CHEMISTRY THEORY (043)

MM: 70 Time: 3Hours

General Instructions. Read the following instructions carefully.

(a) There are 33 questions in the question paper. All questions are compulsory.

(b) Section A: Q. No. 1 to 2 are case - based questions having four MCQs or Reason

Assertion type based on given passage each carrying 1 mark.

(c) Section A: Question 3 to 16 are MCQs and Reason Assertion type questions

carrying 01 mark each.

(d) Section B: Q. No. 17 to 25 are short answer questions and carry 2 marks each.

(e) Section C: Q. No. 26 to 30 are short answer questions and carry 3 marks each.

(f) Section D: Q. No. 31 to 33 are long answer questions carrying 5 marks each.

(g) There is no overall choice. However, internal choices have been provided.

(h) Use of calculators and tables is not permitted.

SECTION A (OBJECTIVE TYPE)

1. Read the passage given below and answer the following questions:
Carboxylic acids can be converted to 1o alcohols using Lithium aluminum hydride (LiAlH4).
Note that NaBH4 is not strong enough to convert carboxylic acids or esters to alcohols.
An aldehyde is produced as an intermediate during this reaction, but it cannot be
isolated because it is more reactive than the original carboxylic acid.

The following questions are multiple choice questions. Choose the most appropriate
answer:
LiAlH mention in the study above can be used to convert:
(i) 4
butanoic acid to butanal
a)
b)butanal to butanol
c) butanoic acid to butanol
butanal to butane
d)
Propanoic acid on reaction with ammonia give a compound ‘A’ which on reaction with Br /KOH give
(ii) 2
compound ‘B’. Compound ‘A’ and ‘B’ respectively are :

a) Propanamide , Propanamine
b) Propanamine, Propane
c) Propanamide, Propanal
d) Propane, Propanol
(iii) An organic acid ‘A’ C5H10O2 reacts with Br2 in presence of phosphorous to give ‘B’.
Compound ‘B’ contains an asymmetric carbon atom and yield 3-Methyl butan-2-enoic
acid on dehydrobromination. Compound ‘A’ and ‘B’ respectively are:
a) 3-Methyl butanoic acid, 2- Bromo-3-methyl butanoic acid
 b) 2-Methyl butanoic acid, 2- Bromo-3-methyl butanoic acid
c) 2-Methyl butanoic acid, 3- Bromo-3-methyl butanoic acid
d) 3-Methyl butanoic acid, 3- Bromo-3-methyl butanoic acid
(iv) Ethanoic acid get reduced using LiAlH4 to give:
a) Ethanal
b) Ethanol
c) Ethanone
d) Ethane
OR
Ethanol get oxidised using KMnO4/H2SO4 to give:
a) Ethanal
b) Ethanoic acid
c) Ethane
d) Ether

2. Read the passage given below and answer the following questions: (1x4=4)

Ozone is an allotropic form of oxygen. At a certain height of about 20 km in the atmosphere, it is

formed from oxygen in the presence of sunlight. It protects earth’s surface from an excessive

concentration of UV radiations. It is prepared by subjecting a slow stream of pure and dry oxygen

through a silent electrical discharge. It is pale blue gas and poisonous in nature. It is used as strong

oxidising agent.

2. In these questions (Q. No. 5-8) a statement of assertion followed by a statement of

reason is given. Choose the correct answer out of the following choices.

(a) Assertion and reason both are correct statements and reason is correct
explanation for assertion.

(b) Assertion and reason both are correct statements but reason is not correct

explanation for assertion.

(c) Assertion is wrong statement and reason is correct statement.

(d) Assertion is correct statement and reason is wrong statement.

(i) Assertion: Ozone is destroyed by CFCs in upper stratosphere.

Reason: Ozone hole cause excessive UV radiations to reach the surface of earth.
(ii) Assertion:  Ozone is thermodynamically less stable than oxygen.

Reason: Formation of ozone from oxygen has large negative value of ∆Go.

(iii) Assertion:  it is used as a disinfectant.

Reason:  Ozone is oxidising nature.

 OR

Assertion: Ozone oxidises black lead sulphide to white lead sulphate.

Reason: Ozone is a oxidising agent.

