Practice question for second term- Grade 11(Chemistry)

Mole concept + ….
Multiple choice Questions:
1. Electrolysis of an aqueous NaCl solution makes the solution at the cathode
i. Neutral ii. Weakly acidic
iii. Basic iv. Strongly acidic
2. One mole of glucose (C6H12O6) is burnt completely into CO2 and H2O. The volume of CO2
produced at NTP is
i. 22.4L ii. 44.8L
iii. 89.6L iv. 134.4L
3. The least number of atom is in
i. 1g of H2 ii. 7g of N2
iii. 8g of CH4 iv. 11g of CO2
4. Which law holds good even for the existence of different isotopes of an element?
i. Law of conservation of mass
ii. Law of constant proportions
iii. Law of multiple proportion
iv. all of the above
5. 6 g of a magnesium metal reacts with excess of an acid, the amount of hydrogen
produced would be
i. 0.5g ii. 1.0g
iii. 2g iv. 4g
6. 4.4g of an unknown gas occupies 2.24 litres of volume at standard temperature and
pressure. The gas may be
i. SO2 ii. CO
iii. O2 iv. CO2
7. The vapour density of a gas is half of the vapour density of sulphurdioxide. The
molecular mass of the gas is
i. 16 ii. 48
iii. 32 iv. 64

8. The mass of an atom of diatomic molecule is 6× 10-23g. The molecular mass of the gas is
i. 18 ii. 36
iii. 54 iv. 72
9. If the density of water is 1g/cc, the volume occupied by 1 molecule of water is
i. 2.98×10-23cc ii. 2.98×1023cc
 iii. 6.022×10-23cc iv. 6.022×1023cc
10. 60g of a compound on analysis gave 24g of C, 4g of H and 32g of O. The empirical
formula of the compound is
i. C2H4O2 ii. CH2O2
iii. C2H2O2 iv. CH2O

Short Questions
1. 2 g of magnesium is burnt in as closed vessel containing 3 g of oxygen.
I. Which one is limiting reactant and why?
II. Calculate the mole of reactant left over.
III. How many gram of MgO is produced?
IV. What is the mass of H2SO4 required to neutralize MgO formed in the reaction.
Ans: a) Mg b) 0.052 mole c) 3.33g d) 8.15g

2. Fe2O3 + 3CO 2Fe + 3CO2

The reaction is carried out by mixing 130g of Fe2O3 and 50g of CO
i. Find the limiting reactant.
ii. How much mass of iron is produced?
iii. How many number of moles of unreacted reagent is left over?
iv. Calculate the volume of CO2 produced at 25˚C and 2atm pressure.
Ans: a) CO b) 66.66g c) 0.65mole d) 43.54L

3. 150g of 80% pure ZnCO3 is completely reacted with excess HCl to produce ZnCl2, CO2,
and H2O.
i. Which one is limiting reactant?
ii. Calculate the mass of ZnCl2 formed?
iii. How many molecules of water are produced?
iv. What volume of CO2 are produced if the reaction is carried out at 27˚C and 760
mm of Hg pressure?
Ans: a) ZnCO3 b) 130.56g c) 5.78 ×1023 d) 23.626 L
4. Ca(OH)2 + 2NH4Cl CaCl2 + 2NH3 + 2H2O
The reaction is carried out by mixing 7g of pure Ca(OH)2 and 7g of pure NH4Cl.
a. Find the limiting reactant.
b. Calculate the mole of unreacted reactant left over?
c. How many moles of CaCl2 are formed?
d. What volume of NH3 is produced at 27˚C and 1.5 atm pressure.
Ans: a) NH4Cl b) 0.029mole c) 7.26g d) 2.13 L
 5. A metal ‘X’ forms two chlorides A and B. 4 g each of A and B contains 1.434g and 2.111g
chlorine respectively. Calculate the masses of metal in grams which combine with one
gram of chlorine in each case. Which chemical law do these data illustrate, state and
explain the law?
Ans: 2:1 Law of multiple proportion
6. State and illustrate the law of reciprocal proportions from the following data.
i. 0.86g Mg produces 1.433g magnesium oxide
ii. 1.5g Mg displaces 1400cc of H2 at NTP from acid
iii. 2.925g water formed by the combination of 2.6g of oxygen with hydrogen.
7. State Avogadro’s hypothesis and derive the relationship between vapour density and
molecular mass of a gas. An oxide of nitrogen contains same of its own volume of
nitrogen whose vapour density is 54. Determine its molecular formula.
Ans: N2O5
8. Define Avogardo’s hypothesis and show that molar volume of gas at STP is 22.4 L. The
volume occupied by 0.8g of a gas ‘X’ and 0.55g of a gas ‘Y’ are same at same
temperature and pressure. If vapour density of ‘X’ is 32, find the vapour density and
molecular mass of the gas ‘Y’. Ans: V.D=22.07 M= 44.17

