JEE

Lakshya JEE (2025)

Practice Sheet (Chemistry)
Solutions

Q1 O2 is bubbled through water at 293 K . Assume Q6 Which has maximum freezing point?
that O2 exerts a partial pressure of 0.98bar , (A) 6 g urea solution in 100 gH2 O
find the solubility of O2 in gL
−1
. The value of (B) 6 g acetic acid solution in 100 gH2 O
Henry's Law constant KH for O2 is 34.84k bar. (C) 6 g sodium chloride in 100 gH2 O
(A) 0.05 (B) 0.08 (D) All have equal freezing point
(C) 0.07 (D) 0.01
Q7 The vapour pressure of a pure liquid A is
Q2 If relative decrease in vapour pressure is 0.4 for 40 mm Hg at 310 K . The vapour pressure of
a solution containing 1 molNaCl in this liquid in a solution with liquid B is
3 molH2 O, NaCl is .... % ionised. 32 mmHg . Mole fraction of A in the solution, if it
(A) 60% (B) 50% obeys Raoult's law is:
(C) 100% (D) 40% (A) 0.8 (B) 0.5
(C) 0.2 (D) 0.4
Q3 Which one of the following solutions in water
will have the highest freezing point? Q8 Two liquids X and Y are perfectly immiscible. If
(A) Solution which is 0.1M in KNO3 and 0.2M X and Y have molecular masses in ratio 1 : 2 ,
in Ba(NO3 ) 2 the total vapour pressure of a mixture of X and
(B) Solution which is 0.1M in Ca(NO3 )
2
and Y prepared in weight ratio 2 : 3 should be:
0.1M in Ba(NO3 ) 2 (given Px
0
= 400 torr, Py
0
= 200 torr)
(C) Solution which is 0.2M in urea and 0.2M in (A) 300 torr (B) 466.7 torr
glucose (C) 600 torr (D) 700 torr
(D) Solution which is 0.1M both in Al2 (SO 4 )
3
Q9 A 0.50 molal solution of ethylene glycol in water
and 0.1M in K2 SO4 .
is used as coolant in a car. If the freezing point
Q4 A 5.2 molal aqueous solution of methyl alcohol, constant of water is 1.86
∘
per molal, at which
CH3 OH , is supplied. What is the mole fraction temperature will the mixture freeze?
of methyl alcohol in the solution? (A) 1.56∘ C
(A) 1.100 (B) 0.190 (B) −0.93∘ C
(C) 0.086 (D) 0.050 (C) −1.86∘ C
(D) 0.93∘ C
Q5 Consider following cases:
I: 2MCH3 COOHsolution in benzene at 27 C
∘
Q10 Which of the following observations indicates
where there is 100% dimerisation colligative properties?
II: 0.5MKCl aq. solution at 27∘ C, which ionises I. A 0.5MNaBr solution has a higher vapour
100% Which is/are true statements(s) : pressure than 0.5MBaCl2 .
(A) both are isotonic II. A 0.5MNaOH solution freezes at a lower
(B) I is hypertonic temperature than pure water.
(C) II is hypotonic
(D) none is correct

Android App | iOS App | PW Website

 JEE

III. Pure water freezes at a higher temperature (A) Add 50 mL water

than pure ethanol. (B) evaporate 50 mL solution
(A) Only I (B) Only II (C) add 0.1 mol KCl
(C) Only III (D) I and II (D) add 0.01 mol KCl

Q11 Phenol dimerises in benzene having vant Hoff Q17 In which of the following pairs of solutions will
factor 0.54 . What is the degree of association? the values of the van’t Hoff factor be the same?
(A) 1.92 (B) 0.98 (A) 0.05 M K4[Fe(CN)6] and 0.10 M FeSO4
(C) 1.08 (D) 0.92 (B) 0.10 M K4[Fe(CN)6] and 0.05 M FeSO4
(NH4)2SO4. 6H2O
Q12 Henrys Law constant for CO2 in water is
(C) 0.20 M NaCl and 0.10 M BaCl2
1.67 × 10
8
Pa at 298 K. CO2 gas is packed in
(D) 0.05 M FeSO4.(NH4)2SO4.6H2O and 0.02 M
500mlH2 O at 298 K under a pressure of
KCl.MgCl2.6H2O
2.5 atm . Thus, quantity of CO2 in 500mlH2 O

is: Q18 Which of the following statement is correct?

