4.

5 gm of solute having molar mass of 90 gm/mol is dissolved in

water to make 250 ml solution. Calculate molarity of the solution.

A 0.1

B 0.2

C 0.15

D 0.3
4.5 gm of solute having molar mass of 90 gm/mol is dissolved in
water to make 250 ml solution. Calculate molarity of the solution.

A 0.1

B 0.2

C 0.15

D 0.3
The density of 3 M solution of sodium chloride is 1.252 g mL−1 . The
molality of the solution will be : (molar mass, NaCl 58.5 g mol-1 )

A 2.60 m

B 2.18 m

C 2.79 m

D 3.00 m
The density of 3 M solution of sodium chloride is 1.252 g mL−1 . The
molality of the solution will be : (molar mass, NaCl 58.5 g mol-1 )

A 2.60 m

B 2.18 m

C 2.79 m

D 3.00 m
What would be the molality of 20% (mass/mass) aqueous solution
of KI? (Molar mass of KI = 166 g mol-1 )

A 1.48

B 1.51

C 1.35

D 1.08
What would be the molality of 20% (mass/mass) aqueous solution
of KI? (Molar mass of KI = 166 g mol-1 )

A 1.48

B 1.51

C 1.35

D 1.08
The density (in g mL−1 ) of a 3.60 M sulphuric acid solution having
29% H2SO4 (molar mass = 98 g mol-1 ) by mass, will be

A 1.64

B 1.88

C 1.22

D 1.45
The density (in g mL−1 ) of a 3.60 M sulphuric acid solution having
29% H2SO4 (molar mass = 98 g mol-1 ) by mass, will be

A 1.64

B 1.88

C 1.22

D 1.45
The molarity of a solution obtained by mixing 750 mL of 0.5 M HCl
with 250 mL of 2 M HCl will be

A 1.00 M

B 1.75 M

C 0.975 M

D 0.875 M
The molarity of a solution obtained by mixing 750 mL of 0.5 M HCl
with 250 mL of 2 M HCl will be

A 1.00 M

B 1.75 M

C 0.975 M

D 0.875 M
25 mL of a solution of barium hydroxide on titration with 0.1 molar
solution of hydrochloric acid gave a titre value of 35 mL. The
molarity of barium hydroxide solution was

A 0.07 M

B 0.14 M

C 0.28 M

D 0.35 M
25 mL of a solution of barium hydroxide on titration with 0.1 molar
solution of hydrochloric acid gave a titre value of 35 mL. The
molarity of barium hydroxide solution was

A 0.07 M

B 0.14 M

C 0.28 M

D 0.35 M
K2HgI4 is 40% ionised in aqueous solution. The value of its van’t Hoff
factor (i) is

A 1.6

B 1.8

C 2.2

D 2.0
K2HgI4 is 40% ionised in aqueous solution. The value of its van’t Hoff
factor (i) is

A 1.6

B 1.8

C 2.2

D 2.0
The vapour pressure of a given liquid will increase if

A Surface area of liquid is decreased

B The volume of liquid in the container is decreased

C The volume of the vapour phase is increased

D The temperature is decreased

The vapour pressure of a given liquid will increase if

A Surface area of liquid is decreased

B The volume of liquid in the container is decreased

C The volume of the vapour phase is increased

D The temperature is decreased

18 g of glucose (C6H12O6) is added to 178.2 g water. The vapour
pressure of water (in torr) for this aqueous solution is

A 76.0

B 752.4

C 759.0

D 7.6
18 g of glucose (C6H12O6) is added to 178.2 g water. The vapour
pressure of water (in torr) for this aqueous solution is

A 76.0

B 752.4

C 759.0

D 7.6
A compound X undergoes tetramerization in a given organic
solvent. The van't Hoff factor is ?

A 4.0

B 0.25

C 0.125

D 2.0
A compound X undergoes tetramerization in a given organic
solvent. The van't Hoff factor is ?