9. Butyric acid contains C, H, and O. 4.24mg sample of butyric acid is completely burned, it
gives 8.45mg of CO2 and 3.46mg of H2 O. The vapour density of butyric acid was
determined to be 44amu. What is the molecular formula? Ans: C4H8O2
10. Write the relationship between empirical and molecular formula. An organic compound
contains C, H, and O. When 1.265g of the compound was burned, 2.417g of carbon
dioxide and 1.484g of water were formed. The molecular mass of the compound is 46.
Determine its molecular formula? Ans: C2H6O
ETV+…….
Short questions:
1.
a. Predict the shape , geometry and bond angle in H2O molecule on the basis of VSEPR. 3
b. Compare the bond angle of H2O with H2S .Explain with reason. 2
2.
a.Both NH3 and BF3 are tetra-atomic molecules, but they have different geometry. 2 + 2
b. Is the molecule of SO2 linear or bent? 1

3.  and  are two types of bond present in covalent molecules.

a. Write total no. of  and  bond present in ethene molecule. 1

 b. Draw molecular orbital picture of ethene molecule. 2
c. State mode of hybridization in C atom in ethene. 1
d. Write the geometry and bond angle of ethene molecule. 1
4. According to VBT, covalent bond is formed by overlapping of half-filled orbitals of opposite
of combining atoms.

a. Differentiate between  and  bond.

b.Amomg  and  bond, which is stronger and why?

c.Explain the formation of Oxygen molecule on the basis of VBT. 2
5. Identify the mode of hybridization in underlined atom in the following molecule.
i.BeH2 ii. BF3 iii. NH3 iv.CO2 v. C2H2 vi. CCl4 vii.CHCl3
viii.PH3 ix.NO3 - x.SO4 - -
6. Neils Bohr, a Danish physicist won a Nobel prize in 1922 at the age of 37 for his contribution
in atomic structure and proposed atomic model
a. How does Bohr's atomic model overcome the limitation of Rutherfords' atomic
model? 2
b. Angular momentum of an electron is quantized.Explain it on the basis of Bohr's
atomic model. 2
c. What is angular momentum of electron present in second orbit of Hydrogen? 1

7. Rutherford and his coworkers performed an - particle scattering experiment to discover

nucleus.

a.What are - particles? 1

b.Why Gold foil is used in this experiment? 1
c.What experimental evidence led Rutherford's to conclude that
i.The atom consists of mostly empty space. 1
ii.The size of nucleus is extremely small as compared to size of an atom.1
iii.The nucleus of an atom is positively charged.1

Long question
1. NH3 and NH4+ are two covalent molecules having different geometry.
 a. Identify the mode of hybridization of central atom. 1
b. Draw molecular orbital picture.1.5 x 2= 3
c. Arrange them on the basis of increasing bond angle. 1
d. Mention the shape of individual species. 2
d. Calculate lone pair of electron in N-atom of each. 1
2. The geometry of diatomic molecules can be explained by VBT but to explain geometrical
shape of polyatomic molecules concept of hybridization is introduced by Pauling modifying VBT.
a.Define hybridization. 1
b.Draw lewis dot structure of methane.1
c.Draw molecular orbital picture of methane. How would you interpret all C-H bonds in
methane are identical. 2+ 1
d.State mode of hybridization present in methane.1
d.Write the geometry of Methane with its bond angle. 2

MCQ
1. Which of the following pair has identical geometry?
a. BCl3 and PCl3 b. CH3Cl and C2H4
c. CH4 and CCl4 c.XeF4 and SiF4
2. Which of the following interaction is responsible for slight solubility of CO2 in water?
a. Ion-dipole interaction b. Dipole-dipole interaction
c. Dipole-induced dipole interaction d. Induced dipole-induced dipole interaction
3. Which of the following molecule has distorted tetrahedral geometry?
a.BCl3 b. H2O
c.CO2 d. SF6

