APEJAY COMMON ANNUAL EXAMINATION

2020-21
CLASS XI
CHEMISTRY
MM:70 Time: 3 Hours

General Instructions:

Read the following instructions carefully.

a) There are 33 questions in this question paper. All questions are compulsory.
b) Section A: Q. No. 1 to 16 are objective type questions. Q. No. 1 and 2 are passage
based questions carrying 4 marks each while Q. No. 3 to 16 carry 1 mark each.
c) Section B: Q. No. 17 to 25 are short answer questions and carry 2 marks each.
d) Section C: Q. No. 26 to 30 are short answer questions and carry 3 marks each.
e) Section D: Q. No. 31 to 33 are long answer questions carrying 5 marks each.
f) There is no overall choice. However, internal choices have been provided.
g) Use of calculators and log tables is not permitted.
SECTION-A
1. Read the following passage and answer the questions that follows:
In the presence of peroxide, addition of HBr to unsymmetrical alkenes like propene
takes place contrary to the Markovnikov rule. This happens only with HBr but not
with HCl and Hl. This addition reaction was observed by M.S. Kharash and F.R.
Mayo in 1933 at the University of Chicago. This reaction is known as peroxide or
Kharash effect or addition reaction anti to Markovnikov rule.
The following questions are multiple choice questions. Choose the most appropriate
answer:
i. The cleavage of benzoyl peroxide takes place through: 1
a. heterolytic fission
b. homolytic fission
c. partial cleavage
d. none of these
ii. Peroxide effect proceeds via- 1
a) Free radical chain mechanism
b) transition state formation
c) carbocation formation
d) none of these
iii. Addition reactions of HBr to hex-1-ene in the absence of peroxide gives- 1
a) 2-bromohexene
b) 2-bromohexane
c) 1-bromohexene
d) None of these
iv. Addition reaction are given by- 1
a) Alkanes only
b) Alkenes only
c) Both alkenes and alkynes
d) Alkanes, alkenes and alkynes
2. Read the passage and answer the questions that follow:
The atomic and ionic radii decrease with increase in atomic number along a period from left to
right. Atomic size and ionic size increases down the group.
Ionisation enthalpy decreases down the group and increases along a period from left to right. It
also depends upon shielding effect as well as stability of electronic configuration.
Electronegativity decreases down the group but increases along the period.
In these questions (Q. No i-iv), a statement of assertion followed by a statement of reason is
given. Choose the correct answer out of the following choices.
a) Assertion and reason both are correct statements and reason is correct explanation for
assertion. b) Assertion and reason both are correct statements but reason is not correct
explanation for assertion.
c) Assertion is correct statement but reason is wrong statement.
d) Assertion is wrong statement but reason is correct statement.
i. Assertion :Ionic radius of Na+ is smaller than Na 1
Reason :Effective nuclear charge of Na+ is higher than Na
ii. Assertion :Boron has smaller first ionization enthalpy than Beryllium. 1
Reason :The penetration of a 2s electron to the nucleus is more than the 2p electron hence 2p
electron is more shielded by the inner core of electrons than the 2s electrons.
iii. Assertion :First ionisation enthalpy of Gallium is higher than Aluminium. 1
Reason :Weak shielding effect of 3d subshell in Gallium.
OR
Assertion :IE1 of 3rd period elements is as follows. Mg < Si < Al < P < S < Cl <Ar< Na.
Reason: Across period, in aperiodic table from left to right I.E should increase.
iv. Assertion :Electron gain enthalpy of Cl is more negative than F atom. 1
Reason :F is more electronegative than Cl atom.
Following questions (No. 3 -16) are multiple choice questions carrying 1 mark each:
3. Oxidation numbers of P in PO43-, S in SO42- and that of Cr in Cr2O72- are respectively 1
(a) +3, +6 and +5
(b) +5, +3 and +6
(c) +3, +6 and +6
(d) +5, +6 and +6
4. When sodium is dissolved in liquid ammonia, a solution of deep blue colour is obtained. The 1
colour of the solution is due to
(a) ammoniated electron
(b) sodium ion
(c) sodium amide
(d) ammoniated sodium ion
5. Ozonolysis of an organic compound gives formaldehyde as one of the products. This confirms 1
the presence of:
(a) a vinyl group
(b) two ethylenic double bonds
(c) an isopropyl group
(d) an acetylenic triple bond
6. Which of the following oxide is acidic in nature? 1
(a) B2O3
(b) Al2O3
(c) Ga2O3
(d) In2O3
OR

Which one of the following anions cannot be formed by Boron?

(a) BF63-
(b) BH4-
(c) B(OH)4-
(d) BO2-
7. If 20cm³ gas at 1 atm. is expanded to 50 cm³ at constant T, then what is the final pressure 1
(a) 20 × 150
(b) 50 × 120
(c) 1 × 120 × 50
(d) None of these
8. Identify disproportionation reactions 1
(a) CH4+ 2O2 → CO2+ 2H2O
(b) CH4+ 4Cl2→ CCl4+ 4HCl
(c) 2F2+ 2OH-→2F- + OF2+ H2O
(d) 2NO2+ 2OH-→ NO2- + NO3- + H2O
OR
Which of the following arrangements represent increasing oxidation number of the central
atom?
(a) CrO2-, ClO3-, CrO42-, MnO4-
(b) ClO3-, ClO42-, MnO4-, CrO2-
(c) CrO2-, ClO3-, MnO4-, CrO42-
(d) CrO22-, MnO4-, CrO2-, ClO3-
9. The ionization enthalpy of hydrogen atom is 1.312 × 106 J mol-1. The energy required to excite 1
the electron in the atom from n = 1 to n = 2 is
(a) 8.51 × 105 J mol-1
(b) 6.56 × 105 J mol-1
(c) 7.56 × 105 J mol-1
(d) 9.84 × 105 J mol-1
10. Which of the following pairs have the same number of atoms? 1
(a) 16 g of O2(g) and 4 g of H2(g)
(b) 16 g of O2 and 44 g of CO2
(c) 14 g of N2 and 32 g of O2
(d) 12 g of C(s) and 23 g of Na(s)
11. Which of the following are Lewis acids? 1
(a) BCl3 and AlCl3
(b) PH3 and BCl3
(c) AlCl3 and CCl4
(d) PH3 and SiCl4
12. Which one of the following sets of ions represents a collection of isoelectronic species? 1
(Atomic nos.: F = 9, Cl = 17, Na = 11, Mg = 12, Al = 13, K = 19, Ca = 20, Sc = 21)
(a) K+, Ca2+, Sc3+, Cl–
(b) Na+, Ca2+ , Sc3+, F–
(c) K+, Cl–, Mg2+, Sc3+
(d) Na+, Mg2+, Al3+, Cl–
13. What is the correct order of increasing energy of the listed orbitals in the atom of titanium? 1
(Atomic number Z=22)
(a) 3s <3p <3d< 4s
(b) 3s < 3p< 4s< 3d
(c) 3s < 4s< 3p< 3d
(d) 4s < 3s< 3p< 3d
14. Based on VSEPR theory. the number of 90° F -Br -F angles in BrF5 is: 1
a. 8
b. 2
c. 4
d. 0
15. Electronegativity of carbon atoms depends upon their state of hybridization. In which of the
following compounds, the carbon marked with asterisk is most electronegative?
(a) CH3-CH2-*CH2-CH3
(b) CH3-*CH=CH-CH3
(c) CH3-CH2-C≡*CH
(d) CH3-CH2-CH=*CH2
16. The IUPAC name of CH3 – CH = CH – C ≡ CH is:
(a) Pent-3-en-1-yne
(b) Pent-3-en-4-yne
(c) Pent-2-en-4-yne
(d) pent-2-en-3-yne
SECTION-B
The following questions, Q.No 17 – 25 are short answer type and carry 2 marks each.
17. Explain why PCl5 is trigonal bipyramidal whereas IF5 is square pyramidal. 2
OR
Represent diagrammatically the bond moments and the resultant dipole moment in CO2 and
NF3.
18. 3.0 g of H2 react with 29.0 g of O2 yield H2O. 2
(i) Which is the limiting reagent.
(ii) Calculate the maximum amount of H2O that can be formed.
19. Which of the following represents the correct IUPAC name for the compounds 2
concerned?
a. 2, 2-Dimethylpentane or 2-Dimethylpentane
b. 2, 4, 7-Trimethyloctane or 2, 5, 7- Trimethyloctane
c. 2-Chloro-4-methylpentane or 4-Chloro-2-methylpentane
d. But-3-yn- 1-ol or But-4-ol-yne.
OR
Why does SO3 act as an electrophile?
20. For the reaction, NO(g) + O3(g) NO2(g) + O2(g) . Kc= 6.3 x 1014 at 1000 K. Both the 2
forward and reverse reactions are elementary bimolecular reactions in equilibrium. What is Kc
for the reverse reaction?
21. What will be the pressure of the gas mixture when 0.5 L of hydrogen at 0.8 bar and 2 L of 2
oxygen at 0.7 bar are introduced in a 1 L vessel at 27oC?
22. a) What do you mean by functional isomerism? Give one example. 2
b) What type of isomerism is represented by CH3-O-C3H7 and C2H5-O-C2H5?
23. a) How many electrons are possible in all shells with n+l=5? 2
b) Calculate the total number of angular nodes and radial nodes present in 3p orbital?
24. Complete the following reactions: 2
alc.KOH/Heat HBr/ Peroxide
a. Isopropyl bromide A B

ConcH2SO4
b. n-Propylalcohol A B
443K Δ/O2, Ag
25. 0.561 g KOH is dissolved in water to give 200 mL of solution at 298K. Calculate the 2
concentration of potassium, hydrogen and hydroxyl ions. What is the pH of the solution?
Given log2=0.3010
SECTION-C
Q.No 26 -30 are Short Answer Type II carrying 3 mark each.
26. Calculate the velocity of electron in the first Bohr orbit of hydrogen atom. Given that 3
Bohr radius = 0.529A0, planck’s constant (h) = 6.626x10-34 Js, mass of electron=9.11x10-31 Kg
and 1 J=1Kg m2s-2. Also calculate the velocity of electron in 3rd orbit of He+ ion.
27. Balance the following redox reactions : 3
MnO4-(aq) +I-(aq)→MnO2(s)+I2(s) (Basic medium)
OR
MnO4-(aq)+SO2(g)→Mn2+(aq) +SO42-(Acidic medium)
28. What do you understand by (i) electron deficient (ii) electron precise and (iii) electron rich 3
compounds of hydrogen. Provide justification with suitable examples.
29. Explain the following: 3
(a) Pb4+ acts as an oxidizing agent but Sn2+ acts as a reducing agent.
(b) Carbon shows catenation property but lead does not.
(c) White fumes appear around the bottle of anhydrous aluminium chloride.
30. Assign reason for the following: 3
(i) Lithium salts are commonly hydrated while those of other alkali metal ions are usually
anhydrous.
(ii) Alkali metals are strong reducing agent.
(iii) LiCl is more covalent than NaCl.
 OR
Arrange the following in order of property mentioned against each :
(i) BaCl2, MgCl2, BeCl2, CaCl2 (Increasing ionic character)
(ii) Mg(OH)2, Sr(OH)2, Ba(OH)2, Ca(OH)2 (Increasing solubility in water)
(iii) BeO, MgO, BaO, CaO (Increasing basic strength)
SECTION-D
Q.No 31 to 33 are long answer type carrying 5 marks each.
31. Arrange the following in the order of property indicated against each set: 1x5
(i) –NO2, –COOH, –Br, –F (In the increasing order of –I effect) =5
(ii) CH3-CH2-CH2-CH2+, (CH3)3C+, CH3-CH2-CH+- CH3(In the order of increasing stability)
(iii) –COOH , –CONH2, –CHO (In the increasing priority order if present in same molecule)
(iv) HCOOH, CH3COOH, ClCH2COOH (Increasing order of acidic strength)
(v) 2,3-Dimethylbut-2-ene, But-2-ene, 2-Methylbut-2-ene (Increasing order of relative stability)
OR
(a) An alkene ‘A’ of molecular mass 28 u on treatment with Br2 gives product ‘B’. The 3
compound ‘B’ on further dehalogenation with zinc gives back ‘A’. Give the structures of ‘A’
and ‘B’ and also give the sequence of reactions. Write the reaction when ‘A’ reacts with
Baeyer’s reagent.
(b) Write short note on (i) Decarboxylation reaction (ii) Kolbe’s electrolysis 2
32. a. What is meant by the term bond order? Calculate the bond order of N2, O2, O2+,O2– 1+2

b. Describe the hybridisation in case of PCl5. Why are the axial bonds longer as compared to 2
equatorial bonds?

OR

a. Explain the non linear shape of H2S and non planar shape of PCl3 using valence shell 2
electron pair repulsion theory.
b. Structures of molecules of two compounds are given below:
 (i) Which of the two compounds will have intermolccular hydrogen bonding and which 3
compound is expected to show intramolecular hydrogen bonding?
(ii) The melting point of a compound depends on among other things, the extent of hydrogen
bonding. On this basis explain which of the above two compounds will show higher melting
point.
(iii) Solubility of compounds in water depends on power to form hydrogen bonds with water.
Which of the above compounds will form hydrogen bond with water easily and be more soluble
in it?
33. (a) Predict the signs of ∆H and ∆ S for the reaction: 1
2Cl(g) → Cl2(g)
(b) For an isolated system, ∆ U=0, What will be ∆S? 1
(c) The reaction of cyanamide, NH2CN (s), with dioxygen was carried out in bomb calorimeter,
and ∆U was found to be -742.7 kJ mol-1 at 298 K. Calculate enthalpy change for the reaction at 3
298 K.
NH2CN(g) + 3/2O2(g) N2(g) + CO2(g) +H2O(I)
OR
(a) Define Hess’s law of constant heat summation. 1
(b)Derive the relationship between ∆H and ∆ U for an ideal gas. Explain each term involved in
the equation. 2
(c) Propane has the structure CH3-CH2-CH3. Calculate the enthalpy change, ∆rHo for the
reaction:
C3H8(g) + 5 O2(g) → 3CO2(g) + 4 H2O(g) 2
The average bond enthalpies of carious bonds are:
Bonds C-C C-H O=O C=O O-H
KJ/mol 347 414 498 741 464