CPP-SANKALP_ST-08-PH-I

CPP
STOICHIOMETRY- SHEET : 8
(Titration - Acid-Base, simple and back)

LEVEL - 1
1. 10 g CaCO3 were dissolved in 250 ml of M HCl and the solution was boiled. What volume of 2 M KOH
would be required to eqivalence point after boiling? Assume no change in volume during boiling.
2. Potassium acid oxalate K2C2O 4 . 3H2C2O 4 . 4H2O can be oxidized by MnO4– in acid medium. Calculate
the volume of 0.1 M KMnO 4 reactign in acid solution with one gram of the acid oxalate.
3. 0.5M KMnO 4 solution completely reacts with 0.05 M FeC2O 4 solution under acidic conditions where
the products are Fe3+, CO 2 and Mn2+. The volume of FeC2O 4 used is 125 ml. What volume of KMnO 4
was used.
4. A solution is made by mixing 200 ml of 0.1 M FeSO 4, 200 mL of 0.1 M KMnO4 and 600 ml 1 M HClO 4.
A reaction occurs in which Fe2+ is converted to Fe3+ and MnO4– to Mn2+ in acid solution. Calculate the
concentration of each ion.
5. 1.5 g of chalk were treated with 10 ml of 4N - HCl. The chalk was dissolved and the solution made to
100 ml 25 ml of this solution required 18.75 ml of 0.2 N - NaOH solution for complete neutralisation.
Calculate the percentage of pure CaCO 3 in the sample of chalk?

6. Hydrogen peroxide in aqueous solution decomposes on warming to give oxygen according to the
equation 2H2O2(aq.) → 2H2O(l) + O2(g) under conditions where one mole of gas occupies
24 dm3, 100 cm3 of XM solution of H2O2 produces 3dm3 of O2. X is thus?
7. One gram of a mixture of Na2CO 3 and NaHCO 3 consumes y gram equivalents of HCl for complete
neutralisaton. One gram of the mixture is strongly heated, then cooled and the residue treated with
HCl. How many gram equivalents of HCl would be required for complete neutralisation?
8. 5 ml of N HCl, 20 ml N/2 H2SO 4 and 30 ml of N/3 HNO3 are mixed together and volume made to 1 litre.
The normality of resultingsolution?
9. 100 mL of 0.1N I 2 oxidizes Na2S2O 3 in 50 ml solution to Na2S4O6. The normality of this hypo solution
against KMnO 4 (which oxidizes it to Na2SO 4) would be
(A) 0.1 (B) 0.2 (C) 1.0 (D) 1.6
10. x mmol of XeF4 quantitatively oxidized KI to I2 and liberated Xe, alongwith formation of KF. This iodine
required 20 ml of decinormal hypo solution for exact titration. The value of x is
(A) 0.5 (B) 1.0 (C) 2.0 (D) 5.0

LEVEL - 2
11. 1 mole of chlorine reacts exactly with a given sample of HI to give ICl and HCl completely. If exactly
same amount of HI is dissolved in distilled water to give 10L solution, normality of this acid solution
against NaOH will be
(A) 0.05 (B) 0.1 (C) 0.2 (D) 0.4

12. 0.1 mol of MnO4– (in acidic medium) can :

(A) oxidise 0.5 mol of Fe2+ (B) oxidise 0.166 mol of FeC2O4
(C) oxidise 0.25 mol of C2O42– (D) oxidise 0.6 mol of Cr2O72–
13. Sb2S3 is oxidized to SbF5 and SF 6 by fluorine (F 2). If meq of antimony (Sb), sulfur and fluorine in this
redox reaction are x, y and z respectively then
(A) x = y (B) x + y = z (C) 9x = y (D) 2x + 3y = z
CPP-SANKALP_ST-08-PH-I

14. 10.78 g of H3PO 4 in 550 ml solution is 0.40 N. Thus this acid:

(A) has been neutralised to HPO 42– (B) has been neutralized to PO 42–
2–
(C) has been reduced to HPO 3 (D) has been neutralised to H2PO 4–
15. 100 mL of a solution of an acid (molar mass = 98g/ mol) containing 29.4 g of the acid per litre were
completely neutalized by 40 meq. of NaOH per 500 mL. The basicity of the acid is:
(A) 3 (B) 2 (C) 1 (D) data insufficient
16. H2C2O 4 and NaHC2O4 be have as acids as well as reducign agents. Whih are correct statement?
(A) equivalent weight of H2C2O4 and NaHC2O4 are equal to their molecualr weights when behaving as
reducing agents
(B) 100 ml of 1 N solution of each is neutralised by equal volume of 1M Ca(OH)2
(C) 100 ml of 1 N solution of eah is neutralised by equal volume of 1N Ca(OH)2
(D) 100 ml of 1 M solution of each is oxidised by equal volumes of 1M KMnO 4
17. Which of the following statemetns are correct?
(A) the point at which an equivalent amount of the titrant is added is called the equivalence point.
(B) the point at which the reaction is observed to be complete is called the end point
(C) at the end point of a reaction there is no change in the properties of teh solution
(D) at the equivalence point of a reaction the stioichiometric amount of the titrant is not added
18. Which of following will be present in the solution formed when 50 mL of 0.1 M HCl is mixed
with 50 mL of 0.1 M NaOH ?
(A) 4.5 m mol of H+ (B) 0.05 m mol of OH–
(C) 0.05 M NaCl (D) 10-7 M of H+ ion
19. Which of the following statements are correct ?
(A) during the titration of a strong acid against a strong base, the pH at the equivalence point will
be neutral
(B) during the titration of a weak acid against a strong base, the pH at the equivalence point will
be alkaline
(C) during the titration of a weak acid against a strong base, the pH at the equivalence point will
be acidic
(D) during the titration of a weak acid against a weak base, the pH at the equivalence point will be
neutral
20. 1 mol of H2SO4 will exactly neutralize
(A) 2 mol of ammonia (B) 1 mol of Ba(OH)2
(C) 0.5 mol of Ba(OH)2 (D) 2 mol of KOH

ANSWER KEY
1. V = 25 mL 2. V = 31.68 ml 3. 7.5 ml
3+ – + 2+
4. Fe = 0.02M; MnO4 = 0.016 M; H = 0.568 M; Mn = 0.004M;
SO42 – = 0.02M; K+ = 0.02M, ClO4– = 0.6M
5. 83.33
6. 2.5
7. y gram equivalents
8. N/40
9. D 10. A 11. B 12. A, B, C
13. B, C 14. A 15. A 16. D
17. A, B 18. C, D 19. A, B 20. A, B, D