DPP_LT_CHE_08-07-21

SR.PHYSICAL CHEMISTRY REVISION WORK SHEET

SOLUTIONS & COLLIGATIVE PROPERTIES
1. The vapour pressure of water depends upon :

a) Surface area of container b) Volume of container

c*) Temperature d) All

2. Among the following substances, the lowest vapour pressure is

exerted by :

a) Water b*) Mercury c) Acetone d) Ethanol

4. Two liquids X and Y are perfectly immiscible. If X and Y have

molecular masses in ratio 1 : 2, the total vapour pressure of a mixture
of X and Y prepared in weight ratio 2 : 3 should be ( Px 0 = 400 torr, Py 0

=200 torr)

A*) 600 torr b) 400 torr c) 800 torr d) 1000

torr

5. For a binary ideal liquid solution, the toral pressure of the solution is
given as :

a) Ptotal = P0 A + ( P0 A − P0 B ) X B b*) Ptotal = P0 B + ( P0 A − P0 B ) X A

C) Ptotal = P0 B + ( P0 B − P0 A ) X A d) Ptotal = P0 B + ( P0 B − P0 A ) X B
6. Two liquids A and B have P 0 A and P 0 B in the ratio of 1 : 3 and the ratio

of number of moles of A and B in liquid phase are 1 : 3 then mole

fraction of ‘A’ in vapour phase in equilibrium with the solution is equal
to :

A*) 0.1 b) 0.2 c) 0.5 d)

7. The vapour pressure of the solution of two liquids A( P 0 = 80 mm) and

B( P 0 = 120 mm) is found to be 100 mm when X A = 0.4 . The result shows

that

a) solution exhibits ideal behavior b) solution shows positive

deviastins

c*) solution shows negative deviations

d) solution will show positive deviations for lower concentration and

negative deviations for higher concentrations.

8. Which of the following will form non-ideal solution ?

A*) C2 H 5OH and water b*) HNO3 and water

C*) CHCI 3 and CH 3COCH 3 d) C6 H 6 and C6 H 5CH 3

9. The solubility of N2 ( g ) in water exposed to the atmosphere, when the

partial pressure is 593 mm is 5.3  10 −4 M . its solubility at 760 mm and

at the same temperature is :

a) 4.1 10 −4 M . b*) 6.8 10−4 M . c) 1500 M d) 2400

M

10. Some of the following gases are soluble in water due to formation of
their ions :
I) CO2 ; II) NH 3 III) CHI ; IV) CH 4 V) H 2

Water insoluble gases can be :

a) I, IV, V b) I, V c) I, II, III d*) IV, V
11. One mole of a solute A is dissolved in a given volume of solvent. The
association of the solute take place as follows:
nA An

If  is the degree of association of A, the van’t Hoff factor i is expressed as:


1− +

a) i = 1 −  b) i = 1 + c*) i = n d) i = 1
n 1

12. In which of the following pairs of solutions will the values of the vant
Hoff factor be the same ?

a) 0.05 M K4  Fe ( CN )6  and 0.10 M FeSO4

b*) 0.10 M K4  Fe (CN )6  and 0.05 M FeSO4 ( NH4 )2 SO4 .6H2O

c) 0.20 M NaCI and 0.10 M BaCI 2

d*) 0.05 M FeSO4 ( NH 4 )2 SO4 .6H 2O and 0.02 M KCI . MgCI 2 6H 2O

13. if M normal is the normal molecular mass and  is the degree of ionization

of K 3  Fe ( CN )6  . then the abnormal molecular mass of the complex in

the solution will be :

a) M normal (1 + 2 ) b*) M normal (1 + 3 )

−1 −1

c) M normal (1 +  )
−1
d) equal to M normal

14. PtCl4 .6 H 2O can exist as a hydrated complex 1 molal aq. Solution has

depression in freezing point of 3.720. Assume 100% ionisation and

K f ( H 2O ) = 1.860 mol −1 kg, then complex is-

a)  Pt ( H 2O )6  Cl4 b)  Pt ( H 2O )4 Cl2  Cl2 .2H 2O

c*)  Pt ( H 2O )3 Cl3  Cl.3H 2O d)  Pt ( H2O )2 Cl4  4H 2O

15. How many moles of sucrose should be dissolved in 500 g of water so
as to get a solution which has a difference of 1040 C between boiling
point and freezing point. ( K f = 1.86 K Kg mol −1 , Kb = 0.52 K Kg mol −1 )

a) 1.68 b) 3.36 c) 8.40 d*) 0.840

16. Which of the following has been arranged in order of decreasing

freezing point?

