Professional Documents
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Level # 1 ................................................................................... 45
Level # 2 ........................................ ........................................ 35
Level # 3 ........................................ ........................................ 17
Level # 4 ........................................ .......................................... 5
Total No. of questions ............................................................ 102
LEVEL # 1
Q.1 The equivalent mass of calcium phosphate Q.8 The number of milli equivalents of acid in 100
Ca3(PO4)2 (Mol. wt. = 310) is - ml of 0.5 N HCl solution is -
(A) 310/2 (B) 310/6 (A) 50 (B) 100
(C) 310/3 (D) 310 (C) 25 (D) 200
Q.2 The equivalent mass of crystalline oxalic acid Q.9 For preparation of one litre of N/10 H2SO 4
is equal to the equivalent weight of - solution we need H2SO 4 equal to -
Q.3 Molecular mass of tribasic acid is W. Its Q.10 100 c.c. of 0.5 N NaOH solution is added to
10 c.c. of 3N H2SO 4 solution and 20 c.c. of
equivalent mass would be -
1N HCl solution. The solution will be -
(A) W/2 (B) W/3
(A) Strongly acidic (B) Alkaline
(C) W (D) 3W
(C) Neutral (D) Fairly acidic
Q.4 Equivalent wt. of H3PO 4 in each of the
reaction will be respectively- Q.11 The normality of a solution obtained by mixing
100 ml of 0.2 N HCl and 500 ml of 0.12 M
H3PO 4 + OH– H2PO 4– + H2O
H2SO 4 is -
H3PO 4 + 2OH– HPO 42– + 2H2O (A) 0.233 N (B) 0.466 N
H3PO 4 + 3OH– PO43– + 3H2O (C) 0.116 N (D) 2.33 N
(A) 98, 49, 32.67
Q.12 0.115 gm of sodium metal was dissolved in
(B) 49, 98, 32.67 500 ml of the solution in distilled water. The
(C) 98, 32.67, 49 normality of the solution would be -
(D) 32.67, 49, 98 (A) 0.010 N (B) 0.0115 N
(C) 0.023 N (D) 0.046 N
Q.5 Sulphur forms two chlorides S2Cl 2 and SCl2.
The equivalent mass of sulphur in SCl2 is 16 Q.13 The amount of water required to be added to
g/mole. The equivalent mass of sulphur in 200 c.c. of a semi-normal solution of NaOH
S2Cl 2 is - to make it exactly decinormal is -
(A) 8 g/mole (B) 16 g/mole (A) 200 c.c. (B) 400 c.c.
(C) 48 g/mole (D) 32g/mole (C) 800 c.c. (D) 100 c.c.
Q.6 Equivalent mass of NH3 is - Q.14 The amount of water to be added to 100 c.c.
(NH3 + H+ NH4+) of normal HCl solution to make it decinormal
is -
(A) 17 (B) 17/2
(A) 900 c.c. (B) 850 c.c.
(C) 1.7 (D) 17/3
(C) 400 c.c. (D) 600 c.c.
Q.7 The equivalent weight of iron in ferric chloride Q.15 The amount of CuSO4. 5H2O required to
is (At. wt. of Fe = 55.8) – prepare 500 c.c. of 0.5 N solution is -
(A) 25.8 (B) 18.6 (Mol.wt. of CuSO4.5H2O = 249.5)
(C) 71.8 (D) 23.6 (A) 249.5 (B) 249.5/2
(C) 249.5/8 (D) 249.5/3
Q.16 100 c.c. of 0.6 N H2SO4 and 200 c.c. of 0.3 Q.24 On dissolving 1 mole of each of the following
N HCl were mixed together. The normality of acids in 1 litre water, the acid which does
the resulting solution will be - not give a solution of strength 1 N is -
(A) 0.2 N (B) 0.4 N (A) HCl (B) HClO4
(C) HNO3 (D) H3PO 4
(C) 0.8 N (D) 0.6 N
Q.17 How many gram of KMnO4 are contained in Equivalent weight of metal
4 litres of 0.05 N solution? The KMnO4 is to
be used as an oxidant in acid medium. Q.25 a1 gm of the metal gave a2 gm of its oxide.
