EQUILIBRIUM (AAMS Assignment )

(1mark questions)

1. The equilibrium constant for a reaction is 1.3×10-2 at 15oC at 2.9×10-2 at 95oC. Is the reaction endothermic
(Ans. Endothermic)

2 What is the effect of increasing pressure on melting of ice H2O(s) ⇌ H2O(l)?

3. What are the factors n which the rate of evaporation of the liquid depends?

4. Explain what do understand solution.

5. Enlist the characteristic equilibrium constant.

6. The pKa value of acids A, B, C and D are 1.6, 4.9, 3.2 and 2.5. Arrange them in order of thir increasing
strength.

7. What is the value of free change when the system is in equilibrium?

8. Find out Kc for SO3 ⇋ SO2 + 1/2 O2 if Kc for 2SO2 + O2 → 2SO3 is 16.

9. for the reaction 2NO + O2 ⇋ 2NO2, Kp is 12 at 300 K. Find out Kc.

10. What is the expression of Ka for HCN in aqueous solution?

(2 Mark questions)

11. (a) What is ionic product of water

(b) Define pH of a solution.

12. State Le Chatelaine’s principle.

13. (a) How does removal of a product affect Qc?

(b) What is the effect of catalyst on equilibrium constant?

14. Define the following:

(i) Bronsted-lowry acids and bases

(ii) Arrhenius aids and bases

15. Give the corresponding conjugate acid and bases for the following:

HSO4,- NH3, HCO3- and H2O

(3 Mark questions)
16. Write the proton transfer equilibrium for the following acids in aqueous solutions.

(i) H3PO4 (ii) H2SO4 (iii) HCIO4

17. A sample of pure PCI2 was introduced into an evacuated vessel at 473K. After equilibrium was attained,
concentration of PCI5 was found to be 0.5×10-1 mol-1 If value of Kc is 8.3 × 10-3, what are the concentrations of
PCI3 and Cl2 at equilibrium. (Ans. PCI3 = Cl2 = 0.020 mol L-1)
18. Bromine monochloride BrCI decomposes into Bromine and chlorine and the reaction the reaches
equilibrium

2BrCI (g) → Br2 (g) + Cl2 (g)

For which K = 32 at 500k. If initially pure BrCI is present at a concentration of 3.30 × 10-3 molL-1, which is
its molar concentration in mixture at equilibrium? (Ans. 2.6 × 10-4 mol L-1)

19. Account for the following:

(a) Silver chloride dissolves more in water than in silver nitrate solution.

(b) CH3COONa makes slightly basis solution whereas NaCI solution is neutral.

20. Calculate the hydronium ion concentration and hydroxide ion concentration and pH of a 0.2M solution of
hydrocyanic acid. The ionization constant of which is 7.2×10-10 at 298K.
(Ans. H3O+ = 1.2x 10-5 M, pH = 4.92, OH- = 8.3 ×10-10M)

HOTS

21. For a reaction Br2 → 2Br, the equilibrium constant at 600K are 6.1× 10-7.

What is the nature of the reaction? (Ans. Endothermic)

22. Water is rather natural but become a strong base when HCI is dissolved in water. Explain.

23. Vessel at 1000K contains CO2 with a pressure of 0.5atm. Some co2 is converted into CO on addition of
graphite. Calculate the value of Kp if the total pressure of equilibrium mixture is 0.8 atm. (1.8 atm)

24. 20% of N2O4 molecules are dissociated in a sample of a gas at 27oC and 760 tor pressure. Calculate the
density of the equilibrium mixture. (3.12 gL-1)

25. A sample of AgCI was treated with 5.0ml of 105MNa2CO3 solution to give Ag2CO3.The remaining solution
contained in 0.0026g of CI- ions per liter. Calculate the solubility product of AgCI.(Ksp of Ag2CO3 is 8.2 ×10-12)

(Ans. Ks = 1.71 × 10-10)

26. What is hydrolysis? What will be pH of a salt solution of strong base and weak acid?

27. What will be the nature of the medium when these salts are dissolved in water?

(a) NaCI (b) CH3 COOK (c) NH4 NO3

28. Drive expression for determining the pH of a salt of weak acid and strong base.

29. Determine the pH of the following

(a) 10-6M H2SO4

(b) 200 ml of 0.01M HCI mixed unit 200 ml of 0.01M Ba (OH)2.
(c) 50 ml of 0.01M CH3COOH is mixed in 450 ml of 0.1M NaOH.