A*) 0.05 M KNO3  0.04 M CaCl2  0.140 M suger  0.075 M CuSO4

b) 0.04 M BaCl2  0.140 M sucrose  0.075 M CuSO4  0.05 M KNO3

c) 0.075 M CuSO4  0.140 M sucrose  0.04 M BaCl2  0.05 M KNO3

d) 0.075 M CuSO4  0.05 M NaNO3  0.140 M sucrose  0.04 M BaCl2

17. A complex of iron and cyanide ions is 100% ionised at 1m (molal). If

its elevation in b.p. is 2.08. Then the complex is ( Kb = 0.520 mol −1 kg ) :

A*) K 3  Fe ( CN )6  b) Fe ( CN )2 c) K4  Fe ( CN )6  d) Fe ( CN )4

18. A solution of x moles of sucrose in 100 grams of water freezes at

−0.20 C. As ice separates the freezing point goes down to 0.250 C . How
many grams of ice would have separated?

a) 18 grams b*) 20 grams c) 25 grams d) 23 grams

19. Consider following cases :

I : 2M CH 3COOH solution in benzene at 270C where there is dimer

formation to the extent of 100%

II : 0.5 M KCl aq. Solution at 270C, which ionises 100%

Which is/are true statements(s) :

A*) both are isotonic b) I is hypertonic c) II is hypotonic d) none is correct

20. Osmotic pressure of a solution of glucose is 1.20 atm and that of a
solution of cane sugar is 2.5 atm. The osmotic pressure of the mixture
containing equal volumes of the two solutions will be

a) 2.5 atm b) 3.7 atm c*) 1.85 atm d) 1.3 atm.

ELECTRO CHEMISTRY

21. The minimum equivalent conductance in fused state is shown by:

1) MgCl2 2*) BeCl2 3) CaCl2 4) SrCl2

22. On electrolyzing a solution of dilute H 2 SO4 between platinum electrodes, then gases

evolved at the anode and cathode are respectively:

1) SO2 andO2 2) SO3andH 2 3*) O2 andH 2 4) H 2 andO2

23. The metal that can not be obtained by electrolysis of the aqueous solution of its salts is:
1) Ag 2) Cr 3) Cu 4) Al
24. A galvanic cell is composed of two hydrogen electrodes, one of which is a standard one. In
which of the following solutions should the other electrode be immersed to get maximum
EMF ?
1) 0.1M HCl 2) 0.1M CH 3COOH 3) 0.1M H 3 PO4 4*) 0.1M

H 2 SO4
25. For which cell EMF is independent of the concentrations of electrolytes used ?

1) Fe FeO( s ) KOH( aq ) NiO( s ) Ni2O3( s ) Ni 2) Pt ( H 2 ) HCl Pt (Cl2 )

3) Zn Zn( NO3 )2 CuSO4 Cu 4*) Hg , HgCl2 KCl AgNO3 Ag

26. Saturated solution of KNO3 is used to make salt bridge because:

−
1) Velocity of K + is greater than that of NO3
−
2) Velocity of NO3 is greater than that of K +
−
3*) Velocity of both K + and NO3 are nearly the same

4) KNO3 is highly soluble in water

27. Consider the standard potentials of the following cells,

A) Mg 2+ + 2e ⎯⎯
→ Mg E 0 = −2.37V

B) Zn 2+ + 2e ⎯⎯
→ Zn E 0 = −0.76V
C) Ni 2 + + 2e ⎯⎯
→ Ni E 0 = −0.25V
D) Fe 2+ + 3e ⎯⎯
→ Fe E 0 = −0.44V
Which is the strongest reducing agent?
2+
1) Mg 2*) Mg 3) Fe3+ 4) Fe
28. A solution containing one mol per litre each of Cu ( NO3 ) 2 , AgNO3 , Hg ( NO3 ) 2 and

Mg ( NO3 )2 Is being electrolysed by using inert electrodes. The value of standard electrode
.
potentials in volt
(reduction potentials) are,

