CHEMISTRY

Q1. Mole fraction of solvent in 0.2 m binary aqueous solution of camphor (m = molality)
(A) 0.996 (B) 0.004 (C) 0.96 (D) 0.976

Q2. Volume V1 ml of 0.1 M K2Cr2O7 is needed for complete oxidation of 0.678g N2H4 in acidic medium.
The volume of 0.3 M KMnO4 needed for same oxidation in acidic medium will be
2 5
(A) V1 (B) V1 (C) 113 V1 (D) can't say
5 2

Q3. Ocidation state of sulphur in Caro's acid, H2SO5 is

(A) +8 (B) +6 (C) +3 (D) - 2

Q4. The molarity of Cl- in an aqueous solution which was (w/V) 2% NaCl, 4% CaCl2 and 6% NH4Cl
will be
(A) 0.342 (B) 0.721 (C) 1.12 (D) 2.18

Q5. The molar ratio of Fe++ to Fe+++ in a mixture of FeSO4 and Fe2(SO4)3 having equal number of
sulphate ion in both ferrous and ferric sulphate is
(A) 1 : 2 (B) 3 : 2 (C) 2 : 3 (D) can't be determined

Q6. How many mg of quick lime is required to remove hardness of 1 Kg of hard water having 366 ppm
of HCO3 and Ca++ as the only cation
(A) 72 mg (B) 84 mg (C) 168 mg (D) 170 mg

Q7. DNA has density 1.1 gm/ml and its molecular weight is 6 x 103 g/mol. Average volume occupied by
its single molecule will be
(A) 9.1 x 10-20cc (B) 9.1 x 10-21cc (C) 9.8 x 10-21cc (D) 9.6 x 10-20cc

Q8. How many ml of 0.3M K2Cr2O7 (acidic) is required for complete oxidation of 5 ml of 0.2 M
SnC2O4 solution
(A) 3.33 ml (B) 2.22 ml (C) 11 ml (D) 4.44 ml

Q9. In the balanced chemical reaction:

aCrO 24   bFe(OH ) 2  4H 2 O  cCr (OH ) 3  dFe(OH ) 3  OH 
the value of a, b, c and d are respectively
(A) 1, 4, 3, 1 (B) 1, 3, 1, 3 (C) 1, 3, 4, 1 (D) 3, 4, 3, 1

Q10. In which of the compound(s) Iodine has positive oxidation state

(A) Iodoform (B) I2O5 (C) ICl (D) HIO3

Q11. For the conversion of 0.240 g NaH2PO4 in a solution to monohydrogen phosphate, 21.4 ml NaOH
solution is needed. The molarity of NaOH solution will be
(A) 0.093 (B) 0.93 (C) 0.087 (D) 0.083

Q12. 22.7 ml of N/10 Na2CO3 solution neutralises 10.2 ml of dilute H2SO4. Then the volume of water
that must be added to 400 ml of same H2SO4 to make it exactly N/10 is
(A) 245 ml (B) 484.6 ml (C) 480 ml (D) 490.2 ml

Q13. The volume of NH3(at STP) needed to pass into 30 ml of 1N H2SO4 solution to bring down its
strength to M/10 is
(A) 0.5 litre (B) 636 ml (C) 537.6 ml (D) 540.3 ml
Q14. 1.0 gm of a mixture of CaCO3 and NaCl reacts completely with 120 ml of N/10 HCl. The percentage
of NaCl in the mixture is
(A) 40% (B) 50% (C) 60% (D) 66%

Q15. 50 g of 8% by mass NaOH is mixed with 100 g of 8% by mass of HCl, the resulting solution is
(A) acidic (B) basic (C) neutral (D) strongly basis

Q16. 0.62g Na2CO3 . xH2O completely neutralises 100 ml of N/10 H2SO4. The value of x muxt be
(A) 1 (B) 6 (C) 8 (D) 10

Q17. How many litre of O3 at STP will be needed to completely oxidise 10 ml of 0.4M KI into I2
(A) 0.448 (B) 0.0448 (C) 4.48 (D) 2.24

