Chemistry

KVPY (+1) Assignment – 2

1. A 5.0 mL solution of H2O2 liberates 1.27 g of iodine from an acidified KI solution. The
percentage strength of H2O2 is :
(a) 11.2 (b) 5.6 (c) 1.7 (d) 3.4

2. If an ore sample containing Mn is treated with 50 mL of 0.2750 M Na2C2O4 and the

unreacted Na2C2O4 required 8.28 mL of 0.1232 M KMnO4 in acidic medium, the number
of moles of Mn in the ore is
(a) 1.38 × 10-2 (b) 1.49 × 10-3 (c) 1.15 × 10-2 (d) 8.12 × 10-3

3. 10 mL of a solution of H2O2 of 10 volume strength decolourises 100 mL of KMnO4

solution acidified with dil. H2SO4. The amount of KMnO4 in the given solution is (K = 39,
Mn = 55)
(a) 0.282 g (b) 0.564 g (c) 1.128 g (d) 0.155 g

4. 3.4 g sample of H2O2 solution containing x% H2O2 by weight requires x mL of a KMnO4

solution for complete oxidation under acidic condition. The normality of KMnO4 solution
is
(a) 1 N (b) 2 N (c) 3 N (d) 0.5 N

5. If 100 mL of acidified 2 N H2O2 is allowed to react with KMnO4 solution till there is a
light tinge of purple colour, the volume of oxygen produced at STP is
(a) 2.24 L (b) 1.12 L (c) 3.36 L (d) 4.48 L

6. In the following equation :


CrO 24  S2 O32  O H  [Cr(OH) 4 ]1  SO 24
What volume of 0.2 M Na2CrO4 solution is required just to react with 30 mL of 0.2 M
Na2S2O3 solution.
(a) 40 mL (b) 80 mL (c) 20 mL (d) 60 mL

7. How many moles of MnO 4 ion will react with 1 mol of ferrous oxalate in acidic medium?
(a) 1/5 (b) 2/5 (c) 3/5 (d) 5/3

8. In a reaction, 4 mol of electrons are transferred to 1 mole of HNO3. The possible product
obtained due to reduction is:
(a) 0.5 mol of N2 (b) 0.5 mol of N2O (c) 1 mol of NO2 (d) 1 mol of NH3
9. If equal volumes of 1 M KMnO4 and 1 M K2Cr2O7 solution are allowed to oxidize Fe (II)
to Fe (III) in acidic medium, then Fe (II) oxidised will be
(a) More by KMnO4 (b) More by K2Cr2O7
(c) Equal in both cases (d) Can’t be determined

10. Sulphuryl chloride SO2Cl2 reacts with water to give a mixture of H2SO4 and HCl. Moles of
NaOH required to neutralize the solution formed by adding 1 mol of SO2Cl2 to excess
water is are
(a) 1 (b) 2 (c) 3 (d) 4

11. 100 mL of 0.01M KMnO4 oxidised 100 mL H2O2 in acidic medium. Volume of the same
KMnO4 required in alkaline medium to oxidise 100 mL of the same H2O2 will be ( MnO 4
changes to Mn2- in acidic medium and to MnO2 in alkaline medium)
100 500 300
(a) mL (b) mL (c) mL (d) None of these
3 3 5

12. 10 mL of H2O2 solution (volume strength = x) required 10 mL of N/0.56 MnO 4 solution

in acidic medium. Hence, x is :
(a) 0.56 (b) 5.6 (c) 0.1 (d) 10

13. 4I  Hg 2  HgI 24

1 mol each of Hg2+ and I will form HgI 24 .
(a) 1 mol (b) 0.5 mol (c) 0.25 mol (d) 2 mol