Ag + Ag = 0.80, 2 Hg Hg 22+ = 0.79,

Cu Cu 2+ = +0.34andMg Mg + = −2.37

Which increasing voltage, the sequence of deposition of metals on the cathode will be:
1) Ag, Hg, Cu, Mg 2) Mg, Cu, Hg, Ag 3*) Ag, Hg, Cu 4) Cu, Hg, Ag
−5
29. The specific conductance of saturated solution of CaF2 is 3.86  10 mho cm −1 and that of

water used for solution is 0.15  10 −5 .The specific conductance of CaF2 alone is:

1*) 3.7110−5 2) 4.01 10 −5 3) 3.7  10 −5 4) 3.86  10 −4

30. 0.04N solution of a weak acid has specific conductance 4.23  10 −4 mho cm −1 .if the degree
of dissociation of acid at this dilution is 0.0612, then equivalent conductance at infinite

dilution is……. mho cm −1 eq −1 .

1*) 172.8 2) 130.1 3) 120.8 4)115.8

31. The   of NH 4OH at infinite dilution is …….S cm2 eq −1 . Given OH


− = 174,  − = 66 and

Cl

NH
 −1
Cl = 130S cm eq respectively.
4
2

1*) 238 2) 218 3) 198 4) 160

32. Two electrolytic cells, one containing acidified ferrous chloride and another acidified ferric
chloride are connected in series. The ratio of iron deposited at cathodes in the two cells
when same electricity is passed through the cells will be:
1) 3:1 2) 2:1 3) 1:1 4*) 3:2

33. The hydrogen electrode is dipped in a solution of pH=3 at 250 C .The reduction potential of
the cell would be:
1) 0.177V 2*) – 0.177V 3) 0.087V 4) 0.059V

34. The standard reduction potentials for Zn 2+ / Zn, Ni 2+ / Ni and Fe2+ / fe are −0.76, −0.23
and

– 0 .44V respectively.The reaction X + Y 2 + → X 2 + + Y will be spontaneous when:

1) X=Ni, Y=Zn 2) X=Fe, Y=Zn 3*) X=Zn, Y=Ni d) X=Ni, Y=Fe

SOLID STATE
35. The formula of an oxide of iron is Fe0.93O1.00 . If the compound has hundred
O −2 ions, then it contains

1. 93Fe +2ions 2. 93Fe +3ions

3*. 79 Fe+2 ,14 Fe+3 4. 93Fe+2 ,14 Fe+3
36. The percentage of void space of a metallic element crystallizing in a
ABCABC…….type lattice pattern is
1. 24% 2*. 26% 3. 34% 4. 74%

37. List – I List – II

A) Antiferromagnetic 1) ZnFe2O4

B) Covalent crystal 2) NiO

C) Ferrimagnetic 3) Diamond
The correct match is
*1. A-2;B-3;C-1 2. A-3;B-2;C-1 3. A-1;B-2;C-3 4. A-1;B-
3;C-2

38 Edge length of cube is 400 pm. Then its body diagonal length would be
1. 600 pm 2. 566 pm 3*. 693 pm 4. 500 pm

39 In a hypothetical ionic crystal, B is arranged in cubic close packing and A

occupies all octahedral voids and alternative tetrahedral voids. Then correct
formula of the compound
1. AB 2. A2 B3 3. AB2 4*. A2 B

40 The electricity produced on applying stress on the crystals is called

1. Pyroelectricity 2*. Piezoelectricity
3. Ferroelectricity 4. Anti-ferroelectricity

41 If one mole of AgCl is dopped with 10−5 mole of CaCl2 , then number of

Ag + ions lost from the lattice

1. 10−5 2. 6 1018 3*. 1.2 1019 4. 3 1018

42 Which of the following system is not correctly characterized?

1. cubic: a = b = c; =  =  = 900

2. tetragonal: a = b  c;  =  =  = 900

3. orthorhombic: a  b  c;  =  =  = 900

4*. rhombohedra: a = b  c;  =  =  = 900

43. In which of the following pairs of structures, tetrahedral as well as octahedral holes are found

1*) hcp and ccp 2) bcc and hcp

3) bcc and fcc 4) hcp and simple cubic

44. A crystal is made of particles X,Y and Z. X forms fcc packing . Y occupies all
the octahedral voids of X and Z occupies all the tetrahedral
voids of X. If all the particles along one body diagonal are removed then
the formula of the crystal would be
1) XYZ 2 2) X 2YZ 2 3) X 8Y4 Z 5 4*) X 5Y4 Z8
45. The type of structure and repeating pattern of sheets in Silver metal lattice is
1*) CCP, ABC ABC ... 2) HCP, ABAB...
3) BCC, ABAB.... 4) HCP, ABC ABC
46. The cubic unit cell of a metal (molar mass = 63.55 gms) has an edge length of 362 p.m. Its
3
density is 8.92 gm / cm , then the type of unit cell is