A 4.0

B 0.25

C 0.125

D 2.0
The van’t Hoff Factor ί for an electrolyte which undergoes
dissociation and association in solvent are respectively :

A greater than 1 and less than 1

B less than 1 and greater than 1

C less than 1 and less than 1

D greater than 1 and greater than 1

The van’t Hoff Factor ί for an electrolyte which undergoes
dissociation and association in solvent are respectively :

A greater than 1 and less than 1

B less than 1 and greater than 1

C less than 1 and less than 1

D greater than 1 and greater than 1

The normal boiling point of water is 373 K. Vapor pressure of water at
temperature T is 19 mm Hg . If enthalpy of vaporization is 40.67
kJ/mol, then temperature T would be :
(Use: log2 = 0.3, R = 8.3 JK-1 mol-1)

A 250 K

B 291.4 K

C 230 K

D 290 K
The normal boiling point of water is 373 K. Vapor pressure of water at
temperature T is 19 mm Hg . If enthalpy of vaporization is 40.67
kJ/mol, then temperature T would be :
(Use: log2 = 0.3, R = 8.3 JK-1 mol-1)

A 250 K

B 291.4 K

C 230 K

D 290 K
The boiling point of C6H6, CH3OH, C6H5NH2 and C6H5NO2 are 80oC,
65oC, 184oC and 212oC respectively. Which will show highest vapour
pressure at room temperature?

A C6H6

B CH3OH

C C6H5NH2

D C6H5NO2
The boiling point of C6H6, CH3OH, C6H5NH2 and C6H5NO2 are 80oC,
65oC, 184oC and 212oC respectively. Which will show highest vapour
pressure at room temperature?

A C6H6

B CH3OH

C C6H5NH2

D C6H5NO2
Which one of the following aqueous solutions will exhibit highest
boiling point?

A 0.01 M Na2SO4

B 0.01 M KNO3

C 0.015 M urea

D 0.015 M glucose
Which one of the following aqueous solutions will exhibit highest
boiling point?

A 0.01 M Na2SO4

B 0.01 M KNO3

C 0.015 M urea

D 0.015 M glucose
3 aqueous solution of NaCl are labelled as ‘A’, ‘B’ and ‘C’ with
concentrations 0.1 M, 0.01 M and 0.001 M, respectively. The value of
van’t Hoff factor for these solution will be in the order of :

A ίA < ίB < ίC

B ίA > ίB > ίC

C ίA = ίB = ίC

D ίA < ίB > ίC
3 aqueous solution of NaCl are labelled as ‘A’, ‘B’ and ‘C’ with
concentrations 0.1 M, 0.01 M and 0.001 M, respectively. The value of
van’t Hoff factor for these solution will be in the order of :

A ίA < ίB < ίC

B ίA > ίB > ίC

C ίA = ίB = ίC

D ίA < ίB > ίC
Consider separate solution of 0.500M C2H5OH(aq), 0.100M
Mg3(PO4)2(aq), 0.250M KBr(aq) and 0.125M Na3PO4(aq) at 25° C.
Which statement is true about these solution, assuming all salts to
be strong electrolytes?

A They all have the same osmotic pressure

0.100M Mg3(PO4)2 (aq) has the highest osmotic

B
pressure

0.125 M Na3PO4(aq) has the highest osmotic

C
pressure

0.500 M C2H2OH(aq) has the highest osmotic

D
pressure
Consider separate solution of 0.500M C2H5OH(aq), 0.100M
Mg3(PO4)2(aq), 0.250M KBr(aq) and 0.125M Na3PO4(aq) at 25° C.
Which statement is true about these solution, assuming all salts to
be strong electrolytes?

A They all have the same osmotic pressure

0.100M Mg3(PO4)2 (aq) has the highest osmotic

B
pressure

0.125 M Na3PO4(aq) has the highest osmotic

C
pressure

0.500 M C2H2OH(aq) has the highest osmotic

D
pressure
Choose the correct statement :

Heat of vaporization for a pure solvent and for a solution are

A similar because similar intermolecular forces between
solvent molecules must be overcome in both cases.

Entropy change between solution and vapour is smaller than

B
the entropy change between pure solvent and vapour.

Boiling point of the solution is larger than that of the pure

C
solvent.

D All statements are correct.

Choose the correct statement :

Heat of vaporization for a pure solvent and for a solution are

A similar because similar intermolecular forces between
solvent molecules must be overcome in both cases.

Entropy change between solution and vapour is smaller than

B
the entropy change between pure solvent and vapour.

Boiling point of the solution is larger than that of the pure

C
solvent.

D All statements are correct.

One mole of a solute A is dissolved in a given volume of solvent. The
association of the solute takes place as follows: nA ⇌ An
If α is the degree of dissociation of A, the van’t Hoff factor ί is
expressed is :

A ί=1-α

B ί = 1 + α/n

ί = 1 - α + α/n
C
1

D ί=1
One mole of a solute A is dissolved in a given volume of solvent. The
association of the solute takes place as follows: nA ⇌ An
If α is the degree of dissociation of A, the van’t Hoff factor ί is
expressed is :

A ί=1-α

B ί = 1 + α/n

ί = 1 - α + α/n
C
1

D ί=1
Which of the following aqueous solutions has osmotic pressure
nearest to pure solvent ?

