BATCH CODE -17-LNB51EA

• Subject Name- Chemistry

• Chapter Name - Some basic concept of
Chemistry

By- Ramesh sir

Lecture No.- 01
 11th NEET

2
 Question

The order of KH values of A, B and C gases is 𝐾𝐻𝐴 > 𝐾𝐻𝐶 > 𝐾𝐻𝐵 . Then, the correct order of their
solubility in a liquid at given temperature is

A A>C>B

B B>A>C

C B>C>A

D A>B>C
 Question

Which of the following aqueous solution will have the highest freezing point?

A 0.1 𝑚 𝑁𝑎𝐶𝑙 𝑠𝑜𝑙𝑢𝑡𝑖𝑜𝑛

B 0.1 𝑚 𝑆𝑢𝑔𝑎𝑟 𝑠𝑜𝑙𝑢𝑡𝑖𝑜𝑛

C 0.1 𝑚 𝑀𝑔𝐶𝑙2 𝑠𝑜𝑙𝑢𝑡𝑖𝑜𝑛

D 0.1 𝑚 𝐴𝑙𝐶𝑙3 𝑠𝑜𝑙𝑢𝑡𝑖𝑜𝑛

 Question

Which of the following is/are colligative property?

A 𝐿𝑜𝑤𝑒𝑟𝑖𝑛𝑔 𝑖𝑛 𝑣𝑎𝑝𝑜𝑢𝑟 𝑝𝑟𝑒𝑠𝑠𝑢𝑟𝑒

B 𝐹𝑟𝑒𝑒𝑧𝑖𝑛𝑔 𝑝𝑜𝑖𝑛𝑡

C 𝐵𝑜𝑖𝑙𝑖𝑛𝑔 𝑝𝑜𝑖𝑛𝑡

D 𝐵𝑜𝑡ℎ 2 & (3)

 Question

The average osmotic pressure of human blood is 7.8 bar at 37°C. The concentration of
aqueous NaCl solution that could be used in the blood stream is

A 0.15 mol/L

B 0.32 mol/L

0.30 mol/L
C

D 0.45 mol/L
 Question

A 5 molar solution of H2SO4 is diluted from 1 litre to 10 litres. The normality of the resulting
solution is

A 0.25 N

B 1.0 N

2.0 N
C

D 0.5 N
 Question

Which of the following with respect to negative deviation is correct?

A GSol < 0, HSol < 0, SSol < 0

B GSol < 0, HSol < 0, SSol > 0

C GSol > 0, HSol < 0, SSol < 0

D GSol > 0, HSol > 0, SSol > 0

 Question

The total vapour pressure, Ptotal (in torr) for a mixture of two volatile components, A and B is
given by:
Ptotal = 220 – 110 XB
Where, XB is mole fraction of component, B is mixture Hence, pressure (in torr) of pure
components, A and B are respectively

A 110, 220

B 220, 110

220, 330
C

D 220, 150
 Question

2 m aqueous solution of H2SO4 contains

A 49 g of H2SO4 per 250 g of solution

B 98 g of H2SO4 per 250 g of solvent

49 g of H2SO4 per 250 g of solvent

C

D 98 g of H2SO4 per 250 g of solution

 Question

The concentration of sucrose solution which is isotonic with 0.02 M solution of Na2SO4
(assume complete dissociation) at 30°C is

A 0.04 M

B 0.02 M

0.06 M
C

D 0.08 M
 Question

If degree of dissociation of Al2(SO4)3 is 25% in a solvent, then

A Normal boiling point = experimental boiling point

B Normal osmotic pressure = 2 × experimental osmotic pressure

Normal molecular weight = 2 × experimental molecular weight

C
1
D Normal freezing point = × experimental freezing point
4
 Question

Which of the following pairs of solutions can we expect to be isotonic at the same
temperature?

A 0.1 M NaCl and 0.1 Na2SO4

B 0.1 M urea and 0.1 M NaCl

0.1 M urea and 0.2 M MgCl2

C

D 0.1 M Ca (NO3)2 and 0.1 M Na2SO4

 Question

In the case of osmosis, solvent molecules move from

A Higher vapour pressure to lower vapour pressure

B Higher concentration to lower concentration

Lower vapour pressure to higher vapour pressure

C

D Higher osmotic pressure to lower osmotic pressure

 Question

Assuming salts to be 90% dissociated, which of the following will have highest osmotic
pressure?

