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Class 11 - Chemistry
Sample Paper 01
Maximum Marks: 35
Time Allowed: 90
minutes
General Instructions:
Section A
1. To which block of elements in the periodic table 3d104s2 belongs?
a. d- Block
b. p- Block
c. f- Block
d. s- Block
2. Among the following pairs of orbitals which orbital will experience the larger effective nuclear charge?
(i) 2s and 3s, (ii) 4d and 4f, (iii) 3d and 3p:
a. 4f, 3d, and 3s respectively
b. 2s, 4d and 3p respectively
c. 2s, 4d and 3d respectively
d. 4d, 3p and 2s respectively
3. What is the general electronic configuration of the elements of group 14?
a. [Inert] ns2 np1
b. [Inert] ns2 np4
c. [inert] ns2, np2
d. [Inert] ns2 np3
4. The state of hybridization of the central atom and the number of lone pairs over the central atom
in POCl3 are:
a. sp, 0
b. dsp2, 1
c. sp2, 0
d. sp3, 0
5. Oxidation and reduction always occur simultaneously, hence, the word “redox” was coined for this
class of chemical reactions. In the following redox reaction, identify the species undergoing
oxidation and reduction: 3Fe3O4(s) + 8 Al (s) 9 Fe (s) + 4Al2O3(s)
a. Aluminium (Al) is oxidised, (Fe3O4) is reduced
d. [NH3 and ]
12. In the reaction of metallic cobalt placed in nickel sulphate solution, there is a competition for release of
electrons At equilibrium, chemical tests reveal that both Ni2+ (aq) and Co2+ (aq) are present at moderate
concentrations. The result is that:
a. Neither the reactants nor the products are greatly favoured
b. Only [Co(s) and (aq)] are favoured
c. Only (aq) and Ni (s)] are favoured
d. Only one reactant and one product is greatly favoured.
13. Hydrogen peroxide is obtained by the electrolysis of .
a. water
b. fused sodium peroxide
c. hydrochloric acid
d. sulphuric acid
14. Electrophilic addition reactions proceed in two steps. The first step involves the addition of an
electrophile. Name the type of intermediate formed in the first step of the following addition reaction.
H3C—HC = CH2 + H+ ?
a. 2° Carbocation
b. 1° Carbocation
c. 2° Carbanion
d. 1° Carbanion
15. There are L in 12.0 ml?
a. 0.10 L
b. 0.012 L
c. 0.12 L
d. 0.0012 L
16. Lines in the hydrogen spectrum which appear in the visible region of the electromagnetic
Spectrum, then they are called as:
a. Balmer series
b. Lyman series
c. Paschen series
d. Bracket series
17. Which of the following is most powerful oxidizing agent in the following:
a. KMnO4
b. K2Cr2O7
c. O3
d. H2O2
18. Rank the bonds in the set C=O, C-O, C O in order of decreasing bond strength.
a. C-O < C O > C=O
b. C O > C=O > C-O
c. C=O < C O > C-O
d. C O > C-O < C=O
19. In sulphur estimation, 0.157 g of an organic compound gave 0.4813 g of barium sulphate. What is
the percentage of sulphur in the compound?
a. 24%
b. 11%
c. 42.10%
d. 41.6%
If 300g of C4H10 (g) is burnt with 1000 g of O2, the yield of H2O and the limiting reagent in the
reaction are and respectively.
a. 435 g and O2
b. 400 g and O2
c. 350 g and C4 H10
d. 465 g and O2
21. A balanced chemical equation has the same number of atoms of each element on both sides of
the equation. This is in accordance with one of the following laws
a. Gay Lussac's Law of gaseous volumes
b. Avogadro Law
c. Law of conservation of mass
d. Law of Definite Proportions
22. Identify the correct statements with reference to the given reaction as follows:
.
a. Hydrogen is undergoing oxidation as well as reduction.
b. Phosphorus is undergoing oxidation only.
c. Phosphorus is undergoing reduction only.
d. Phosphorus is undergoing oxidation as well as reduction.
23. A qualitative measure of the stability of an ionic compound is provided by:
a. lattice enthalpy
b. Electron affinity
c. electron gain enthalpy
d. ionization enthalpy
24. In Carius method of estimation of halogen, 0.15 g of an organic compound gave 0.12 g of AgBr. Find
out the percentage of bromine in the compound.
a.
b.
c.
d.
25. A person is suffering with fever with a high temperature of 104 °F. What will be his body
temperature in °C?
a. 32.38 °C
b. 28 .10 °C
c. 18.68 °C
d. 40 °C
Section B
26. Rutherford’s –particle scattering experiment supported the discovery of:
a. nucleus
b. electron
c. radioactivity
d. proton
27. Which of the following angle corresponds to sp2
hybridisation? a. 109°
b. 180°
c. 90°
d. 120°
28. Only one element of forms hydride.
a. group 9
b. group 7
c. group 8
d. group 6
29. 2-bromo butane can be represented in various ways. Choose the incorrect one from the following
a. CH2CHBrCH2CH2
b.
c.
d.
d. sp4
35. The molar mass of C6H10O5 is:
a. 172.09 u
b. 182 g
c. 152.00 g/mol
d. 162.14 g/mol
36. Correct expression for all series of lines in the hydrogen spectrum is (n1 = 1, 2, 3... and n2 = n1 + 1, n1
+2, ... , and is the wavenumber)
a.
b.
c.
d.
a.
