‫بسم هللا الرحمن الرحيم‬

Chapter 14
1. Write a net ionic equation for the reaction between solutions of

a. nitric acid and lithium hydroxide

b. ammonia and hydrogen iodide
c. hydrogen fluoride and potassium cyanide
d. calcium hydroxide and nitrous acid, HNO2

2. Given three acid-base indicators: methyl orange (end point at pH 4),

bromthymol blue (end point at pH 7), and phenolphthalein (end point at
pH 9), which would you select for the following acid-base titrations?
a. formic acid with sodium hydroxide
b. ethylamine, C2H5NH2, with hydrochloric acid
c. sodium acetate with hydrochloric acid
d. perchloric acid with lithium hydroxide

3. 75.00 mL of 0.1350 M perchloric acid is titrated with 0.3375 M KOH.

Calculate the pH of the resulting solution (assuming volumes are
additive) when the following amounts of base are added.
a. 10.00 mL b. 20.00 mL c. 30.00 mL

4. Thirty mL of 0.100 M acetic acid, HC2H3O2, is titrated with NaOH.

a. What is the pH of the acetic acid solution before titration?

b. How many moles of NaOH are required to react with the

acetic acid?

c. Write a net ionic equation for the reaction.

d. If the total volume of the solution at the equivalence point is

45.0 mL, what is the pH of the solution?
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5. Calculate [OH-] and pH in a solution in which [HClO] is 0.25 M and

[ClO-] is
a. 0.50 M b. 0.25 M c. 0.050 M d. 0.010 M

6. A NaHCO3-Na2CO3 buffer is to be prepared with a pH of 10.00

a. What must be the ratio [HCO3-]/[CO3-2] ?
b. What volume of 1.00 M NaHCO3 should be added to a liter of
1.00 M Na2CO3 to form this buffer?

7. A buffer is made up of one liter each of 0.100 M HC 2H3O2 and 0.150

M NaC2H3O2. Calculate
a. the pH of the buffer
b. the pH of the buffer after the addition of 0.0100 mol HCl
c. the pH of the buffer after the addition of 0.0200 mol NaOH

8. Write the equilibrium equation and the Ksp expression for each of the
following electrolytes.
a. Cu2P2O7 b. Ni3(AsO4)2
c. Fe(OH)3 d. Mg(NbO3)2

9. Complete the following table (Ksp Ag2CO3 = 8 x 10-12):

[Ag+] [CO3-2]

----------------------------------------------------------------
a. 1 x 10-3 M ____________
b. ___________ 5 x 10-3 M
c. 5 x 10-4 M ____________
d. ___________ 1 x 10-5 M
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10. Calculate the solubility (grams per liter) of copper(II) sulfide in

a. pure water
b. 0.010 M Na2S
c. 0.020 M CuSO4

11. The concentrations of various ions in sea water, in mole per liter, are;

Ion Molarity( M) Ksp

Na+ 0.46 NaOH > x 10-5
Mg2+ 0.056 Mg(OH)2 = 6 x 10-12

Ca2+ 0.01 Ca(OH)2 = 5 x 10-5

Al3+ 4 x 10-7 Al(OH)3 = 2 x 10-31

Fe3+ 2 x 10-7 Fe(OH)3 = 3 x 10-39

a. At what
[OH
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] does Mg(OH)2 start to precipitate?

b. At This concentration, will any other ions precipitate?
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c. If enough
OH
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is added to precipitate 50% of the Mg 2+, what percentage of each of

the other ions will be precipitated?
d. Under the conditions in (c), what mass precipitate will be obtained
from one liter of sea water?