A Decimolar Al2(SO4)3

B Decimolar BaCl2

Decijmolar Na2SO4
C

D A solution obtained by mixing equal volumes of (B) and (C) and filtering
 Question

If P° and P are the vapour pressure of solvent and solution n1 and n2 are the moles of solute
and solvent then

 n 
A P = P  2 
 n1 + n2 

 n 
B P = P  2 
 n1 + n2 

 n1 
P = P  
C +
 1 2
n n

P = P  n1
D
 Question

Which of the following is correct about a solution showing positive deviation?

A Vapour pressure observed will be the less than that calculated form Raoult’s law

B Minimum boiling azeotrope will be formed

C Hmix < 0

D Vmix < 0
 Question

The relationship between osmotic pressure (P) at 273 K when 10 g glucose (P1), 10 g urea
(P2) and 10 g sucrose (P3) are dissolved in 250 ml of water is

A P1 > P2 > P3

B P2 > P1 > P3

P2 > P3 > P1
C

D P3 > P2 > P1
 Question

Arrange the following aqueous solutions in the order of their increasing boiling points

(i) 10–4 M NaCl (ii) 10–3 M Urea

(iii) 10–3 M MgCl2 (iv) 10–3 M NaCl

A (i) < (ii) < (iv) < (iii)

B (ii) < (i) = (iii) < (iv)

(i) < (ii) < (iii) < (iv)

C

D (iv) < (iii) < (i) = (ii)

 Question

K4Fe(CN)6 is supposed to be 40% dissociated when 1M solution prepared. Its boiling point is
equal to another solution of 20% A. Considering molality = molarity. The molecular weight of
A is

A 77

B 67

57
C

D 47
 Question

Which of the following equimolar solution have highest vapour pressure?

A Glucose

B NaCl

K2SO4
C

D K4[Fe(CN)6]
 Question

If solute- solvent interactions are more than solute-solute and solvent-solvent interactions
then

A It is ideal solution

B It is non-ideal solution with positive deviation

It is non-ideal solution with negative deviation

C

D None
 Question

W gm of non-volatile organic substance of molecular mass M is dissolved in 250 gm benzene.

Molal elevation constant of benzene is Kb. Elevation in its boiling point is given by

𝑀
A 𝐾𝑏𝑊

4𝐾𝑏𝑊
B 𝑀
𝐾𝑏𝑊
C 4𝑀

𝐾𝑏𝑊
D 𝑀
 Question

The graph plotted vapour pressure vs mole fraction is the graph for which of the following
example

A Hexane and Heptane

B Ethyl bromide and Ethyl chloride

Ethanol and Water

C

D Chloroform and acetone

 Question

Minimum boiling azeotropes and Maximum boiling azeotropes respectively on the examples
of

A Non-ideal solution following +ve deviation and ideal solution

B Ideal solution and non-ideal solution following negative deviation

C Both are ideal solution

Non-ideal solution showing positive deviation and Non-ideal solution showing

D
negative deviation
 Question

For CrCl3. × NH3, elevation in boiling point of 1 molal solution is double of 1 molal solution of
glucose; hence x is , if complex is 100% ionized

A 4

B 5

6
C
3
D
 Question

pH of 1M HA (weak acid) is 3. Hence, van’t Hoff factor is

A 1.01

B 1.001

1.1
C
1.04
D
 Question

Which of the following is not a colligative property?

A Vapour pressure of pure liquid solvent

B Elevation in boiling point

Depression in freezing point

C
Osmotic pressure
D
 Question

Which of the following statement is/are correct?

A Higher the value of KH, higher is the solubility of the gas in the liquid.

B Different gases have different KH values at the same temperature

Mole fraction of gas in the solution is inversely proportional to the partial pressure
C
of the gas

D All
 Question

If a reactant ‘A’ is tetramerized, then the van’t Hoff factor (i) is equal to

A 0.75

B 70%

60%
C

D 75%
 Question

Which of the following will not obey Henry law?

A CO

B H2

O2
C

D NH3
Question
Match the following correctly.
a. Positive deviation (i) Hmix = –ve
b. Ideal solution (ii) Vmix = 0
c. Cryoscopic constant (iii) Vmix = +ve
𝑅𝑇02
d. Negative deviation (iv)
1000𝐼𝑓

𝑅𝐼𝑓2
(v)
A a(iii), b(ii), c(iv), d(i) 1000𝑇0

B a(i), b(ii), c(v), d(iii)

C a(iii), b(ii), c(v), d(i)

D a(i), b(ii), c(iv), d(iii)

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