(A) 0.00152 mol (A) CH3COCH3 & CHCl3 mixture ⇒ ΔHsolution < 0
(B) 0.171 mol & ΔVsolution < 0
(C) 0.012 mol (B) When mercuric iodide is added to an
(D) 0.042 mol aqueous solution of potassium iodide then
freezing point is raised and boiling point is
Q13 A complex of iron and CN− ion is 100%, ionized
lowered.
at 1 m (molal). If its elevation in boiling point is
(C) NaCl is less soluble in D2O than H2O.
2.08 . Then the complex is
(D) H2O and C2H5OH mixture ⇒ ΔHsolution < 0 &
:
−1
[Kb = 0.52 K kg mol ]
ΔVsolution < 0
(A) K3 [Fe(CN)6 ]
(B) [Fe(CN)2 ] Q19 For the depression of freezing point experiment
(C) K4 [Fe(CN)6 ] involving non-volatile solute. The correct
(D) K2 [Fe(CN)6 ] statement(s) is/are:
(A) Vapour pressure of pure solvent is more than
Q14 The Vant Hoff factor of an aqueous solution of
that of solution.
storage battery containing 49%H2 SO 4 by
(B) Vapour pressure of pure solvent is less than
weight and a depression in freezing point of
that of solution.
27.9 K is approximately;
(C) Only solute molecules solidify at the freezing
.
−1
[Kf H2 O = 1.86 KKgmol ]
point.
(A) 1 (B) 1.5
(D) Only solvent molecules solidify at the
(C) 3 (D) 2
freezing point.
Q15 The vapour pressure lowering caused by the
Q20 2.5% (mass/volume) NaCl in water at ∘
27 C is
addition of 100g of sucrose (molecular mass =
to be desalinated by reverse osmosis. The
342) to 1000g of water if the vapour pressure of
minimum external pressure to be applied on
pure water at 25oC is 23.8 mm Hg
solution for desalination of water is
(A) 1.25 mm Hg (B) 0.125 mm Hg
(A) 21.05 atm
(C) 1.15 mm Hg (D) 0.012 mm Hg
(B) 10.52 atm
Q16 We have 100 mL of 0.1 M KCl solution. To make it (C) 8.52 atm
0.2 M, (D) 6.52 atm

Android App | iOS App | PW Website

 JEE

Q21
The Van’t Hoff factor of K4[Fe (CN)6] assuming 100% (2) The osmotic pressure of the solution of Y will
dissociation is______. be lower than that X
(3) The freezing point of the solution of X will be
Q22 Aqueous solution of Barium phosphate which is
ΔTf
lower than that of Y
100% ionized has Kf
as 0.40. Hence, given (4) The relative lowering of vapour pressure of
solution is x × 10–2 molal. What is the value of x? both the solutions will be the same
Select the correct answer from the option given
Q23 MX2 dissociates into M2+ and X– ions in an
below
aqueous solution, with a degree of dissociation
(A) 1, 2 and 3
(α) of 0.5. The ratio of the observed depression
(B) 2, 3 and 4
of freezing point of the aqueous solution to the
(C) 1, 2 and 4
value of the depression of freezing point in the
(D) 1, 3 and 4
absence of ionic dissociation is______.
Q27 Determine the volume/volume percent solution
Q24 Statement I: Addition of AgCN (s) to aqueous
made by combining 25 mL of ethanol with
solution of KCN increases the freezing point.
enough water to produce 200 mL of the
Statement II: A complex K [Ag(CN)2 ] is formed
solution
in above process.
(A) 12.5 (B) 20
(A) Statement-I and Statement-II both are
(C) 40 (D) 25
correct.
(B) Statement-I is correct but Statement-II is Q28 A solution containing 4.0 g of PVC in 2 litre of
incorrect. dioxane (industrial solvent) was found to have
(C) Statement-I is wrong but Statement-II is an osmotic pressure 3.0 × 10
−4
atm at ∘
27 C .
True. The molar mass of the polymer (g/mol) will be :
(D) Both Statement I and II are wrong. (A) 1.6 × 104
(B) 1.6 × 105
Q25 Statement I: The observed molar mass of
(C) 1.6 × 103
Acetic acid in Benzene is more than that in H2O.
(D) 1.6 × 102
Statement II: Molecules of Acetic acid dimerize
in Benzene due to H-bonding. Q29 Moles of Na2 SO 4 to be dissolved in 12 mole
(A) Statement-I and Statement-II both are water to lower its vapour pressure by 10 mmHg
correct. at a temperature at which vapour pressure of
(B) Statement-I is correct but Statement-II is pure water is 50 mm is:
incorrect. (A) 1.5 mole (B) 2 mole
(C) Statement-I is wrong but Statement-II is (C) 1 mole (D) 3 mole
True.
(D) Both Statement I and II are wrong. Q30 During osmosis, flow of water through a
semipermeable membrane is
Q26 Consider 0.1 M solutions of two solutes X and (A) from both sides of semipermeable
Y . The solute X behaves as a univalent membrane with equal flow rates
electrolyte while the solute Y dimerises in (B) from both sides of semipermeable
solution. Which of the following statements are membrane with unequal flow rates
correct regarding these solutions? (C) from solution having lower concentration
(1) The boiling point of the solution of X will be only
higher than that of Y (D)

