MANASLU WORLD COLLEGE 4.

Principal, azimuthal and the magnetic quantum number

are respectively related to
Chuchchepati, Chabahil, Kathmandu a. Size, shape and orientation
PRE-FINAL EXAM– 2077 b. Shape, size and orientation
c. Size, orientation and shape
Grade: XI Subject: Chemistry Time: 3 hrs d. None of the above
Stream: Science F.M. 75 5. Hybridization of carbon in C2H2
a) Sp3 b) Sp2 c) Sp d ) Sp3d
P.M. 30 6. Oxidation no. of H in MgH2
Candidates are required to give their answers in their a) +1 b) -1 c) +2 d) -2
own words as far as practicable. The figures in the 7. Carbon reduction process is not applicable for
margin indicate full marks. a) Fe b) Zn c) Cr d) Sn
GROUP A 8. The acidic nature is the order
a. HF > HCl > HBr > HI
Answer all the questions. (1×11 = 11) b. HI > HBr > HCl > HF
1. Which pair of species will have equal volumes at NTP? c. HCl > HBr > HI > HF
a. 12.8 g of SO2 and 0.5 mole of NO2 d. HCl > HF > HBr > HI
b. 6.023 × 1022 SO2 molecules and 0.1 mole solid carbon 9. With which of the following metals is Minamata disease
c. 6.023 × 1022 O2 molecules and 0.2 mole of N2 gas related?
d. 1 gm molecules of CO2 and 71 g of Cl2 a) Fe b) Cd c) Hg d) Ag
2. Molecular weight of a volatile compound is equal to 10. Find the incorrect statement for a nucleophile
a. Its vapor density (a) A nucleophile is a Lewis acid
b. Square of its vapour density (b) Nucleophiles do not seek electron
c. Half of its vapour density (c) Ammonia is a nucleophile
d. Double of the value of its vapour density (d) Nucleophiles attack low electron density sites
3. To reduce the volume of a gas of 200 ml to 100 ml at 11. The hydrocarbon formed on heating isopropyl bromide
20oC with sodium metal is
a. Temp should be lowered to 10oC a) Hexane b) 1,1,2,2,-tetramethylethane
b. Pressure and temperature should be doubled c) Propane d) 2,3-Dimethylbutane
c. Pressure should be doubled
d. Pressure and temperature should be halved
 Group B
Attempt all the questions. (8×5=40)
1. What is screening effect. How it affects the ionization
potential? Describe the variation of ionization potential
along the group and period. (2+3)
OR
Write characteristics of chemical equilibrium. Derive the
relationship between Kp and KC.
2. Explain Graham's law of diffusion. What are the
application of Graham's law of diffusion?
3. How many grams of silver could be plated out on a serving
tray by passing electricity through a solution of Ag(I) salt
for 8 hours at a current of 9 amperes? What is the area of
the trey, if thickness of the silver plating is 0.002 cm?
Density of silver is 10 g/cm3. ( Ag = 107.8 )
4. What is the principle behind the froth floatation process?
Write down the difference between calcination and
roasting. (2+3)
5. What happens when: (2+3)
a) White phosphorous is exposed to air?
b) The gas produced by the action of white Phosphorous
with Sodium hydroxide is passed through AgNO3
solution. Write along with the reactions involved.
6. Define Allotropy. Discuss the different allotropic form
of Carbon. (5)
7. State Markovnikov's rule giving an example. Give the
reaction when 3-ethyl Butene reacts with:
a) HBr/ Peroxide b) HCl/Peroxide c) H2/Ni and give
the IUPAC name of the product formed. (2+3)
8. What are the environmental impacts of chemical
industry? Describe the role of chemical fertilizer on
socio-economic status of Nepal.
Group C
Attempt all the questions. (8×3=24)
1. Derive the relationship between vapour density and
molecular weight. 200g of 90% pure CaCO3 is reacted
with 1.95 mole of HCl to produce CaCl2, H2O and CO2.
i. Which one is limiting reagent? Justify your answer.
ii. Calculate the mass of CaCl2 formed.
iii. How many moles of water produced?
iv. What volume of CO2 are produced if the reaction is
carried out at 27oC temperature and 760 mmHg
pressure?
2. a) Describe the Kipp's apparatus method for the
manufacturing of H2S. Give a reaction to show H2S is a
reducing agent. (5)
b) Write any two differences between the bleaching
action of Cl2 and SO2. (3)
OR
Describe manufacturing process of Sodium carbonate by
Solvay process with necessary description.
3. a) Describe Kolbe's electrolysis method for the
preparation of alkene and alkynes. (4)
b) Identify A: (2)
c. Identify A & B and give their IUPAC name. (2)