A Na2SO4

B BaCl2

C Al2(SO4)3

D C12H22O11
Which of the following aqueous solutions has osmotic pressure
nearest to pure solvent ?

A Na2SO4

B BaCl2

C Al2(SO4)3

D C12H22O11
Two aqueous solutions , A and B are separated by a
semi-permeable membrane. The somatic pressure of solution A
immediately begins to decrease. Which of the following statements
is true ?

The solvent molecules are moving from the solution of

A
higher osmotic pressure to that of lower osmotic pressure.

The initial osmotic pressure of solution B is greater than that

B
of solution A.

Solvent molecules are moving from solution B into solution

C
A.

D Both (A) and (B) are true statements.

Two aqueous solutions , A and B are separated by a
semi-permeable membrane. The somatic pressure of solution A
immediately begins to decrease. Which of the following statements
is true ?

The solvent molecules are moving from the solution of

A
higher osmotic pressure to that of lower osmotic pressure.

The initial osmotic pressure of solution B is greater than that

B
of solution A.

Solvent molecules are moving from solution B into solution

C
A.

D Both (A) and (B) are true statements.

The empirical formula of a non-electrolyte is CH2O. A solution
containing 3g L-1 of the compound exerts same osmotic pressure as
that of 0.05M glucose solution. The molecular formula of the
compound is ?

A CH2O

B C2H4O2

C C4H8O4

D C3H6O3
The empirical formula of a non-electrolyte is CH2O. A solution
containing 3g L-1 of the compound exerts same osmotic pressure as
that of 0.05M glucose solution. The molecular formula of the
compound is ?

A CH2O

B C2H4O2

C C4H8O4

D C3H6O3
The osmotic pressures of equimolar solutions of urea , BaCl2 and
AlCl3 will be in the order :

A AlCl3 > BaCl2 > urea

B BaCl2 > AlCl3 > urea

C urea > BaCl2 > AlCl3

D BaCl2 > urea > AlCl3

The osmotic pressures of equimolar solutions of urea , BaCl2 and
AlCl3 will be in the order :

A AlCl3 > BaCl2 > urea

B BaCl2 > AlCl3 > urea

C urea > BaCl2 > AlCl3

D BaCl2 > urea > AlCl3

An aqueous solution is 1.00 molal in KI. Which change will cause the
vapour pressure of the solution to increase ?

A Addition of water

B Addition of NaCl

C Addition of Na2SO4

D Addition of 1.0 molal KI

An aqueous solution is 1.00 molal in KI. Which change will cause the
vapour pressure of the solution to increase ?

A Addition of water

B Addition of NaCl

C Addition of Na2SO4

D Addition of 1.0 molal KI

A solution is prepared by dissolving 0.6 g of urea (molar mass = 60 g
mol-1 ) and 1.8 g of glucose (molar mass = 180 g mol -1 ) in 100 mL of
water at 27°C. The osmotic pressure of the solution is (R = 0.08206 L
atm K-1 mol -1 )

A 8.2 atm

B 2.46 atm

C 4.92 atm

D 1.64 atm
A solution is prepared by dissolving 0.6 g of urea (molar mass = 60 g
mol-1 ) and 1.8 g of glucose (molar mass = 180 g mol -1 ) in 100 mL of
water at 27°C. The osmotic pressure of the solution is (R = 0.08206 L
atm K-1 mol -1 )

A 8.2 atm

B 2.46 atm

C 4.92 atm

D 1.64 atm
The osmotic pressure of a dilute solution of an ionic compound XY in
water is four times that of a solution of 0.01 M BaCl2 in water.
Assuming complete dissociation of the given ionic compounds in
water, the concentration of XY (in mol L -1 ) in solution is

A 4 × 10-2

B 16 × 10-4

C 4 × 10-4

D 6 × 10-2
The osmotic pressure of a dilute solution of an ionic compound XY in
water is four times that of a solution of 0.01 M BaCl2 in water.
Assuming complete dissociation of the given ionic compounds in
water, the concentration of XY (in mol L -1 ) in solution is

A 4 × 10-2

B 16 × 10-4

C 4 × 10-4

D 6 × 10-2