Android App | iOS App | PW Website

 JEE

from solution having higher concentration molar mass = 164 ) in water if the observed
only molar mass by measuring elevation in boiling
point is 65.6 :
Q31 At 25 C
∘
, the vapour pressure of pure liquid A
(A) 75% (B) 25%
(mol. wt. = 40 ) is 100 torr, while that of pure
(C) 65% (D) None of these
liquid B is 40torr , (mol. wt. = 80 ). The vapour
pressure at ∘
25 C of a solution containing 20 g Q37 A solution of 0.640 g of azulene in 100.0 g of
of each A and B is: benzene boils at 80.23 C
∘
. The boiling point of
(A) 80 torr benzene is ∘
80.10 C ; and Kb is ∘
2.53 C/molal .
(B) 59.8 torr What is the molecular mass of azulene?
(C) 68 torr (A) 108 (B) 99
(D) 48 torr (C) 125 (D) 134

Q32 K2 HgI4 is 40% ionised in aqueous solution. The Q38 Which of the following statements are correct
value of its vant Hoff factor (i) is about the solubility of gases in liquids?
(A) 1. 6 (B) 2. 0 (A) Mole fraction of the gas in the solution is
(C) 2. 2 (D) 1. 8 directly proportional to the partial
pressure of the gas above the solution.
Q33 1 kg of water under a nitrogen pressure of 1
(B) Volume of the gas dissolved measured at
atmosphere dissolves 0.02gm of nitrogen at
the pressure used is independent of
293 K . Calculate Henry's law constant :
the pressure of the gas.
(A) 7.7 × 104 atm
(C) Solubility of gas is always an exothermic
(B) 7.7 × 103 atm
process.
(C) 2 × 10−5 atm
(D) Gibbs energy change of dissolution of a
(D) 2 × 10−2 atm
gas may be positive or negative.
Q34 Reverse osmosis is a process,
Q39 Identify the mixture that shows positive
(A) in which applied pressure to the solution
deviations from Raoult's Law
side, is larger than the osmotic pressure
(A) CHCl3 + (CH3)2CO
(B) in which solvent moves from solution of
(B) (CH3)2CO + C6H5NH2
higher concentration to solution of lower
(C) (CH3)2CO + CS2
concentration
(D) CHCl3 + C6H6
(C) which is used for desalination of sea water
(D) All of the above Q40 We have three aqueous solutions of NaCl
labelled as 'A', 'B' and 'C' with concentration 0.1
Q35 If Mnormal is the normal molecular mass and α
M, 0.01 M and 0.001M, respectively. The value of
is the degree of ionization of K3 [Fe(CN)6 ] ,
van't Hoff fractor (i) for these solutions will be in
then the abnormal molecular mass of the
the order;
complex in the solution will be:
(A) iA < iC < iB
(A) Mnormal (1 + 2α)
−1

(B) iA < iB < iC

(B) Mnormal (1 + 3α)
−1

(C) iA > iB > iC

(C) Mnormal (1 + α)
−1

(D) iA = iB = iC
(D) equal to Mnormal
Q41 The quantity which changes with temperature
Q36 Calculate the percentage degree of
is:
dissociation of an electrolyte XY2 (Normal
(A) Mass percentage

Android App | iOS App | PW Website

 JEE

(B) Molality (B) (A)-(III), (B)-(II), (C)-(I), (D)-(IV)