4.The shape of BF3 molecule is planar with a bond angle equal to 120.It is due to
a.sp3 hybridization of B atom b. sp2hybridization of B atom
c. sp hybridization of B atom d.sp 2 hybridization of F atom
5. The axial overlap between two orbital leads to the formation of
a. pi- bond b. sigma bond
c. multiple bond d. none of the above
6. The total no. of orbital taking part in sp hybridization in carbon atom is
a. one b. three
c. two d .four
7.sp3 hybridization leads to

a. trigonal geometry with bond angle 120

b. tetrahedral geometry with bond angle 109.5

c. tetrahedral geometry with bond angle 90

d. square planar geometry with bond angle 90

8.A molecule of acetylene contains

a. one  and two  bonds

b.two  abd two  bonds

c.three  and two  bonds

d.two  and three  bonds

9. In So2 molecule , S atom is
a.sp3 hybridized b. sp 2 hybridized
c. sp hybridized d. dsp 2 hybridized
10.Which of the following spectral series of H-atom have wave lengths in UV region of
electromagnetic wave?
a. Lymen series b. Balmer series
c. Paschen Series d. Brackett series
11. The existence of a molecule as a tiny positive centre of an atom was discovered by
a. Max planks b. J.J Thomson
c. E. Goldstein d. Rutherford
12.The carbon atom in ethane is
a.sp3 hybridized b. sp 2hybridized
c. sp hybridized d. none of the above
13. Charge of an electron in coulombs is equal to
a. 1.672 X 10 -24 b. - 1.602 X 10 -19
c. 1.602 X 10 -19 d. 1.675 X 10 -24
14. Most of the alpha particles passed through the gold foil without deflection because
a. atom are stable b. most of the space inside the atom is empty
b. atoms are unstable c. all the space in the atom is covered by nucleus
15.The angular momentum of electron in nth orbit is given by
ℎ ℎ
a. b.
2 2n
𝑛ℎ
c.mvr d. 2

16. Shape of p-orbital is

a. circular b. spherical
c. dumb-bell c. complicated
Answer key:
1.C 2.C 3. B 4. B 5. B 6.B 7. B 8.A 9. B 10. A
11.D 12. B 13.B 14.B 15.D 16.C

Redox reaction +…….

