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PATHSHALA JEE Dropper

DPP-01
Solutions
1. A liquid is kept in a closed vessel. If a glass 6. The vapour pressure of pure liquid solvent
plate (negligible mass) with a small hole is A is 0.80 atm. When a non-volatile
kept on top of the liquid surface, then the substance B is added to the solvent, its
vapour pressure of the liquid in the vessel is vapour pressure drops to 0.60 atm. Mole
(A) More than what would be if the glass fraction of the component B in the solution
plate were removed is
(B) Same as what would be if the glass (A) 0.50 (B) 0.25
plate were removed (C) 0.75 (D) 0.40
(C) Less than what would be if the glass
plate were removed 7. When one mole of non-volatile solute is
(D) Cannot be predicted dissolved in three moles of solvent, the
vapour pressure of the solution relative to
2. The vapour pressure of water depends upon the vapour pressure of the pure solvent is
(A) Surface area of container 1 1
(A) (B)
(B) Volume of container 3 4
(C) Temperature 3
(D) All of these (C) (D) 1
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3. Among the following substances, the lowest 8. The vapour pressure of a dilute aqueous
vapour pressure is exerted by solution of glucose is 750 mm of Hg at 373
(A) Water K. The mole fraction of solute is
(B) Mercury 1 1
(C) Kerosene (A) (B)
10 7.6
(D) Rectified spirit
1 1
(C) (D)
4. Which does not influence the solubility of a 35 76
solid in a liquid solvent
(A) Nature of solute 9. The vapour pressure of pure liquid A is 10
(B) Nature of solvent torr and at the same temperature when 1 g of
(C) Temperature B solid is dissolved in 20 g of A, its vapour
pressure is reduced to 9.0 torr. If the
(D) Pressure
molecular mass of A is 200 amu, then the
molecular mass of B is
5. The boiling point of C6H6, CH3OH, (A) 100 amu (B) 90 amu
C6H5NH2 & C6H5NO2 are 80°C, 65°C,
(C) 75 amu (D) 120 amu
184°C, and 212°C respectively. Which will
show highest vapour pressure at room
temperature
(A) C6H6 (B) CH3OH
(C) C6H5NH2 (D) C6H5NO2
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10. The vapour pressure of pure benzene at

50°C is 268 torr. How many mole of non-
volatile solute per mole of benzene is
required to prepare a solution of benzene
having a vapour pressure of 167 torr at 50°C
(A) 0.377 (B) 0.605
(C) 0.623 (D) 0.395
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ANSWER KEY
1. (B)
2. (C)
3. (B)
4. (D)
5. (B)
6. (B)
7. (C)
8. (D)
9. (B)
10. (B)