REDOX_C3_EQUIVALENT

WEIGHT_REDOX TITRATION

Dr. Manoj Majumder, MTBC

EFFERVESCENCE Coochbehar
 REDOX_C3_EQUIVALENT WEIGHT_REDOX TITRATION

LEVEL-EASY: (a) mol. wt. (b) mol. wt./8

1. In the conversion NH2OH→N2O, the equivalent (c) mol. wt./6 (d) none of these
weight of NH2OH will be :
(a) M/4 (b)M/2 (c)M/5 (d)M/1 11. The eq. wt. of K2CrO4 as an oxidising agent in acid
medium is
2. The mass of oxalic acid crystals (H2C2O4 .2H2O) (a) mol. wt./2 (b) 2 mol. wt./3
required to prepare 50 mL of a 0.2 N solution is : (c) mol. wt./3 (d) mol. wt./6
(a) 4.5 g (b) 6.3 g
(c) 0.63 g (d) 0.45 g 12. If equal volumes of 0.1 M KMnO4 and 0.1 M K2
Cr2O7 solutions are allowed to oxidise Fe2+ to Fe3+ in
3. M is molecular weight of KMnO4.. The equivalent acidic medium, then Fe2+ oxidised will be :
weight of KMnO4 when it is converted into K2MnO4 is : (a) More by KMnO4 (b) More by K2Cr2O7
(a) M (b) M/3 (c) Equal in both cases (d) Cannot be determined.
(c) M/5 (d) M/7
13. Volume V1 mL of 0.1M K2Cr2O7 is needed for
4. The equivalent mass of oxidising agent in the complete oxidation of 0.678 g N2H4 in acidic medium.
following reaction is SO2 + 2H2S → 3S + 2H2O The volume of 0.3 M KMnO4 needed for same
(a) 32 (b) 64 (c) 16 (d) 8 oxidation in acidic medium will be :
(a) 2/5 V1 (b) 5/2 V1
5. In the following reaction : (c) 113 V1 (d) Can not be determined
NO3- + As2S3 + H2O → AsO43- + NO +SO42- + H+
the equivalent weight of As2S3 (with molecular 14. 80 mL of KMnO4 solution reacts with 3.4 g of Na2
weight M) is : C2O4 .2H2O in acidic medium. The molarity of the
(a) 3M/28 (b) M/4 KMnO4 solution is
(c) M/24 (d) M/28 (a) 0.5 M (b) 0.1 M
(c) 5 M (d) 1 M
6. Equivalent weight of H3PO2 (molecular weight = M)
when it disproportionates into PH3 and H3PO3 is 15. What weight of NaHSO3 is required to react with
(a) M (b) M/2 100 mL of solution containing 0.33 g of NaIO3
(c) M/4 (d) 3M/4 according to the following reaction
IO3- + HSO3-→ I- + SO42-
7. Equivalent weight of MnO4- in acidic, neutral and (a) 0.52 g (b) 5.2 g
basic media are in ratio of : (c) 1.04 g (d) 10.4 g
(a) 3 : 5 : 15 (b) 5 : 3 : 1
(c) 5 : 1 : 13 (d) 3 : 15 : 5 16. How many moles of MnO4- ion will react with 1
mol of ferrous oxalate in acidic medium ?
8. K2CrO4 oxidises KI in the presence of HCl to I2 . The (a) 1/5 (b) 2/5
equivalent weight of the K2CrO4 is (c) 3/5 (d) 5/3
2
(a) M/2 (b) M × 3
17. What volume of 0.05 M K2Cr2O7 in acidic medium
(c) M/3 (d)M/6 is needed for complete oxidation of 200 mL of 0.6 M
FeC2O4 solution?
9. The equivalent weight of MnSO4 is half its (a) 1.2 mL (b) 1.2 L
molecular weight when it is converted to (c) 120 mL (d) 800 mL
(a) Mn2O3 (b) MnO2
(c) MnO4 (d) MnO42- 18. KI reacts with H2SO4 producing I2 and H2S. The
volume of 0.2 M H2SO4 required to produce 0.1 mol of
10. In the reaction VO + Fe2O3→FeO+V2O5 H2S is
the eq. wt. of V2O5 is equal to its (a) 4 L (b) 2.5 L

DR. MANOJ MAJUMDER, MTBC 1

 REDOX_C3_EQUIVALENT WEIGHT_REDOX TITRATION

(c) 3.8 L (d) 5 L

LEVEL-HARD(ADVANCE):
ANSWER KEY:
19. (I) When BrO3 ion react with Br ion in acidic
- –
LEVEL-EASY:
medium, Br2 is liberated. Calculate the ratio of 1-B 2-C 3-A 4-C 5-D 6-D 7-A
molecular weight and equivalent weight of KBrO3. 8-C 9-B 10-C 11-C 12-B 13-A
14-B 15-A 16-C 17-B 18-B
20. (I) A volume of 12.5 mL of 0.05 M SeO2 reacts
with 25mL of 0.1M CrSO4 which is oxidised to Cr3+. To
what oxidation state was the selenium converted by ANSWER KEY:
the reaction? LEVEL-HARD(ADVANCE):
19(I)-0005 20(I)-0000 21-A 22-A 23-
21. For the reaction, H3PO2 + NaOH→ NaH2PO2 + H2O M/8 24-B 25-A,C,D
What is the equivalent weight of H3PO2 ? (mol. wt. is
M)
(a) M (b) M/2
(c) M/3 (d) None of these

22. For the reaction,

Fe0.95O (molar mass: M) → Fe2O3. What is the eq. wt.
of Fe0.95O ?
(a) M/0.85 (b) M/0.95
(c) M/0.8075 (d) None of these

23. (I) In the reaction :

Na2S2O3 + 4Cl2 + 5H2O → Na2SO4 + H2SO4 + 8HCl, the
equivalent weight of Na2S2O3 will be : (M = molecular
weight of Na2S2O3)

24. 1 mole of equimolar mixture of ferric oxalate and

ferrous oxalate will require x mole of KMnO4 in acidic
medium for complete oxidation, x is:
(a) 0.5 mole (b) 0.9 mole
(c) 1.2 mole (d) 4.5 mole

25. 25 mL of 0.5 M H2O2 solution is added to 50 mL of

0.2 M KMnO4 in acid solution. Which of the following
statements is false :
(a) 0.010 mole of oxygen gas is liberated.
(b) 0.005 mole of KMnO4 is left.
(c) 0.030 g of oxygen gas is evolved.
(d) 0.0025 mole H2O2 does not react with KMnO4.

DR. MANOJ MAJUMDER, MTBC 2