ST.

XAVIER’S HIGH SCHOOL, BALASORE

Annual Examination – 2022 - 23
CLASS-XI FM-70
SUB- CHEMISTRY TIME-3 HOURS

General Instructions:
(1) There are 35 questions in all. All questions are compulsory
(2) This question paper has five sections: Section A, Section B, Section C, Section D and Section E. All the sections
are compulsory.
(3) Section A contains eighteen MCQ of 1 mark each, Section B contains 7 questions of2 marks each, Section C
contains 5 questions of 3 marks each, section D contains 3 long questions of 5 marks each and Section E
contains two case study-based questions of 4 marks each.
(4) There is no overall choice. However, an internal choice has been provided in section B, C, D and E. You have
to attempt only one of the choices in such questions.

SECTION A (1 MARK)
1. Which of the following is not an actinide?
a. curium b. terbium c. californium d. uranium
2. What is the correct order of radii?
a. I+<I<I- b. Na>Mg>Al c. Na+>Mg2+>Al3+ d. all of these
3. The smallest ion among the following is
a. Na+ b. Al3+ c. mg2+ d. Si4+
4. The method used for Nitrogen analysis is
a. iodin method b. kjeldahl’s method c. dumas method d. both b& c
5. In which of the following compounds, an element exhibits two different oxidation states?
a. NH2OH b. NH4NO3 c. N2H4 d. N3H
6. Number of angular nodes for 3d orbital is
a. 4 b. 3 c. 2 d. 1
7. The oxidation number of mn is maximum in
a. MnO2 b. K2MnO4 c. Mn3O4 d. KMnO4
8. Which of the following acts as an electrophile in the chlorination of benzene?
a. Cl+ b. Cl- c. Cl d. FeCl3
9. Calculate the oxidation number of S in H2SO4
a. 7 b. 6 c. -1 d. 5
10. The specific heat capacity at constant pressure is 8J/kg.K find the heat capacity at constant volume.
a. 16.314 b. 8.314 c. 8 d. 0.314
11. Which of the following is weak acid weak base hydrolysis constant?
a. kw/kb b. kw/ka c. kw/kakb d. 1/kakb
12. Which of the following have shortest bond length
a. N2 b. N2+ c. N2- d. N22-
13. Which of the following has maximum mass?
 a. 1.2g atom of oxygen b. 5.2g atom of iodin c. 5.6g atom of chlorine d. 5.6g atom of
sodium
14. The hybridisation of “C-2” in CH3COOH
a. sp b. sp2 c. sp3 d. dsp2

Question number 15 – 18 contains assertion reason type. Write answer of the questions out of the below
options.
(a) Assertion is correct, reason is correct; reason is a correct explanation for assertion.
(b) Assertion is correct, reason is correct; reason is not a correct explanation for assertion
(c) Assertion is correct, reason is incorrect
(d) Assertion is incorrect, reason is correct.

15. Assertion: the decomposition of H2O2 to form H2O is an example of disproportionation reaction.
Reason: the O2 of peroxide is in -1 oxidation state in O2 & -2 oxidation state in H2O

16. Assertion: pyrrole is an aromatic heterocyclic organic compound.

Reason: it has 6𝜋 e-s that are cyclic & delocalised.

17. Assertion: the three elements in a trial have the same atomic mass gaps.
Reason: the reason for this is that the properties of the elements in a trio are comparable.

18. Assertion: butane and 2 – methyl butane is homologous

Reason: butane is a straight chain alkane while 2- methyl butane is a branched chain alkane.

SECTION B (2 MARKS)

19. Calculate the oxidation number of S in H2S

20. Explain the term with example

a. enthalpy of vaporisation
b. enthalpy of combustion

21. All transition elements are d-block elements, but all elements do not transition elements. Explain.

22. What are the characteristics of a good blackbody?

23. Draw the structure of XeO2F2 & the name of the geometry with Bond pair & lone pair.

24. If radius of 2nd orbit of Li2+ ion is x, then calculate the radius of 3rd orbit of Be3+.

25. What do you understand by ‘nte’ rule. Explain with an example.

OR
Write the structure of H2S2O7, H2S2O8.

SECTION C (3 MARKS)

26. state and explain disproportionation reaction.

27. An equation to explain the relationship between wavelength and velocity of a particle.
28. Write about Friedel craft acylation reaction.
OR
Write about Friedel craft alkylation reaction.

29. Find out the pH if pka = 0.20 & pkb = 0.40

30. Write note on different types of isomerism with example.

SECTION D (5 MARKS)

31. Draw the resonating structure of the following compounds.

a. C6H5OH (phenol) b. C6H5NH2 (aniline)
OR
Write IUPAC names of the following compounds.
a. (CH3)3 C CH2 C (CH3)3
b. (CH3)2 C (C2H5)2
c. tetra-tert-butyl methane
and write the structure of the following
i. 3-ethyl-5-methyl heptane
ii. propane-2-Ol

32. What do you mean by law of mass action, state & explain. Also prove that kp = kc (RT)∆n
OR
State and explain Le-chatelier’s principle for the preparation of ammonia by Haber’s process.

33. Write the postulates of Bohr’s atomic model and also write its limitations.
OR
State and explain different types of quantum numbers with details.

SECTION E (4 MARKS)

34. Case study

A saturated solution of sodium chloride is precipitated due to increased Concentration of chloride
ion available from the dissociated of HCl which help to make the sodium chloride active greater
purity. The Common ion effect also help to finish the particular ion precipitated as Sparingly Soluble
water with very Low Value of Solubility product. Thus, we con Precipitate Silver ion as silver
chloride, Ferric ion as its hydroxide & barium ion as its sulphate for quantitative estimation.

i. Differentiate the solutions depending upon the solubility of the salt. (1 mark)
 ii. Explain the effect of common salt on the solubility of ions salts. (1 mark)
iii. What is buffer solution? (2 marks)

35. Case study

Actually, when we intake the food it undergoes an oxidation and transform into Cu₂ & H₂O. When
the energy is changed in the independent pathway, here is the Hess Law imply. This means that
through burning the food equal amount of energy is released. Thus, the Carbohydrates split into
simple sugar.

i. What is entropy? (1 mark)

ii. Define Hess’s law. (1 mark)
iii. What are the applications of Hess’s law? (2 mark)