(iv) Assertion: Ozone layer is getting depleted at upper atmosphere which is a cause of concern.
 
Reason:  CFC reacts with ozone and breaks it.
3. Out of the following transition elements, the maximum number of oxidation states is shown by

(a) Sc (Z = 21)
(b) Cr (Z = 24)
(c) Mn (Z = 25)
(d) Fe (Z = 26)
OR
Total number of unpaired electrons present in Co3+ (Atomic number = 27) is
(a) 2
(b) 7
(c) 4
(d) 5
4. How many ions are produced from the complex [Co(NH3)5Cl] Cl2 in solution?
(a) 4
(b) 2
(c) 3
(d) 5

OR
IUPAC name of [Pt(NH3)2Cl(NO2)] is

a. Platinum diamminechloronitrite
b. Chloronitrito-N-ammineplatinum (II)
c. Diamminechloridonitrito-N-platinum (II)
d. Diamminechloronitrito-N-plantinate (II)

5. Haemoglobin has

a. Primary structure
b. Secondary structure
c. Tertiary structure
d. Quaternary structure

OR

  Name the simplest amino acid

a. Alanine
b. Tyrosine
c. Asparagine
d. Glycine

6.  The equivalent conductance of Ba2+ and Cl– are respectively 127 and 76 ohm-1 cm-1 eq-1 at

 infinite dilution. The equivalent conductance of BaCl2 at infinite dilution will be

a. 139.5
b. 203
c. 279
d. 101.5

7. Which of the following condition is not satisfied by an ideal solution?

(a) ΔHmixing = 0
(b) ΔVmixing = 0
(c) Raoult’s Law is obeyed
(d) Formation of an azeotropic mixture

8. Amides may be converted into amines by a reaction named after

(a) Hofmann Bromide
(b) Claisen
(c) Perkin
(d) Kekule

OR

 Reduction of nitroalkanes yields which compound?

a) Amine
b) Alcohol
c) Acid
d) Diazo compounds

9. Which of the following has magnetic moment value of 5.9?

(a) Fe2+
(b) Fe3+
(c) Ni2+
(d) Cu2+

10.
Methyl bromide reacts with AgF to give methyl fluoride and silver bromide. This reaction is
called
(a) Fittig reaction
(b) Swarts reaction
(c) Wurtz reaction
(d) Finkelstein reaction

.
In a simple cubic, body-centred cubic and face-centred cubic structure, the ratio of the
11
number of atoms present is respectively

a. 8:1:6
b. 1:2:4
c. 4:2:1
d. 4:2:3

Note: In the following questions (Q. No. 12-16) a statement of assertion followed by a statement of
reason is given. Choose the correct answer out of the following choices.

(b) Assertion and reason both are correct statements and reason is correct
explanation for assertion.

(b) Assertion is correct statement and reason is wrong statement.

(c) Assertion is wrong statement and reason is correct statement.

(d) Assertion and reason both are correct statements but reason is not correct

explanation for assertion.

12. Assertion : All naturally occurring α-aminoacids except glycine are optically active.

Reason : Most naturally occurring amino acids have L-configuration.

13. Assertion: SF6 cannot be hydrolysed but SF4 can be.

Reason: Six F atoms in SF6 prevent the attack of water on sulphur atom of SF6

14. Assertion: If red blood cells were removed from the body and placed in pure water,

pressure inside the cell increase.

Reason: The concentration of the salt content in the cells increase

OR

Assertion: Cooking time is reduced in pressure cooker.

Reason: Boiling point inside the pressure cooker is raised.

15. Assertion: Aromatic aldehydes and formaldehyde undergo Cannizaro reaction.

Reason: Aromatic aldehydes are almost as reactive as formaldehyde.

16. Assertion: Like bromination of benzene, bromination of phenol is also carried

out in the presence of Lewis acid.

Reason: Lewis acid polarizes the bromine molecule.

17. For a 5% solution of urea (Molar mass = 60 g/mol), calculate the osmotic pressure at 300 K.

[R = 0·0821 L atm K–1 mol–1]

18. Aluminium crystallises in a fcc structure. Atomic radius of the metal is 125 pm. What is the
length of the side of the unit cell of the metal?