(Mol. wt. of KMnO4 = 158) Hence equivalent weight of the metal -
(A) 1.58 g (B) 15.8 g
a1 a 2 a1
(C) 6.32 g (D) 31.6 g (A) × 8 (B) × 8
a 2 a1 a1
1
1
JK
8 (D) a × 8
2
the molarity of the final mixture would be -
(A) 3.25 M (B) 4.0 M
(C) 3.75 M (D) 3.50 M Q.26 5.6 g of a metal forms 12.7 g of metal chloride.
Hence equivalent wt. of metal is -
Q.19 If 250 ml of 0.25 M NaCl solution is diluted (A) 127 (B) 254
with water to a volume of 500 ml, the new (C) 56 (D) 28
concentration of the solution is -
(A) 0.167 M (B) 0.125 M Q.27 0.5 g of a metal on oxidation gave 0.7 g of
(C) 0.0833 M (D) 0.0167 M its oxide. The equivalent weight of the metal
is -
Q.20 100 ml of 0.3 N HCl is mixed with 200 ml of
(A) 40 (B) 20
0.6N H2SO 4. The final normality of the
(C) 14 (D) 10
resulting solution will be -
(A) 0.1 N (B) 0.2 N
Q.28 An element f orms an oxide, in which
(C) 0.3 N (D) 0.5 N
the oxygen is 20% of the oxide by weight,
Q.21 What is the normality of a 1 M solution of the equivalent weight of the given element
H3PO4 ? will be -
(A) 0.5 N (B) 1.0 N (A) 32 (B) 40
(C) 60 (D) 128
(C) 2.0 N (D) 3.0 N
Q.22 9.8 g of H2SO4 is present in 2 litres of a Q.29 In a metal chloride, the weight of metal and
solution. The molarity of the solution is - chlorine are in the ratio of 1 : 2. The
(A) 1 M (B) 0.05 M equivalent weight of the metal will be-
(A) 71 (B) 35.5
(C) 0.02 M (D) 2 M
(C) 106.5 (D) 17.75
Q.23 10 ml. of N-HCl, 20 ml of N/2 H2SO 4 and 30
ml of N/3 HNO3 are mixed together and Q.30 0.84 gms, of metal hydride contains 0.04 gms
volume made to one litre. The normality of of hydrogen. The equivalent wt. of metal is.
the resulting solution is - (A) 80 (B) 40
(C) 20 (D) 60
(A) 3N/100 (B) N/10
(C) N/20 (D) N/40
Q.39 1.575 g of a dibasic acid is neutralised by
Acid-Base Neutralization
25 mL 1 M NaOH solution. Hence, molar mass
of dibasic acid is -
Q.31 2 gm of a base whose equiv wt. is 40 reacts (A) 126 g mol–1 (B) 63 g mol–1
with 3 gm of an acid. The equiv wt. of the (C) 12.6 g mol –1 (D) none
acid is -
(A) 40 (B) 60
(C) 10 (D) 80 Redox Titration
Q.32 What is the strength in gm/litre of a solution Q.40 How many moles of K2Cr2O7 are reduced by
of H2SO 4, 12 ml of which neutralizes 15 ml 1 mole of formic acid –
of N/10 NaOH solution ?
(A) 1/3 mole (B) 1 mole
(A) 9.233 gm/lit (B) 0.0923 gm/lit (C) 2/3 mole (D) 5/3 mole
(C) 6.125 gm/lit (D) 4.9 gm/lit
Q.34 If 20 ml of 0.4 N NaOH solution completely Q.42 1 mol of MnO4– will oxidise x mol of ferric
neutralises 40 ml of a dibasic acid, the oxalate in acidic medium, x is -
molarity of the acid solution is -
(A) 0.1 M (B) 0.2 M 5 6
(C) 0.3 M (D) 0.4 M (A) (B)
6 5
Q.2 How many grams of I2 are present in a Q.9 If 200 mL of 0.1 M KHC2O4 , 300 mL of 0.2 M
solution which requires 40 ml of 0.11 N H 2 C 2 O 4 and 500 mL of 0.3 M NaCl is
Na2S2O 3 to react with it ? (I = 127) neutralized by 140 mL of Ca(OH)2 . What is its
S2O32– + I2 S4O62– + 2I¯ molarity ?