Q18. How many moles of FeCr2O4 can be oxidised completely by 1 mole of KMnO4 in acidic medium.
(A) 7 (B) 5 (C) 7/5 (D) 5/7

Q19. A sample of Ca3(PO4)2 contains 3.1 g phosphorous, the weight of Ca in the sample is
(A) 6 gm (B) 4 gm (C) 2 gm (D) 5.56 gm

Q20. For an infinitely dilute aqueous solution molality will be equal to

(A) formality (B) molarity (C) mole fraction (D) ppm

Q21. KI + I2 + HNO3  HIO3 + KIO3 + NO2

If 3 mole of KI & 2 moles I2 are reacted with excess of HNO3, volume of NO2 gas evolved at NTP is
(A) 716.8Lt (B) 1075.2Lt (C) 44.8Lt (D) 67.2Lt

Q22. If a piece of iron gains 10% of its weight due to partial rusting into Fe2O3. the percentage of total iron that
has rusted is
(A) 23 (B) 13 (C) 23.3 (D) 25.67

Q23. In which of the following reaction equivalent weight of oxidant is not difined
(A) 2BrO3- + 12H+ + 10e-  Br2 + 6H2O
(B) BrO3 + eH+ + 6e-  Br- + 3H2O
(C) 3Br2 + 6CO3 + 3H2O  5Br- + BrO3 + 6HCO3
(D) CaOCl2 + H2O  Ca(OH)2 + Cl2

Q24. In which of the following redox reaction 'n' factor of every reactant is non fractional
(A) CsBr + Br2  CsBr3 (B) Mn3O4  Mn++
(C) KI + I2 water
 KI3 (D) NaNH2 + N2O  NaN3 + H2O

Q25. How many mole of electron is needed for reduction of each mole of Cr in the reaction
CrO5 + H2SO4  Cr2(SO4)3 + H2O + O2
(A) 4 (B) 3 (C) 6 (D) 7

Q26. To prepare 0.5M KCl solution from 100 ml of 0.40 M KCl

(A) add 0.745 g KCl (B) add 20 ml of water (C) add 0.1 mole KCl (D) evaporate 10 ml of water

Q27. The moles of Ammonium sulphate needed to react with one mole of MnO2 in acidic medium in a reaction
giving MnSO4 and (NH4)2S2O8 is
(A) 2 (B) 1/2 (C) 1 (D) 1/3
Q28. A 20 ml (specific gravity 1.02) of chlorine water is treated with excess of KI and thr liberated iodine
required 25 ml of 0.2N Na2S2O3. The percentage of free chlorine in chlorine water is
(A) 0.87 (B) 87 (C) 0.78 (D) 0.82

Q29. An ore of iron, Wustite has the formula Fe0.93O1.00. The mole fraction of total iron present in the form of
Fe(II) is
(A) 0.82 (B) 0.85 (C) 0.15 (D) 0.37

Q30. If 1 gm of HCl and 1 gm of MnO2 heated together the maximum weight of Cl2 gas evolved will be
(A) 2 gm (B) 0.975 gm (C) 0.486 gm (D) 0.972 gm

Q31. 35ml sample of hydrogen peroxide gives off 500 ml of O2 at 27oC and 1 atm pressure. Volume strength
of H2O2 sample will be
(A) 10 volume (B) 12.8 volume (C) 11 volume (D) 12 volume

Q32. When 143.6 mg ZnSO4 . xH2O is heated strongly in the absence of air, 40.5 mg yellow residue is
obtained. Value of x is
(A) 7 (B) 5 (C) 6 (D) 2

Q33. Percentage of free SO3 in an oleum bottle labelled 113.5% H2SO4 is

(A) 40 (B) 60 (C) 50 (D) 45

Q34. For 1.34 x 10-3 moles of KBrO3 to reduce into bromide 4.02 x 10-3 mole of Xn+ ion is needed. New
oxidation state of X is
(A) n + 2 (B) n - 2 (C) 2 (D) -2