(C) Mole fraction (C) (A)-(III), (B)-(I), (C)-(IV), (D)-(II)
(D) Molarity (D) (A)-(I), (B)-(III), (C)-(II), (D)-(IV)

Q42 The osmotic pressure of a dilute solution is 7 ×
105 Pa at 273 K. Osmotic pressure of the same
solution at 283 K is ______ × 104 Nm–2.
integer)
Q43 The vapour pressures of pure liquids A and B are
400 and 600 mm Hg, respectively at 298 K. On
mixing the two liquids, the sum of their initial
volumes is equal to the volume of the final
mixture. The mole fraction of liquid B is 0.5 in the
mixture. The vapour pressure of the final
solution, the mole fractions of components A
and B in vapour phase respectively, are
(A) 500 mm Hg, 0.4, 0.6
(B) 500 mm Hg, 0.5, 0.5
(C) 450 mm Hg, 0.4, 0.6
(D) 450 mm Hg, 0.5, 0.5
Q44 What weight of glucose must be dissolved in
100 g of water to lower the vapour pressure by
0.20 mm Hg?(Assume dilute solution is being
formed)
Given: Vapour pressure of pure water is 54.2 mm
Hg atroom temperature. Molar mass of glucose
is 180 g mol–1.
(A) 4.69 g (B) 3.59 g
(C) 2.59 g (D) 3.69 g
Q45 Match List-I with List-II.
Q46 Boiling point of a 2% aqueous solution of a non-
volatile solute A is equal to the boiling point of
(Nearest 8% aqueous solution ofa non-volatile solute B.
The relation between molecular weights of A
and B is
(A) MA = 4MB (B) MB = 4MA
(C) MA = 8MB (D) MB = 8MA
Q47 The number of pairs of the solution having the
same value of the osmotic pressure from the
following is __________.
(Assume 100% ionization)
(A) 0.500 M C2H5OH and 0.25 M KBr (aq)
(B) 0.100 M K4[Fe(CN)6] (aq) and 0.100 M
FeSO4(NH4)2SO4(aq)
(C) 0.05 M K4[Fe(CN)6] (aq) and 0.25 M NaCl (aq)
(D) 0.15 M NaCl (aq) and 0.1 M BaCl2 (aq)
(E) 0.02 M KCl MgCl2.6H2O (aq) and 0.05 M KCl
(aq)
Q48 The elevation in boiling point for 1 molal solution
of non-volatile solute A is 3 K. The depression in
freezing point for 2 molal solution of A in the
same solvent is 6 K. The ratio of Kb and Kf i.e
Kb/Kf is 1 : X. The value of X is ________. [Nearest
Integer]
Q49 Of the following four aqueous solutions, total
number of those solutions whose freezing point
is lower than that of 0.10 M C2H5OH is _____ .
(Integer answer)
(A) 0.10 M Ba3(PO4)2
(B) 0.10 M Na2SO4
(C) 0.10 M KCl
(D) 0.10 M Li3PO4

Q50 1.46 g of a biopolymer dissolved in a 100 mL

Choose the correct answer from the options
given below:
(A) (A)-(III), (B)-(I), (C)-(II), (D)-(IV)
water at 300 K exerted an osmotic pressure of
2.42 × 10–3 bar.
The molar mass of the biopolymer is _____ × 104
g mol–1 (Round off to the Nearest Integer)
[Use: R = 0.083 L bar mol–1 K–1]

Android App | iOS App | PW Website

 JEE

Answer Key
Q1 (A) Q26 (A)

Q2 (C) Q27 (A)

Q3 (C) Q28 (B)

Q4 (C) Q29 (D)

Q5 (A) Q30 (C)

Q6 (A) Q31 (A)

Q7 (A) Q32 (D)

Q8 (C) Q33 (A)

Q9 (B) Q34 (D)

Q10 (D) Q35 (B)

Q11 (D) Q36 (A)

Q12 (D) Q37 (C)

Q13 (A) Q38 (A, B, C)

Q14 (B) Q39 (C)

Q15 (B) Q40 (B)

Q16 (B, D) Q41 (D)

Q17 (B, D) Q42 73

Q18 (A, B, C) Q43 (A)

Q19 (A, D) Q44 (D)

Q20 (A) Q45 (A)

Q21 (5) Q46 (B)

Q22 (8) Q47 4.00

Q23 (2) Q48 1

Q24 (A) Q49 4

Q25 (A) Q50 15

Android App | iOS App | PW Website