DPP-4

Mole concept
200 mL of 1 M HCl solution is mixed with 800 mL
of 2 M HCl solution. Calculate the molarity of final
solution.

A 1.8 M

B 5.6 M

C 2.90 M

D 4.0 M
200 mL of 1 M HCl solution is mixed with 800 mL
of 2 M HCl solution. Calculate the molarity of final
solution.

A 1.8 M

B 5.6 M

C 2.90 M

D 4.0 M
Solution:
If 200 mL of 0.1 M Na2SO4 is mixed with 100 mL of 0.2 M
Na3PO4 solution, what is the molarity of Na+ in the final
solution, if final solution has a density of 1.2 g/mL

A 0.196 M

B 0.33 M

C 1.5 M

D 4.0 M
If 200 mL of 0.1 M Na2SO4 is mixed with 100 mL of 0.2 M
Na3PO4 solution, what is the molarity of Na+ in the final
solution, if final solution has a density of 1.2 g/mL

A 0.196 M

B 0.33 M

C 1.5 M

D 4.0 M
Solution:
Mark the option containing temperature-independent concentration terms.

A All except V

B I, II, IV

C I, II only

D Only II
Mark the option containing temperature-independent concentration terms.

A All except V

B I, II, IV

C I, II only

D Only II
Solution:
The mole fraction of solute in one molal aqueous solution
is

A 0.009

B 0.018

C 0.027

D 0
The mole fraction of solute in one molal aqueous solution
is

A 0.009

B 0.018

C 0.027

D 0
Solution:
Statement 1 : For a very dilute solution, molality and
molarity are always approximately equal
Statement 2 : Mass of solution is always approximately
equal to mass of solvent for a very dilute solution.

Statement 1 and 2 are true. Statement 2 is the correct

A
explanation for statement 1.
Statement 1 and 2 are true. Statement 2 is not the correct
B explanation for statement 1.

C Statement 1 is false, statement 2 is true.

D Statement 1 is true, statement 2 is false.

Statement 1 : For a very dilute solution, molality and
molarity are always approximately equal
Statement 2 : Mass of solution is always approximately
equal to mass of solvent for a very dilute solution.

Statement 1 and 2 are true. Statement 2 is the correct

A
explanation for statement 1.
Statement 1 and 2 are true. Statement 2 is not the correct
B explanation for statement 1.

C Statement 1 is false, statement 2 is true.

D Statement 1 is true, statement 2 is false.

Solution:
Statement 1 : As temperature increases, molality of
solution decreases.
Statement 2 : Molality of solution is dependent on the mass
of solute and solvent.

Statement 1 and 2 are true. Statement 2 is the correct

A
explanation for statement 1.
Statement 1 and 2 are true. Statement 2 is not the correct
B explanation for statement 1.

C Statement 1 is true, statement 2 is false.

D Statement 1 is false, statement 2 is true.

Statement 1 : As temperature increases, molality of
solution decreases.
Statement 2 : Molality of solution is dependent on the mass
of solute and solvent.

Statement 1 and 2 are true. Statement 2 is the correct

A
explanation for statement 1.
Statement 1 and 2 are true. Statement 2 is not the correct
B explanation for statement 1.

C Statement 1 is true, statement 2 is false.

D Statement 1 is false, statement 2 is true.

Solution:

Molality is number of moles of solute in 1 Kg of solvent , it is

independent of volume or temp.
100 mL of H2SO4 solution having molarity 1 M and density
1.5 g/mL is mixed with 400 mL of water. Calculate final
molarity of H2SO4 solution, if final density is 1.25 g/mL:

A 4.4 M

B 0.145 M

C 0.52 M

D 0.227 M
100 mL of H2SO4 solution having molarity 1 M and density
1.5 g/mL is mixed with 400 mL of water. Calculate final
molarity of H2SO4 solution, if final density is 1.25 g/mL:

A 4.4 M

B 0.145 M

C 0.52 M

D 0.227 M
Solution:
An ideal gaseous mixture of ethane (C2H6) and ethene
(C2H4) occupies 28 litre at 1 atm and 273 K. The mixture
reacts completely with 128 g O2 to produce CO2 and H2O.
Mole fraction at C2H6 in the mixture is :

A 0.6

B 0.4

C 0.5

D 0.8
An ideal gaseous mixture of ethane (C2H6) and ethene
(C2H4) occupies 28 litre at 1 atm and 273 K. The mixture
reacts completely with 128 g O2 to produce CO2 and H2O.
Mole fraction at C2H6 in the mixture is :

A 0.6

B 0.4

C 0.5

D 0.8
Solution:
What is the molarity of SO42- ion in aqueous solution that
contain 34.2 ppm of Al2(SO4)3? (Assume complete
dissociation and density of solution 1 g/mL)

A 3 × 10-4 M

B 2 × 10-4 M

C 10-4 M

D None of these
What is the molarity of SO42- ion in aqueous solution that
contain 34.2 ppm of Al2(SO4)3? (Assume complete
dissociation and density of solution 1 g/mL)

A 3 × 10-4 M

B 2 × 10-4 M

C 10-4 M

D None of these
Solution:
Calculate the molality of 1L solution of 80% H2SO4 (w/V),
given that the density of the solution is 1.80 g mL-1.

A 8.16

B 8.6

C 1.02

D 10.8
Calculate the molality of 1L solution of 80% H2SO4 (w/V),
given that the density of the solution is 1.80 g mL-1.

A 8.16

B 8.6

C 1.02

D 10.8
Solution:
1 M HCl and 2 M HCl are mixed in volume ratio of 4 : 1.
What is the final molarity of HCl solution?

A 1.5

B 1

C 1.2

D 1.8
1 M HCl and 2 M HCl are mixed in volume ratio of 4 : 1.
What is the final molarity of HCl solution?

A 1.5

B 1

C 1.2

D 1.8
Solution:
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