19. A first order reaction takes 10 minutes for 25% decomposition. Calculate t 1/2 for the reaction.
(Given: log 2 = 0.3010, log 3 = 0.4771, log 4 = 0.6021).

OR
 Analyse the given graph, drawn between concentrations of reactant vs.

a. Predict the order of reaction.

b. Theoretically, can the concentration of the reactant reduce to zero after infinite time?
Explain.

20.Define order of reaction. How does order of a reaction differ from molecularity for a complex
reaction?
21. Give reasons for the following:

a. Dioxygen is a gas but sulphur a solid.

b. Interhalogens are more reactive than pure halogens.

22. Using IUPAC norms write the formulae for the following :

i. Hexaamminecobalt (III) sulphate

ii. Potassium trioxalatochromate (III)

OR

 [Fe(H2O)6]3+ is strongly paramagnetic whereas [Fe(CN)6]3- is weakly

paramagnetic.

23. Out of  and   which one is more reactive towards SN2

reaction and why?

24. Account for the following:

a. Aromatic carboxylic acids do not undergo Friedel-Crafts reaction.

b. pKa value of 4-nitrobenzoic acid is lower than that of benzoic acid.

OR
  Write short notes on the following:
(i) Carbylamine reaction
(ii) ‘Hofmann’s bromamide reaction

25. Write structures of compounds A and B in each of the following reactions :

a.

b.

26.  Define the following :

(i) Schottky defect
(ii) Frenkel defect
(iii) F-centre

27. Define the following terms :

(i) Electrophoresis
(ii) Adsorption
(iii) Shape selective catalysis

28. What is lanthanoid contraction? What are the consequences of lanthanoid contraction?

OR
(i) E° value for the Mn+3/Mn+2 couple is positive (+1.5 V) whereas that of Cr+3/Cr+2 is negative (-0.4
V). Why? ‘
(ii) Transition metals form colored compounds. Why?
(iii) Complete the following equation:

(iv) 2MnO4– + 16 H+ + 5C204– ———->

29. Complete the following reactions:

a.

b.
 OR

How do you convert the following:

a. N-phenylethanamide to p-bromoaniline
b. Benzene diazonium chloride to nitrobenzene
c. Benzoic acid to aniline

30. Define the following terms with a suitable example of each :

a. Anomers
b. Essential amino acids
c. Denaturation of protein

31. a)  Calculate the time to deposit 1.27 g of copper at cathode when a current of 2 A was passed
through the solution of CuS04.
(Molar mass of Cu = 63.5 g mol-1, 1 F = 96500 C mol-1)

b) Following reactions occur at cathode during the electrolysis of aqueous silver chloride
solution:
Ag+(aq) + e-1 ————> Ag(s)            E° = +0.80 V
H+(aq) + e-1  ———–> 1/2H2(g)        E° = 0.00 V
On the basis of their standard reduction electrode potential (E°) values, which reaction is feasible at the
cathode and why?

32.
a. Concentrated sulphuric acid was added to an unknown salt present in a test tube a brown gas
(A) was evolved. This gas intensified when copper turnings were added to this test tube. On
cooling, the gas (A) changed into a colourless solid (B).
Identify (A) and (B).
Write the structures of (A) and (B).
Why does gas (A) change to solid on cooling ?
b. the following in the decreasing order of their reducing character :
HF, HCl, HBr, HI
c. Complete the following reaction

XeF4 + SbF5 →
OR

a. Give reasons:
i. When Cl2 reacts with excess of F2, ClF3 is formed and not FCl3.
ii. Dioxygen is a gas while Sulphur is a solid at room temperature.
b.Draw the structures of the following :
i. XeF4
ii. HClO3
33.(a)Kolbe’sreaction
(b)
(i) Benzoquinone from phenol
(ii) 2-methylpropan-2-ol from methyl magnesium bromide
(iii) Propan-2-ol from propene.
 OR
(a) How are following obtained:
(i) Toluene from phenol (ii) Phenol from Aniline.
(b)  Give chemical test to distinguish between the following pairs of compound:
(i) Ethanol and phenol
(ii) Methanol and Propan-2-ol.