1. Consider the following reaction and answer the related question: [1x5]
2Al + 3CuSO4 → Al2(SO4)3 + 3Cu
i. Which one is oxidized? Write the half reaction.
ii. Which one is reduced? Write half reaction.
iii. Which species acts as reducing agent and which acts as oxidizing agent?
iv. What is the role of SO42- ions in the reaction?
v. Represent the redox reaction as loss and gain of electrons.
2. Define oxidation number, it is same or different with valency? Justify.
Determine oxidation number of carbon in the following. [1+2+2]
C2H6 HCO3- Fe(CO)5 CH3Cl
3. State whether the following changes involve oxidation or reduction. Indicate electron
transfer in each case?
i. A metal is deposited at the cathode from solution of its salt.[2]
ii. Ferrous ion is converted into ferric ion.[1]
 iii. Sodium metal is reacted with water.[2]
4. Balance the following redox reaction with oxidation number method or ion electron
method.
i. Zn + NO3- → Zn2+ + NH4+
ii. K2Cr2O7 + H2SO4 + (COOH)2 → K2SO4 + Cr2(SO4)3 + CO2 + H2O
5. The disproportionation reaction, P4 + OH- → PH3 + H2PO2-
i. What do you mean by disproportionation reaction? [1]
ii. How can you apply ion electron method to balance above reaction.[4]
Multiple choice questions:
1. Which of the following act as oxidant as well as reductant?
a. H2SO4 b. H2S c. HNO3 d. SO2
2. The oxidation number of Ni in Ni(CO)4 is
a. +4 b. – 4 c. +2 d. 0
3. Magnesium when heated with chlorine gas forms magnesium chloride. The reaction is
a. Addition reaction b. combustion reaction c. redox reaction d. all of them
4. A metal ion, M3+ loses 3 electrons, its oxidation number will be
a. +6 b. +3 c. 0 d. -3
5. A reducing agent
a. oxidizes other substance b. accepts electron
c. has maximum oxidation number d. itself oxidized.
6. What is the oxidation number of elements in free or in the uncombined state?
a. 0 b. -1 c. + 1 d. +2
7. Oxidation number of H in NaH, CaH2 , LiH, respectively
a. -1, -1, -1 b. -1, +1, +1 c. +1, +1, -1 d. +1, +1, +1
8. The name for NO2 using stock notation is
a. Nitrogen (IV) oxide b. nitrogen dioxide
c. nitrogen per oxide d. all of these
9. oxygen has an oxidation state +2 in the compound
a. F2O b. CO2 c. H2O d. none of these
10. oxidation number of Na is zero in
a. sodium amalgam b. soda lime c. soda ash d. washing soda
answer kye
1 2 3 4 5 6 7 8 9 10
d d c a d a a a a a
Applied chemistry
1. Under ordinary condition nitrogen and hydrogen does not react. It react to produce
ammonia in a large scale by Haber’s process.
i. Write the reaction principle for the Haber’s process. [1]
ii. The process of formation of ammonia is monitored by Le-Chatelier’s principle.
What are the conditions that increase the production of ammonia? [1]
iii. The optimum temperature about 4500 – 5000C is applied in the process. What is
meant by optimum temperature? [1]
iv. Draw the flow sheet for manufacture of NH3 by Haber’s process. [2]
2. Compound ‘A’ is prepared by catalytic oxidation of ‘B’ which is used as important
laboratory reagent.
i. Identify ‘A’ and ‘B’. [1]
ii. Write the reaction principle to produce A from B. [2]
iii. Why cooler is needed for the conversion of NO to NO2. [1]
iv. Write the name of the process to prepare ‘A’. [1]
3. Sodium carbonate is manufactured by ammonia soda process by using CO2 and brine
solution saturated with ammonia.
i. What is brine solution? [1]
ii. What are the sources of CO2 and NH3 in this process? [1]
iii. What is the final product obtained from carbonation tower? [1]
iv. Draw the flow sheet diagram of this process. [2]
1. The oxidation of SO2 to SO3 is reversible reaction and exothermic.
2SO2 + O2 ⇋ SO3
i. How is yield of SO3 maximized? [1]
ii. How is SO3 converted into H2SO4 in the process? [1]
iii. Why is V2O5 replaced Pt-asbestos in this process? [1]
iv. Write the name of mechanism to test purification of SO2 in test box. [1]
v. What is fuming sulphuric acid [1]

Long question
1. According to the latest data from the Ministry of Agriculture, although different
fertilizers are provided for growing crops, production rates are lower than last year.
Therefore, people lose interest in agriculture.
i. Is the excessive usage of fertilizer best for plant? What are its effects? [2]
ii. What are essential macronutrient for plant? Which one is better organic or
chemical in terms of soil fertility? Why? [2]
iii. Write the Chemical formula of Thomas Slag and CAN fertilizer. [2]
iv. Draw the flow sheet diagram of production of urea. [2]
MCQ Practice questions:
1. H2S207 is
a) Sulphuric acid b) Persulphuric acid
c) Oleum d) metasulphuric acid
2. The quantitative yield of ammonia is monitored by
a) Le-Chatelier principle b) Carl Bosch principle
C) Friz Haber principle d) Haber-Bosch principle