Q35. Each molecule of tear gas, Lewisite contains 2 Hydrogen atoms, 1.78 x 10-22 gm. Chlorine, 2 carbon
atoms and 1.25 x 10-22 gm of an unknown metal. Its molecular weight will be
(A) 206 (B) 207.5+1 (C) 280 (D) 280.8

Q36. We have three separate solutions of KCl, MgCl2 and AlCl3. The concentration of Cl- ion is same in all
three solution. Which solution will require the least volume to coagulate (precipitate) a negativelycharged
colloidal solution.
(A) KCl solution (B) MgCl2 solution (C) AlCl3 solution (D) All the same

Q37. What volume of 0.3N Cr2O7--/H+ is needed for complete oxidation of 200 ml of 0.6M FeC2O4 soution.
(A) 1.2 cc (B) 1.2 Litre (C) 120 cc (D) 800 cc

Q38. 25 ml of Na2CO3 solution requires 100 ml of 0.1N HCl to reach end point with Phenolphthalein as
indicator. Molarity of resulting solution with respect to HCO3- ion
(A) 0.008M (B) 0.004M (C) 0.16M (D) 0.08M

Q39. Which concentration of a solution will change on heating a solution

(A) molality (B) mole fraction (C) volume strength (D) %(W/V)

Q40. 5 gm of a metal carbonate on heating strongly releases 1.51 litre CO2 gas at STP. The equivalent weight
of metal is
(A) 7 (B) 23 (C) 21 (D) 5

Q41. If equal volumes of 0.1M KMnO4 and 0.1M K2Cr2O7 solutions are allowed to oxidise. Fe2+ to Fe3+ in
acidic medium, then Fe2+ oxidised will be
(A) more by KMnO4 (B) more by K2Cr2O7 (C) equal in both cases (D) can't be determined.
Q42. Equivalent weight of MnO4- in acidic, basic and nuetral medium are in the ratio of
(A) 3 : 5 : 15 (B) 5 : 3 : 1 (C) 5 : 1 : 3 (D) 3 : 15 : 5

Q43. Cl2 reacts with hot NaOH solution, oxidation number of chlorine changes from
(A) -1 to 0 (B) 0 to -1 (C) 0 to +5 (D) b; c.

Q44. Molarity of H2SO4 is 18 M. Its density is 1.8 g/cm3, hence molality is

(A) 18 (B) 100 (C) 36 (D) 500

Q45. x g of the metal gave y g of its oxide. Hence equivalent weight of the metal
yx x x xy
(A) x8 (B) x8 (C) x8 (D) x8
x (y  x) y x

Q46. Mole fraction of ethyl alcohol in aqueous ethyl alcohol solution is 0.25. Hence percentage of ethyl
alcohol by weight is
(A) 54% (B) 25% (C) 75% (D) 46%

Q47. 254g of Iodine and 142 g of Chlorine are made to react completely to give a mixture of ICl and ICl3. The
moles of each one formed is
(A) 0.1M ICl and 0.1M ICl3 (B) 1.0M ICl and 1.0M ICl3
(C) 0.5M ICl and 0.1M ICl3 (D) 0.5M ICl and 1.0M ICl3

Q48. 0.1M of MnO4-(in acidic medium) can(Assume the volume of reducing agent will be same in the MnO4-)
(A) oxidise 0.25M C2O42- (B) oxidise 0.5M Fe2+
(C) oxidise 0.166M FeC2O4 (D) oxidise 0.6M Cr2O72-

Q49. Which of the following are redox reactions?

(A) Zn + 2HCl  ZnCl2 + H2 (B) Al(OH)3 + 2HCl  AlCl3 + 3H2O
(C) Disproportionation of Cu+ ions in a gave solution (D) Ag+(aq.) + I-(aq.)  AgI(s)

Q50. In which of the following species, valency and oxidation numbers have different numerical values?
(A) CO2 (B) CH4 (C) CHCl3 (D) CCl4