(A) 12.7 g (B) 0.558 g (A) 1 (B) 0.5
(C) 25.4 g (D) 11.4 g (C) 1.5 (D) 2
Q.19 KMnO4 reacts with oxalic acid according to the Q.26 If in a reaction HNO3 is reduced to NO, the
reaction : mass of HNO3 absorbing one mole of electrons
2KMnO4 + 5C 2 O 24 + 16H+ would be -
2Mn2+
+ 10CO2 + 8H2O (A) 12.6 g (B) 21.0 g
Then, 20 mL of 0.1 M KMnO4 is equivalent to: (C) 31.5 g (D) 63.0 g
(A) 30 mL of 0.5 M C2H2O4 (oxalic acid)
(B) 50 mL of 0.1 M C2H2O4 (oxalic acid) Q.27 If in a given reaction NO 3 is reduced to NH4 ,
(C) 20 mL of 0.5 M C2H2O4 (oxalic acid)
the mass of NO 3 absorbing one mole of
(D) 10 mL of 0.1 M C2H2O4 (oxalic acid)
electrons would be -
(A) 31.0 g (B) 12.4 g
Q.20 The number of moles of Cr2O72– required to
(C) 6.29 g (D) 7.75 g
oxidize one mole of FeC2O4 in acidic medium -
Q.28 For the reaction
(A) 0.5 (B) 0.6
(C) 0.2 (D) 0.3 Br2 OH Br BrO 3 H2O what is the
equivalent weight of Br2
Q.21 The number of moles of MnO4– ions needed to (A) M/8 (B) M/5
react with one mole of sulphite ions in acidic (C) 3M/5 (D) 5M/8.
medium are - Q.29 Equivalent weight of iron in Fe2O3 would be -
(A) 0.8 (B) 0.4 (Fe = 56)
(C) 0.6 (D) 0.5 (A) 28 (B) 56 (C) 18.6 (D) 112.
Q.30 For the reaction,
Q.22 When the ion Cr2O72– acts as an oxidant in
acidic aqueous solution the ion Cr3+ is formed. M x MnO4 MO3 Mn2
How many moles of Sn2+ would be oxidised to if one mole of MnO 4 oxidises 1.67 moles of
Sn4+ by one mole of Cr2O72– ions - M x to MO 3 , then the value of x in the
(A) 2/3 (B) 3/2 reaction is -
(C) 2 (D) 3 (A) 5 (B) 3 (C) 2 (D) 1
Q.31 Amount of oxalic acid required to prepare 250 Q.34 The value of n in the equation,
mL of N/10 solution (Mol. mass of oxalic acid =
Cr2 O 72 + 14H+ + ne¯ 2Cr3+ + 7H2O is:
126) is:
(A) 1.5759 g (B) 3.15 g (A) 2 (B) 3
(C) 15.75 g (D) 63.0 g (C) 4 (D) 6
Q.32 The equivalent mass of phosphoric acid (H3PO4) Q.35 Mixture of 1mol MgCl2 and 2 mol H2SO4 can
is 49. It behaves as ... acid. be neutralised by:
(A) monobasic (B) dibasic (A) 1 mol KOH (B) 2 mol Ca(OH)2
(C) tribasic (D) tetrabasic (C) 2 mol NaOH (D) 2 mol KOH
LEVEL # 1
Q u s. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A ns . B B B A D A B A B C A A C A C B C C B D
Q u s. 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40
A ns . D B A D A D B A D C B C B A A B B A A A
Q u s. 41 42 43 44 45
A ns . B A B A B
LEVEL # 2
Qus. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
Ans. A B B A B B B D B A D C C B C B D A B A
Qus. 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35
Ans. B D C C B B D C C C A B C D B
LEVEL # 3
1. B 2. C 3. A 4. B 5. D 6. True 7. False 8. True
LEVEL # 4
SECTION : A
Qus. 1
Ans. B
SECTION : B
Qus. 1 2 3 4
Ans . A A B D