3. Plants growth and development are also influenced by:

a. PH b) Temperature

c) Humidity d) All of the above

4. Which of the mentioned conditions will favor the synthesis of ammonia by Haber’s
process?

a) High temperature and high pressure b) Low temperature and high pressure

c) High temperature and low pressure d) Low temperature and low pressure

5. What is the catalyst used in the industrial manufacture of nitric acid?

a) Powdered Iron (III) Oxide b) Vanadium (V) Oxide

c) Zinc-Mercury amalgam d) Platinum-Rhodium Gauze sheet

6. What is the first step involved in forming sulphuric acid through contact process?

a) Conversion of SO2 to SO3 b) Roasting sulphide ore

c) Absorption of SO3 in sulphuric acid d) Purifying SO3

7. Brine is the concentrate solution of

a. NaOH b.H2SO4

c. NaCl d.NO

8. In the process of making NaOH by diaphragm cell, what is the function of diaphragm?

a. To forms ions b. To absorb ions

c.To release ions d. To exchange ions

9. Brine solution saturated with ammonia gas reacts with CO2 to form

a. Urea b. sodium carbonate

c. sodium hydroxide d. sodium bicarbonate

10. What is the value of Phosphorus fertilizer measured in?

(a) The amount of available phosphorus

(b) The amount of available H3PO4

(c) The amount of available P2O5

(d) The amount of available P2O3

11. How is possible traces of arsenic removed in the purification of SO2 gas?

(a) By Washing it with H20 (b) By treating it with H2S04

(c) By using Fe(OH)3 (d) By using conc.H2SO4

12. What is the molecular formula for Thomas slag?

(a) H3P04.Ca(OH)2

(b) Ca3(PO4)2

(c) Ca(H2PO4)2

(d) P2O5

13. Tyndall effect is used to identify the presence of colloidal dust particles in …………in
contact process.

a. Dust chamber b. Scrubber c. Test chamber d. Drying chamber

14. NaOH is manufactured by

a. Contact process b. Ostwald’s process c. Diaphragm cell d. Solvay process

15. Chamber acid is

a. HNO3 b. H3PO4 c. HCl d. H2SO4

Non metal
MCQ
1. Which of the following is not oxide?
a) NO b) H2O

c) F2O2 d) H2O2
2. which of the following oxide is known as sulphuric acid anhydride?
a)SO2 b) H2O
c) SO3 d) SiO2
3. Higher number of oxygen is present in
a)Neutral oxide b) Amphoteric oxide
c) peroxides d) Superoxide

4. Water can be sterilized by

a)Ozone b) Nitrogen
c) oxygen d) sodium

5. Which of the following is the chemical formula of Nessler’s reagent?

a)K2HgI4 b) KI
c) NH2HgI d) H2O2

6. Aqua fortis is the common name for

a)HCl b) H2SO4
c) HNO3 d) H3PO4

7. The inertness of nitrogen is due to

a)Small size b) High EN
c) stable configuration d)none of above

8. Which of the following is laughing gas?

a)NO b) N2O
c) N2O4 d) N2O3
9. Exhaust fumes of car contains poisonous gas
a)NO2 b) CO
c) SO2 d) CO2

10. In graphite each carbon atom is………….. hybridized.

a)SP b) SP2
c) SP3 d) none of above
 1(c) 2(c) 3( d) 4(a) 5( a)
6( c) 7(c) 8(b) 9(b) 10(b)

1. Ammonia is a polar covalent molecule, gas at room temperature and liquefied at -33ºC.
i) what is responsible for liquification?[1]
ii)How can you prove NH3 is:[3]
a) Basic b) complexing agent c) reducing agent

iii) how is NH3 gas tested in lab? Write any two method.[2]
iv) write one application and harmful effect of NH3.[2]
2. Nitrogen occurs as N2 gas which exist most abundantly (78%) in atmosphere.
i) why is nitrogen molecule found in such a higher percentage in atmosphere?[1]
ii) what is active nitrogen?[1]
iii) How is active nitrogen produced?[1]
iv) write the reaction of Al and Mg with active nitrogen.[[1]
v) What is the reason for inertness of nitrogen at room temperature?[1]
3. A binary compound of oxygen with less EN elements are called oxides which are classified
based on acidic, basic property and structural consideration.
i) what is peroxide, superoxide, suboxide. Give one example of each.[3]
ii) CO2 is acidic but CO is neutral. Why?[2]
iii) what are mixed oxides? Give two example. [1]
iv) Na2O is basic oxide while ZnO amphoteric. Justify.[2]
4. O2 and O3 are allotropes of oxygen having different nature of chemical bonds and different
molecular masses.
i) Define allotropes.[1]
ii) why is ozone more reactive than oxygen.[1]
iii) how is ozone tested in lab?[1]
iv) write one uses of oxygen and ozone.[1]
v) write the mechanism of ozone layer destruction by CFCs.[1]
5. Write the chemical reaction of ring test or nitrate ion test.[1]
What happens when zinc react with [4]
i) conc. HNO3
ii) moderately conc. HNO3
iii) dilute HNO3
iv) very dilute HNO3
6. what happens when [5]
i) conc. HNO3 reacts with Sulphur
ii) HNO3 reacts with CaO
iii) Mg reacts with very dilute HNO3
iv) Mod. Conc. HNO3 reacts with H2S
v) Conc. HNO3 reacts with KI
7. CO is neutral unsaturated oxide which is practically insoluble in water and poisonous gas.
i) Why is CO extremely poisonous gas?[1]
ii) why does CO gives addition reaction. Write any two addition reaction of CO.[1]
iii) write two application of CO.[1]
iv) Write the action of CO with[2]
a) Tollens reagent b) heated iron

