78. The most abundant metal in the earth's
the charge is indicated by a?
crust is:
a. Prefix
a. Cu
b. Suffix
b. Fe
c. Roman numeral following the
c. Na
name
d. Al
d. Superscript
e. Ca
85. The sulfate ion is written in which of
79. Which element has the electron
the following ways?
configuration [Ar] 3d7 4s2?
a. S-2
a. Fe
b. HSO3-1
b. Co
c. SO3-2
c. Cr
d. SO4-2
d. Ti
e. Zn
86. In the compound Pt(C2H3O2)2, what is
the charge on the platinum?
80. What is the electron configuration of
3+ a. +2
Mn ion?
2 10 b. -2
a. [Ar] 4s 3d
c. +3
b. [Ar] 4s2 3d2
5 d. -3
c. [Ar] 3d
4
d. [Ar] 3d
87. Which of the following terms would
e. [Ar] 4d1 3d3
best classify a sample of pure sodium
chloride?
81. The nitrate of which of the following
a. An element
cations would exhibit paramagnetism
b. A highly reactive metal
to the GREATEST extent?
3+ c. A poisonous gas
a. Co
d. A compound
b. Cr3+
3+
c. Fe
88. Linus Pauling is famous for
a. proposing the idea of valence
octets.
b. proposing that ionic and covalent
bonds are at opposite ends of a 92. How many electrons are being shared
chemical bonding spectrum.
c. devising dot diagrams to represent
the electron configuration of
atoms.
d. discovering that there are multiple
covalent bonds between some
atoms.
89. The three dots in the Lewis dot 93. Which of the following molecules
diagram for boron indicate that it
a. can bond with three other atoms.
b. can only form triple covalent
bonds.
c. has three valence electrons.
d. scores a 3 on Pauling's
electronegativity scale.
90. Which statement is true of covalent
bonds?
a. No matter the element, there is
the same bond length between
neighboring atoms.
b. Valence electrons must be shared
equally between atoms in order to
achieve stability.
c. Covalent bonds form when the
nuclei of two atoms attract each
other.
d. Atoms find the ideal separation
distance where electrostatics
forces are reduced to a minimum.
91. If a covalent bond were to be formed
between a nitrogen atom
(electronegativity 3.0) and an oxygen
atom (electronegativity 3.5), which of
the following statements would best
describe such a bond?
a. Non-polar covalent
b. Polar covalent where the oxygen
atom carried the partial negative
charge
c. Polar covalent where the nitrogen
atom carried the partial negative
charge
d. Polar covalent where the oxygen
atom carried the partial positive
charge
between the two carbon atoms in the
compound ethyne? Ethyne has the
Lewis structure: H−C≡C−H
a. 1
b. 2
c. 3
d. 6
would one expect to have a non-polar
covalent bond?
a. HCl
b. F2
c. HF
d. ClF
94. What feature of water molecules
enables ionic substance to dissolve in
water?
a. The water molecules have a
certain shape that allows them to
surround the ions in solution.
b. The water molecules react with
the ions.
c. The water molecules are sticky
and can adhere to the ions.
d. The water molecules are polar
and are attracted to the positive
and negative ions, surrounding
them.
95. What type of intermolecular forces are
due to the attraction between
temporary dipoles and their induced
temporary dipoles?
a. metallic bond
b. London dispersion
c. hydrogen bond
d. ionic bond
e. covalent bond
96. What type of interparticle forces holds
liquid N2 together?
a. ionic bonding
b. London forces
c. hydrogen bonding
 d. dipole-dipole interaction a. HF
e. covalent bonding b. HCl
c. HBr
97. Which response includes only those d. HI
compounds that can exhibit hydrogen e. H2SO4
bonding?
CH4, AsH3, CH3NH2, H2Te, HF
a. AsH3, H2Te 100. The normal boiling point of a liquid is
b. AsH3, CH3NH2 a. the temperature at which the
c. CH4, AsH3, H2Te vapor pressure equals 760 torr.
d. CH3NH2, HF b. the temperature above which the
e. HF, H2Te substance cannot exist as a liquid
regardless of the pressure.
c. the temperature at which the gas
molecules have more kinetic
98. Which of the following boils at the
energy than the molecules in the
highest temperature?
liquid.
a. CH4
d. the only temperature at which
b. C2H6
there can be equilibrium between
c. C3H8
liquid and gas.
d. C4H10
e. the temperature at which the liquid
e. C5H12
will usually boil.
99. Which probably has the lowest boiling
point at 1.00 atm?
ANSWER KEY 24. D 50. D 76. C
Part 1 25. E 51. B 77. E
26. D 52. C 78. D
1. B 27. B 53. D 79. B
2. A 28. D 54. A 80. D
3. A 29. A 55. D 81. C
4. C 30. B 56. C 82. B
5. E 31. C 57. C 83. D
6. A 32. C 58. A 84. C
7. D 33. D 59. D 85. D
8. B 34. A 60. C 86. A
9. B,D,E 35. E 61. B 87. D
10. E 36. C 62. C 88. B
11. C 37. D 63. C 89. C
12. C 38. B 64. C 90. D
13. E 39. A 65. A 91. B
14. B 40. C 66. C 92. D
15. C 41. C 67. C 93. B
16. D 42. D 68. B 94. D
17. D 43. B 69. A 95. B
18. B 44. E 70. A 96. B
19. D 45. A 71. C 97. D
20. D 46. D 72. A 98. E
21. C 47. B 73. C 99. B
22. E 48. B 74. B 100. A
23. A 49. C 75. B