Cl+, CH3C+ = O
d. BF3, Cl+
42. The wave character of electrons is used in the construction of
a. fluorescence microscope
b. compound microscope
c. electron microscope
d. light microscope
43. The outer electronic configuration of a p- block element is:
a. 6s24f3
b. 3s23p64s2
c. 3d104s2
d. ns2 np1-6
44. According to Dalton’s atomic theory
a. Atoms are made of neutrons and protons
b. Atoms are made of electrons and protons
c. Atoms are indivisible
d. Atoms are made of electrons, neutrons and protons
45. Assertion (A): Thomson's atomic model is known as the raisin pudding model.
Reason (R): The atom is visualized as a pudding of positive charge with electrons (raisins) embedded in
it.
a. Both A and R are true and R is the correct explanation of A.
b. Both A and R are true but R is not the correct explanation of A.
c. A is true but R is false.
d. A is false but R is true.
46. Assertion (A): The second period consists of 8 elements.
Reason (R): The number of elements in each period is four times the number of atomic orbitals
available in the energy level that is being filled.
a. Both A and R are true and R is the correct explanation of A.
b. Both A and R are true but R is not the correct explanation of A.
c. A is true but R is false.
d. A is false but R is true.
47. Assertion (A): The hybridisation possessed by the oxygen atom in OF2 molecule is sp2.
52. The addition of HCl to alkene proceeds in two steps. The first step is the attack of H+ ion to
the portion which can be shown as:
A.
B.
C.
Question No. 53 to 55 are based on the given text. Read the text carefully and answer the
questions:
The existing large number of organic compounds and their ever-increasing numbers has made it
necessary to classify them on the basis of their structures. Organic compounds are broadly classified
as open-chain compounds which are also called aliphatic compounds. Aliphatic compounds further
classified as homocyclic and heterocyclic compounds. Aromatic compounds are special types of
compounds. Alicyclic compounds, aromatic compounds may also have heteroatom in the ring. Such
compounds are called heterocyclic aromatic compounds. Organic compounds can also be classified on
the basis of functional groups, into families or homologous series. The members of a homologous
series
can be represented by general molecular formula and the successive members differ from each
other in a molecular formula by a –CH2 unit.
Class 11 - Chemistry
Sample Paper 01
Solution
Section A
1. (a) d- Block
Explanation: d-block element has the general outermost electronic configuration as (n-1)d1-10 ns0-2.
2. (b) 2s, 4d and 3p respectively
Explanation: Nuclear charge is defined as the net positive charge experienced by an electron in the
orbital of a multi-electron atom. The closer the orbital, the greater is the nuclear charge experienced by
the electron (s) in it.
(i) 2s is closer to the nucleus than 3s.Hence 2s will experience larger effective nuclear charge.
(ii) 4d will experience greater nuclear charge than 4f since 4d is closer to the nucleus than 4f.
(iii) 3p will experience greater nuclear charge since it is closer to the nucleus than 3f because 3p
is closer to nucleus than 3f.
3. (c) [inert] ns2, np2
Explanation: The general electronic configuration of different elements is given with reference to the
complete configuration of an inert element preceding. It is usually denoted as and thereafter
the number of electrons in the last orbit of the element is written following notation, where
n = principal quantum number
l = secondary or Azimuthal quantum number
x = number of electrons
So, the general electronic configuration of group 14 elements (ie. a p-block element) is [inert] ns2, np2.
4. (d) sp3, 0
Explanation: CN= 0.5 [V+M-C+A]
For POCl3 V=5 M=3 C =A=0 So CN=4
On cathode : On anode :
As 2° carbocation is more stable than 1° carbocation, the first addition is more feasible.
15. (b) 0.012 L
Explanation: Since , 1L = 1000 ml
12 ml = L = 0.012 L
16. (a) Balmer series
Explanation: The Balmer series or Balmer lines in atomic physics is the designation of one of a set of
six named series describing the spectral line emissions of the hydrogen atom. The Balmer series is
calculated using the Balmer formula, an empirical equation discovered by Johann Balmer in 1885
Balmar series lies in the visible region of the Electromagnetic spectrum.
17. (c) O3
Explanation: Ozone act as powerful oxidising agent because it can easily decompose to give an atom of
nascent oxygen which is more reactive than O2.
18. (b) C O > C=O > C-O
Explanation: The more bonds between atoms, the shorter the bond is. For example, a triple bond will
be shorter than a double bond. Shorter = stronger, so the shorter the bond is the stronger it is (higher
dissociation energy). Bond order is basically the number of bonds between atoms, so a larger number
bond order=more bonds=shorter bonds=stronger bonds.