8. Carbon exists in nature as crystalline and amorphous allotropic forms.

i) List down the allotropes of carbon.[2]
ii) Diamond is bad conductor but graphite is good conductor of electricity although both are
composed of same constituent carbon. Give reason.[1]
iii) At what temperature diamond can be changed to graphite.[1]
iv) How is lamp black prepared? Write its one uses.[1]

Periodic table +……..

Questions:
1. Consider an Organic compound having structural formula CH3CH2NH2
a. Is this compound Aliphatic or Aromatic ?
b. Identify the functional group in the above compound.
c. Identify the heteroelemnt present in the above compound.
d. Define Heteroelement.
e. Which test is used to detect the heteroelement present in the given organic compound?
[ 5]
2. Heteroelement present in the given organic compound can be detected in the lab by converting
them into ionic form.[ 1+2+1+2+2]
a. Why is it necessary to convert them into ionic form?
b. What do you think Sodium extract solution is acidic or basic? Why?
c. What is the composition of Sodium extract If the heteroelements in the organic compound
is Nitrogen?
d. How would you test if the Sodium extract contains the composition formed in qn. No. c?
Give reactions too.
e. If the heteroelement present is Sulphur, which test would you perform to detect it? Give
reactions required to the test.
3. An Organic compound containing structural formula

a. Identify the functional group in the above compound.

b. What would be the secondary suffix of this functional group?
c. In which condition the primary prefix cyclo is used? Give one example.
d. What would be the secondary prefix if the compound contains group OR?
e. What would be the secondary suffix if the compound contains C≡N functional group?
4. Give reason:
a. Which group element in the periodic table have highest electron affinity & why?
b. Alkaline earth metals have nearly Zero electron affinity. Why?
c. Which compound is formed more easily among NaCl & KCl ? Give reason in terms of
ionization energy of Na & K .
d. Polarity of Hydrogen halides decreases from HF to HBr. Give your reason on the basis of
electron negativity of halogens.
5. Write the IUPAC name of the following compounds:
(CH3CH2)2CHCH2CH2C(CH3)

(CH3)2CHCH(CH3)CH2CH(C2H5)2

Multiple Choice questions:

1. In the heteroelement detection, if there is purple colouration with Sodium
nitroprusside test, which heteroelement is present?
a. Nitrogen d. Both Nitrogen &
b. Halogen Sulphur
c. Sulphur
2. IN detection of Nitrogen Prussian blue colour compound has following molecular
formula:
a. Fe4[Fe(CN)6] c. Na4[Fe(CN)6]
b. K4[Fe(CN)6 d. Fe4[Fe(CN)6]3
3. In Detection of Halogens which ions are considered as interfering ions:
a. CN- c. S--
b. Cl- d. a&c
4. In the combined test of N & S, blood red colour compound is formed. Which one
of the following is its molecular formula?
a. NaCNS c. KCNS
b. Fe(CNS)3 d. NaCN
5. The correct order of first ionization energy among following elements Be, B , C, N
& O is:
a. B<Be<C<O<N c. Be<B<C<N<O
b. B<Be<C<N<O d. Be<B<C<O<N
6. The compound propene contains
a. Word root- pent , primary suffix- ane
b. Word root- pent , primary suffix- ene
c. Word root- prop , primary suffix- ane
d. Word root- prop , primary suffix- ene
7. The electron affinity of inert gases is :
a. Zero c. Negative
b. High d. Positive
8. ++
Ca ion is isoelectronic with
a. Mg++ c. Ar
b. Na+ d. Kr
9. Which of the following ion has smallest size:
a. Na+ c. Al3+
b. Mg++ d. F-
10. Higher value of Electron affinity means:
a. Atom will loose electron easily
b. Atom will gain electron easily
c. Atom may form di-positive ion
d. The reason is unknown.