1*) Face centred 2) Primitive 3) Body centred 4) End centred

47. Radius of atom in terms of edge length (a) in Primitive,Body Centered and Face centered are
respectively

a 3 2 3 2 a a 2 3 a 3 2
1*) , a, a 2) a, a, 3) , a, a 4) , a, a
2 4 4 4 4 2 2 4 4 2 2 2
48. List - I List - II

A) Paramagnetic 1) MgFe2O4

B) Ferro magnetic 2) O2

C) Ferri magnetic 3) CrO2

D) Diamagnetic 4) NaCl
The correct match is
A B C D A B C D
1*) 2 3 1 4 2) 2 1 3 4
3) 3 2 1 4 4) 3 1 2 4

49. A metal has bcc structure and the edge lengths of its unit cell is 3.04 A. The volume of the

unit cell in cm 3 will be

1) 1.6  10 −21 cm3 2*) 2.81 10−23 cm3 3) 6.02  10−23 cm3 4) 6.6  10 −24 cm3
CHEMICAL KINETICS

50. The rate of gaseous reaction is given by k A B .If the volume of reaction

vessel is reduced to 1 4th of initial volume, the reaction rate relative to the
original rate is

1)1/16 2*)16 3)1/8 4)8

51. The rate of reaction between A and B increases 100 folds when the
concentration of A is increased 10 folds. The order of reaction w.r.t. A is

1)10 2)1 3)4 4*)2

52 Plotting a graph of log t1 2 against log A 0 of the reactant for a first order

reaction, the slope will be

1) -1 2) -2 3) +1 4*) 0

53.. The time required for completion of 99.9% of a 1st order reaction is 25 min.
Its t1 2 is

1)20 min 2) 10 min 3) 5 min 4*)2.5 min

54. r1 and r2 are the rates of two reactions whose activation energies are ea and
1

ea respectively. If ea is half of ea , then

2 1 2

1) r1 r2 2) r1 2r2 3*) r1 r2 4) r1 r2
55. Which of the following influence the rate of reaction

A) Nature of reactants B) Concentration of reactants

C) Temperature D) Molecularity

1) A,B 2) B,C,D 3) C,D 4*) A,B,C

−1
For a reaction, activation energy Ea = 0 and rate constant k = 3.2 10 S at 300K, the
6
56.

value of the rate constant at 310K is

−12 −1 −1 −1 −1
1) 3.2 10 S 2) 3.2 10 S 3) 6.4 10 S 4*) 6.4 10 S
6 12 6

57. The molecularity of a reaction is

1*) Number of molecules of reactant taking part in a reaction
2) Number of molecular of product formed in a chemical reaction
3) Positive ratio of reactants & products in a chemical reaction
4) Number of molecules of reactants whose concentration determines the rate of reaction
 k = 210−5 s −1 k =810−6 s −1 k =310−3 s −1
58. Consider the consecutive reactions A ⎯⎯⎯⎯→ B ⎯⎯⎯⎯→ C ⎯⎯⎯⎯→ D . The
rate determining step of the reaction is
1) A → B 2) C → D 3*) B → C 4) A → D
59. In a reaction A + B → products , the rate of reaction decreases by a factor of two if the

concentration of A and B, both are doubled. If only concentration of B is doubled , the rate
decreases by a factor of four. The rate law is

1) r = k  A  B 2*) r = k  A  B 3) r = k  A  B 4) r = k  A  B
−1 −1 1 −2 −1 −2 −2 −2