19. (c) 42.10%
Explanation: Molecular mass of BaSO4 = 137 + 32 + 64 g = 233 g
233 g BaSO4 contains 32 g S
So % of S =
S = 42.10%
20. (d) 465 g and O2
Explanation: Calculations
As per the stoichiometry of the given equation,
Calculations:
Step 1/ -
Molar mass of C4H10
= (4 2+1 10) amu = (48 + 10) amu
= 58 amu
300g of C4H10
= moles
= 5.17 moles
Step 2 / -
i. For the yield of H2O;
Since 2 mols of C4H10 yields 10 H2O i.e.
= 10 moles.
5.17 moles of C4H10 would yield 10H2O
= 25.85 moles
465.3 g 465 g
ii. For predicting the limiting reagent;
a. Calculate the number of moles of O2 needed to react with 5.17 moles of C4H10
Since 2 moles of C4H10 requires 13 O2 molecules i.e.
= 13 moles
= 33.62
moles
Number of moles of O2 actually taken for combustion
=
=
= 31.25 moles
Thus, it is noteworthy that,
O2(g) taken for reaction (i.e. 31.25 moles) is lesser than the required number of moles (i.e. 33.62
moles).
Hence, it would be consumed first and is, therefore, the limiting reagent for this reaction.
21. (c) Law of conservation of mass
Explanation: As a result of the law of conservation of mass ( ie." matter can neither be created nor
destroyed " ), it is significant that in any chemical change the total mass of the reacting substances
should be equal to that of the products formed. This is easily represented through a balanced chemical
equation for the reaction being considered. Further, since the number of atoms of different elements,
with their own atomic masses, are involved in a chemical change their number should not change ( or
remain the same ) even before and after the reaction, irrespective of the compound/element used as a
reactant or in products yielded.
22. (d) Phosphorus is undergoing oxidation as well as reduction.
Explanation:
Phosphorus is undergoing oxidation as well as reduction. As the oxidation number of P is 0 in the
reactant and in the product it is -3 as well as +1.
23. (a) lattice enthalpy
Explanation: Lattice energy is an estimate of the bond strength in ionic compounds. It is defined as the
heat of formation for ions of opposite charge in the gas phase to combine into an ionic solid. The
stability of the ionic bond is directly proportional to lattice energy.
24. (d)
Explanation: Molar mass of AgBr = 108 + 80 = 188 g/mol
188 g AgBr contains 80 g bromine
0.12 g AgBr contains (80 x 0.12)/188 g bromine
Percentage of bromine
25. (d) 40 °C
Explanation: 104°F − 32) × 5/9 = 40°C
Section B
26. (a) nucleus
Explanation: Rutherford's model of an atom: Ernest Rutherford was interested in knowing how the
electrons are arranged within an atom. Rutherford designed an experiment for this. In this
experiment, fast-moving alpha ( )-particles were made to fall on a thin gold foil.
On the basis of his experiment, Rutherford put forward the model of an atom, which had the following
features:
There is a positively charged centre in an atom called the nucleus.
Nearly all the mass of an atom resides in the nucleus. The electrons revolve around the
nucleus in well-defined orbits.
The size of the nucleus is very small as compared to the size of the atom.
27. (d) 120°
Explanation: sp2 hybridisation have triangular planar structure so bond angle is 120o
28. (d) group 6
29. (b)
Explanation: methyl group is represented at 3rd carbon no bromine is there on 2nd carbon
30. (d) 169.9 u
Explanation: Molar mass of AgBO3 = [atomic mass of Ag + atomic mass of N + 3 (atomic mass of O))] u
Substituting the atomic masses of Ag, N & O as 107.9, 14 & 16 respectively in the above expression we
get -
Molar mass of AgBO3 = [107.9 + 14 + (3 16) ] u
= 169.9 u
31. (b) J.J. Thomson
Explanation: Electron was discovered by J. J. Thomson in 1897 when he was studying the properties of
the cathode ray. J. J. Thomson won Nobel Prize in 1906 for discovering the elementary particle
electron.
32. (a) Dipole moment
Explanation: A dipole moment is a measurement of the separation of two opposite electrical charges.
Dipole moments are a vector quantity. The magnitude is equal to the charge multiplied by the
distance between the charges and the direction is from negative charge to positive charge: =q
r
33. (a) All of these
Explanation: Hydrogen peroxide (H2O2) is a very pale blue liquid that appears colourless in a dilute
solution, slightly more viscous than water. It is a weak acid. It has strong oxidizing properties and is,
therefore, a powerful bleaching agent that is mostly used for bleaching paper but has also found use
as a disinfectant and as an oxidizer.
Hydrogen peroxide in acid solution is oxidized with KMnO 4 and reduced with KI. When H2O2 serves as
an oxidizing agent, the oxygen is reduced to H 2O. When H2O2 serves as a reducing agent, the oxygen is
oxidized to O2 and bubbles are noticed.
36. (c)
where
i. RH is the Rydberg constant and is 109,737 cm-1
ii. n1 and n2 are integers (whole numbers) with n2>n1
Explanation: