ASSIGNMENT 1 (CH-10) CHEMISTRY

Class 12th
1. Write structures of the following compounds:
(i) 1-Chloro-4-ethylcyclohexane
(ii) 4-tert. Butyl-3-iodoheptane
(iii) 1-Bromo-4-sec. butyl-2-methylbenzene
2. Name the following halides according to IUPAC system and classify them as alkyl,
allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:
(i) (CH3)2CHCH(Cl)CH3
(ii) CH3CH2CH(CH3)CH(C2H5)Cl
(iii) (CH3) 3CCH2CH(Br)C6H5
(iv) CH3CH=C(Cl)CH2CH(CH3) 2
(v) CH3CH=CHC(Br)(CH3)2
(vi) o-Br-C6H4CH(CH3 )CH2CH3
3. Which reagent will you use for the following reaction?

4. Arrange the following compounds in the increasing order of their densities Cl

5. Which of the following is an example of vic-dihalide?

(a) Dichloromethane (b) 1, 2-dichloroethane
(c) Ethylidene chloride (d) Allyl chloride
6. Among the isomeric alkanes of molecular formula C5H12, identify the one that on
photochemical chlorination yields (i) A single monochloride. (ii) Three isomeric
monochlorides. (iii) Four isomeric monochlorides.
7. What is A in the following reaction?

8. Write the reaction of toluene with chloride in the presence of iron and in the
absence of light. Identify the type of reaction.
9. Out of o- and p-dibromobenzene, which one has higher melting point and why?
10. Why is the solubility of haloalkanes in water very low?
11. Write down the structure and IUPAC name for neo-pentylbromide.