60. A plot of In keq versus inverse of temperature for reaction is shown in figure. The reaction

must be
6

ln keq

2.0
1.5  10 −3 1 / T ( K −1 ) 2.0  10 −3

1*) exothermic 2) endothermic

3) one with negligible enthalpy change 4) highly spontaneous at ordinary
temperature
61. consider following reactant samples
I. 1 mole of A and 1mole of B in a 1 L vessel
II. 2 mole of A and 2 mole of B in a 2L vessel
III. 0.2 mole of A and 0.2 mole of B in a 0.1 L vessel
Which of the reactant sample reacts at the highest rate ?
1) I 2)II 3*)III 4) All at equal rate
62. A radioactive element has two isotopes ‘L’ and ‘M’, with half-lives of 5 min and 15 min
respectively .An experiment starts with 4 time as many atoms of ‘L’ as of ‘M’. Radioactive
decay is a first-order reaction. How long will it be before the number of ‘L’ left equals the
number of atoms of ‘M’ left
1) 5 min 2) 10 min 3*) 15 min 4) 20 min
63. A+ B C + D; H = −217 kJ / mol . Mark out the incorrect statement(s) regarding the
reaction .
1) The rate of disappearance of B increases on increase of the concentration of A
2) The rate of formation of D increases on increasing the temperature
3) The rate of formation of C increases on increasing the temperature
4*) The use of catalyst doesn’t affect the rate of formation of B or C
SURFACE CHEMISTRY
63 In which one of the following a negatively charged sol is formed?
1. Dil. KI solution is added to excess of AgNO3 solution

2. FeCl3 solution is added to hot water

3*. AgNO3 solution is added to KI solution

4. Haemoglobin is added to water

x
64 In Freundlich adsorption isotherm the graph between and P, the correct
m
relation between T1,T2 and T3 is s

T1
x
m T2
T3
P

1. T1 = T2 = T3 2. T1  T2  T3 3*. T1  T2  T3 4. T1  T2  T3

65 Among the electrolytes Na2SO4 ,CaCl2, Al2 (SO4 )3 and NH 4Cl the most effective

coagulating agent for As2S 3 sol is

1. Na2 SO4 2. CaCl2 3*. Al2 (SO4 )3 4. NH 4Cl

x
66 Plot of log vs log P is a straight line inclined at an angle of 450. When the
m
pressure is 0.5 atm and Freundlich parameter, K is 10, the amount of solute
adsorbed per gram of adsorbent will be (log 5 = 0.0990)
1. 2 g 2. 2.5 g 3*. 5 g 4. 3 g
67 The coagulation of 100ml of a colloidal sol of gold is completely prevented by
adding 0.25 g of starch to it before adding 10ml. of 10% NaCl solution. The
gold number is
1. 0.25 2. 2.5 3*. 25 4. 250
68 The migration of positively charged colloidal particles, under an electrical field
towards the cathode is called
1. Electro-osmosis 2*. Electrophoresis
3. Electro-dialgsis 4. Sedimentation
69 Which one of the following is not heterogeneous catalysis?

1. 2SO2 + O2 ⎯⎯⎯
VO
→ 2SO3
2 5

2. N 2 + 3H 2 ⎯⎯
Fe
→ 2 NH 3

3. 2 H 2O2 ⎯⎯
Pt
→ 2 H 2O + O2
+
4*. CH 3COO C2 H 5 + H 2O ⎯⎯
H
→ CH 3COOH + C2 H 5OH

70 Cod liver oil is

A. fat dispersed in water B. water dispersed in fat
C*. water dispersed in oil D. fat dispersed in fat
71 The incorrect statement is
A*. colloidal solutions are homogeneous
B. colloidal sols carry either positive or negative charge or even no charge
C. colloidal sols show Tyndall effect

D. the size of colloidal particles ranges between 10 A0 to 2000 A0

72 At critical micelle concentration, the surfactant molecules
A. Decompose B. Dissociate
C*. Associate D. becomes completely soluble
73 Among the following surfactant that will form micelles in aqueous solution at the
lowest concentration at ambient condition is

A*. CH 3 − (CH 2 )15 − N + (CH 3 )3 Br − B. CH 3 − (CH 2 )11 − OSO − Na +

+
C. CH 3 − (CH 2 )6 − COO − Na + D. CH3 − (CH 2 )11 − N (CH3 )3 Br −

74 The correct statement regarding a lyophilic sol is/are

A*. Its surface tension is less than surface tension of H 2O

B*. Its viscosity is higher than that of water

C. Its surface tension is higher than that of water
D. Its viscosity can be either less than or greater than water
75 Which of the following statement regarding a micelle is incorrect
A. It is formed at a certain minimum concentration known as “critical
micellization concentration” C.M.C
B. On dilution, a micelle turns into normal solution
C. It contain a charged terminal, either positive or negative
D*. It is a type of macromolecule
76 Detergent action of synthetic detergents is due to their
A. interfacial area B. high molecular weight
C. Ionization D*. emulsifying properties