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LAKSHYA JEE 2023

SOLUTION DPP-04

1. Which of the following is the expression of 7. The relative lowering of vapour pressure of a dilute
Raoult’s law? aqueous solution containing non-volatile solute is
(p = vapour pressure of pure solvent, ps = vapour 0.0125. The molality of the solution is about
pressure of the solution) (A) 0.70 (B) 0.50
(C) 0.90 (D) 0.80
(A) (B)
8. The vapour pressure of water is 20o C is 17.54 mm.
(C) (D) When 20g of non-ionic, substances is dissolved in
100g of water, the vapour pressure is lowered by
0.30mm. What is the molecular weight of the
2. For a dilute solution, Raoult’s law states that
substances.
(A) The lowering of vapour pressure is equal to mole (A) 210.48 (B) 206.88
fraction of solute
(C) 215.2 (D) 200.8
(B) The relative lowering of vapour pressure is equal
to mole fraction of solute 9. Which of the following is incorrect?
(C) The relative lowering of vapour pressure is (A) Relative lowering of vapour pressure is
proportional to the amount of solute in solution independent of the solute and the solvent.
(D) The vapour pressure of the solution is equal to (B) The relative lowering of vapour pressure is a
the mole fraction of solvent colligative property
(C) Vapour pressure of a solution is lower than the
vapour pressure of the solvent.
3. The vapour pressure of water at room temperature is
(D) The relative lowering of vapour pressure is
lowered by 5% by dissolving a solute in it, then the
directly proportional to the original pressure.
approximately molality of solution is:
(A) 2 (B) 1
10. The mass of a non-volatile solute of molar mass 40g
(C) 4 (D) 3
mol-1 that should be dissolved in 114g of Octane to
lower its vapour pressure by 20% is
4. The vapour pressure of pure benzene and toluene are
(A) 10 g (B) 11.4 g
160 and 60 torr respectively. The mole fraction of
(C) 9.8 g (D) 12.8 g
toluene in vapour phase in contact with equimolar
solution of benzene and toluene is
11. The vapour pressure of pure CHCl3 and CH2Cl2 are
(A) 0.50 (B) 0.6
200 and 41.5 atm respectively. The weight of CHCl 3
(C) 0.27 (D) 0.73
and CH2Cl2 are 11.9 g and 17 g respectively in a
solution. The vapour pressure of solution (in atm) will
5. Relative lowering of vapour pressure of a dilute
(A) 80.5 (B) 79.5
solution is 0.2. What is the mole fraction of the non-
(C) 94.3 (D) 105.5
volatile solute?
(A) 0.8 (B) 0.5
(C) 0.3 (D) 0.2

6. The statement “the relative lowering of the vapour

pressure is equal to the ratio of moles of the solute to
the total number of the moles in the solution” refers to
(A) Hess’s law (B) Dalton’s law
(C) Raoult’s law (D) Charles’ law
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Answer Key
1. (A)
2. (B)
3. (D)
4. (C)
5. (D)
6. (C)
7. (A)
8. (B)
9. (D)
10. (A)
11. (C)
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Hints & Solutions

1. (A) 7. (A)
According to Raoult’s law, for non volatile solute, the Relative lowering of vapour pressure = mole
relative lowering of vapour pressure of a solution is fraction of solute (Raoult’s law)
equal to the mole fraction of the solute

2. (B)
Conceptual

3. (D)
Or

Where X = mole fraction of solute. Hence, molality

B

Molality =
8. (B)

9. (D)
4. (C) According to Raoult’s law the relative lowering of
Total pressure vapour pressure of a dilute solution is equal to the
mole fraction of the solute present in the solution,
P = 110 i.e.,
The mole fraction of toluene in the vapour phase in
contact with an equimolar solution of benzene and
toluene. 10. (A)
According to Raoult’s law:

Where, weight dissolved and molecular

mass of solute respectively.
weight dissolved and molecular mass of
5. (D) solvent respectively.
According to Raoult’s law the relative lowering in
vapour pressure of an ideal solution containing the vapour pressure of pure solvent
non-volatile solute is equal to the mole fraction of the vapour pressure of solvent
solute.
∵ Relative lowering of vapour pressure =0.2
∴ Mole fraction of the solute =0.2

6. (C)
According to Raoult’s law,

11. (C)
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