Intermediate College For Girls

A Project of Gulab Devi Educational Foundation Lahore (Regd.)

1st half book test 2023-2025

Name: __________________________________ Roll No. _____________________

Discipline: F.Sc. Pre-Medi. Subject: Chemistry
Date: 25.03.2024 Time Allowed: 03:00 Hours
Name of Instructor: Miss. Amna Shabbir Total Marks: 85

OBJECTIVE Type

Q1. Select the most suitable answer from give ones in each question. (17 x 1)
1. In Murree Hills, water boils at :
a. 98°C c. 0°C
b. 100°C d. 50°C
2. One mole of SO2 contains:
a. 6.02× 1023of oxygen atoms c. 6.02× 1023of Sulphur atom
b. 18.1×1023 molecules of SO2 d. 4 gram atoms of SO2
3. Acetone and chloroform are soluble in each other due to :
a. Intermolecular hydrogen c. Instantaneous dipole
bonding d. All the above
b. Ion dipole interaction
4. The molar volume of CO2 is maximum at:
a. STP c. 0°C and 2atm
b. 127°C and 1atm d. 273°C and 2atm
5. If absolute temperature of gas is doubled and the pressure is reduced to one half, the volume of
the gas will:
a. Remain unchanged c. Reduce to ¼
b. Increase four times d. Be double

6. Pressure remaining constant, at which temperature the volume of a gas will become twice of what
is at 0°C
a. 546°C c. 546K
b. 200°C d. 273K
7. Which of the following is pseudo solid?
a. CaF2 c. NaCl
b. Glass d. All

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8. Which of the hydrogen halides has the highest percentage of ionic character:
a. HCl c. HF
b. HBr d. HI
9. The mass of one mole of electrons is
a. 1.008mg d. 1.673mg
b. 0.55mg
c. 0.184mg

10. The number of moles of CO2 which contain 8.0g of oxygen.

a. 0.25 c. 1.0
b. 0.50 d. 1.50
11. The volume occupied by 1.4g of N2 at S.T.P is :
a. 2.24dm3
b. 22.4dm3
c. 1.12dm3
d. 112cm3
12. The Wave number of light emitted by a certain source is 2×106cm-1. The wavelength of this light
will be
a. 500nm c. 200nm
b. 500m d. 5×107m
13. Splitting of spectral lines when atoms are subjected to strong electric field is called
a. Zeeman effect c. Photoelectric effect
b. Stark effect d. Compton effect
14. Which of the following species has unpaired electrons in anti-bonding molecular orbitals:
a. O2+2 c. B2
b. N2+2 d. F2
15. Orbitals having same energy are called :
a. Hybrid orbitals c. Degenerated orbitals
b. Valence orbitals d. d- orbitals
16. Which gas will diffuse more rapidly?
a. CO2 c. NH3
b. HCl d. SO2
17. Which of the following molecules have zero dipole moment?
a. NH3 c. H2O
b. CHCl3 d. BF3

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 SUBJECTIVE Type
Section-I

2. Write short answer to any EIGHT (8) questions (8 x 2)

i. How can you justify that molecular formula = n x empirical formula
ii. Define stoichiometry. Write its two important assumptions.
iii. What is the function of two strong peaks in the mass spectrum for bromine, while for iodine
only one peak at 127 amu is indicated?
iv. Why graphite conduct electricity in one direction only not in others?
v. Moles of Cl atoms in 0.822 g C2H4Cl2
vi. Why the size of cation is smaller than anion. Explain it with example
vii. A solid organic compound is soluble in water as well as in chloroform. During its preparation,
it remains in aqueous layer. Describe the method of separation?
viii. Define Rf value and why it has no unit?
ix. What is the habit of crystal. How it can be changed?
x. How will you differentiate between gooch crucible and sintered glass crucibles
xi. Define sublimation with example
xii. A well-known ideal gas is enclosed in a container having volume 500 cm3 at S.T.P. its mass
come out to be 0.72g. What is the molar mass of this gas?
3. Write short answers to any EIGHT (8) questions (8 x 2)
i. Define pressure and 5 different units of pressure
ii. How neutrons were discovered?
iii. Write any three properties of positive rays
iv. Derive the unit of R in torr K-1mol-1
v. Calculate the number of moles of 3g H2SO4
vi. How do you justify from general gas equation that increase in temperature or decrease in
pressure decrease the density of gas?
vii. Why no ionic bond is 100 percent ionic in nature?
viii. Point out the faulty postulates of kinetic molecular theory
ix. What is van der wal repulsion?
x. Convert 100 OC into oF
xi. Explain why NF3 have shorter bond angle than NH3
xii. What are ionic solid. Give 2 examples.
4. Write short answer to any SIX (6) questions (6 x 2)
i. Explain Auf-bau and Pauli’s exclusion principle
ii. Heat of sublimation of a substance is greater than that of heat of vaporization
iii. Why CH4 does not form the coordinate covalent bond but H2O do?
iv. Differentiate between orbit and orbital.
v. Why noble gases do not form chemical bond.
vi. Whichever gas is used in the discharge tube, the nature of the cathode rays remains same.
Why?
vii. Define bond energy.
viii. What is n+l rule. Give an example
ix. Differentiate between emission and line absorption spectrum.

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 Section-II

Note : Attempt any THREE questions (8 x 3)

5. (a) define Molecular orbital theory and also draw the structure of N2 with number of bonds and bond
formula (4)
(b) Explain Manometric method in detail (4)
6. (a) One mole of methane gas is maintained at 300K , its volume is 250cm3. Calculate the pressure
exerted by the gas, when the gas is ideal. (4)
(b) Explain pressure correction in detail (4)
7. (a) Explain azimuthal quantum number (4)
(b) Explain the structure of NH3 by hybridization (4)
8. (a) Structure of sodium chloride in detail (4)
(b) Define yield. What are its types and also explain percentage yield in detail (4)
9. (a) define and explain dalton’s law of partial pressure (4)
(b) write any six properties of cathode rays (4)

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