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Advanced Level Problem Solving-2212

JEE 2022 | Chemistry
JEE ADVANCED Full Syllabus
*Mark questions are more than one options correct type

1. In the reaction : CrO5 + H2SO4 

 Cr2 (SO4 )3 + H2 O + O2
How many moles of O2 are liberated by 1 mol of CrO5 in above reaction?
(A) 5/2 (B) 5/4 (C) 9/2 (D) 7/4
2. A hydrogen like species (atomic number Z) is present in a higher excited state of quantum number n. This excited
atom can make a transition to the first excited state by successive emission of two photons of energies 10.20 eV
and 17.0 eV respectively. Alternatively, the atom from the same excited state can make a transition to the second
excited state by successive emission of two photons of energy 4.25 eV and 5.95 eV respectively. Determine the
value of Z.
(A) 1 (B) 2 (C) 3 (D) 4
Paragraph for Questions 3 - 4
Kinetic theory of gases is a generalization offered by Maxwell, Boltzman, Clausius, etc., to explain the behavior of ideal
gases. This theory assumes that ideal gas molecules neither attract nor repel each other. Average kinetic energy of a gas
molecules is directly proportional to the absolute temperature. A gas equation called kinetic gas equation was derived on the
basis of kinetic theory.
1
PV  mnv2
3
3. The average kinetic energy per molecule of an ideal gas is equal to :
(A) 0.5 kJ (B) 0.5 RT (C) 1.5 KT (D) 1.5 RT2
4. Which of the following do not pertain to the postulates of kinetic theory of gases?
(A) No loss in kinetic energy during collision.
(B) Speed of gas molecules are ever changing.
(C) Pressure exerted by the gas is due to the collision of molecules with the walls of the container.
(D) Kinetic energy of a gas is given by the sum of 273 and temperature in Celsius scale.
5. In which pair first compound has more dipole moment than second compound?
(A) P(CH3)2(CF3)3, P(CH3)3(CF3)2 (B) CH3Cl, CH3F
(C) NH3, NF3 (D) Benzene, Borazine
6. When AgNO3 is heated mildly in a closed vessel, oxygen is liberated and AgNO2 is left behind. At equilibrium
1
according to reaction AgNO3 (s) AgNO2 (s)  O2 (g) :
2
(A) Addition of AgNO2 favours reverse reaction
(B) Addition of AgNO3 favours forward reaction
(C) Increasing temperature favours forward reaction
(D) Increasing pressure favours reverse reaction

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7. Match the Following:

Column 1 Column 2
(A) CH3COOH  NaOH (p) pH > 7
5 ml 1N 5 ml 1N

(B) CH3COOH  NaOH (q) pH < 7

15 ml 1N 10 ml 1N

(C) HCl  NH4OH (r) Buffer

5 ml 1N 15 ml 1N

(D) HCl  NaOH (s) Hydrolysis occurs

1 ml 1N 1 ml 2N

8. Certain amount of a gas confined in a piston-filled cylinder is heated from 27°C to 127°C and the gas expanded
against a constant pressure doing 4.157 kJ of work on surroundings. The number of moles of gas present in the
cylinder is(are) __________.

9. For first order reaction: A 

 P, the temperature (T) dependent rate constant ‘k’ was found to follow the
2000
equation log10 k  6  . The pre-exponential factor ‘A’ and activation energy Ea, respectively :
T
(A) 1  106 s1 and 9.2 kJ mol1
(B) 6.0s 1 and 16.6 kJ mol 1

(C) 1  06 and 16.6 kJ mol1

(D) 1  106 s 1 and 38.3 kJ mol1

10. Which of the following 0.1 M aqueous solutions will have the lowest freezing point?
(A) K 2SO 4 (B) NaCl
(C) Glucose (D) Urea
11. Beryllium occurs naturally in the form of beryl. The metal is produced from its ore by electrolysis after the ore has
been converted to the oxide and then to the chloride. How many grams of Be(s) is deposited from a BeCl 2 solution
by a current of 5.0 A that flows for 1.0 h? (Atomic weight: Be = 9)
(A) 0.840 (B) 1.68 (C) 1.42 (D) 1.08
12. Which of the following statements are false :
(A) The radius of a metal atom is taken as half of the nearest metal-metal distance in a metallic crystal
(B) One tetrahedral void per atom is present in hcp structure
(C) In the fluorite structure (CaF2), the Ca2+ ions are located at the lattice points and the fluoride ions fill all
the tetrahedral holes in the ccp crystal.
(D) In the antifluorite structure (Li2O, Rb2S) the cations are located at the lattice points and anions fill the
tetrahedral holes in the ccp structure.
13. When CH 2  CH  Br is reacted with HBr then the product formed is A and when CH 2  CH  COOH is
treated with HBr then the product is formed is C. Hence, here:
A is CH 2  CH 2
(A) | | (B)
Br Br

C is CH 2  CH 2  COOH
C is CH3  CH  COOH |
(C) | (D) Br
Br

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Paragraph for Questions 14 - 15

Labels of two bottles (X) and (Y) were missing in the lab, as result scientist was not able to know the names of compounds
present in those bottles. By quantitative analysis he found that compounds in both the bottles have molecular formula
C6H12O. Now to know the structure and name of compounds, he did some qualitative test for identification of these
compounds present in bottles (X) and (Y). Compound in bottle (X) was found to meet following criterion:
(i) It gives iodoform test. (ii) It gives DNP test.
(iii) It shows optical rotation. (iv) On vigorous oxidation it gives only acetic acid.
On the other hand, compound in bottle (Y) was found to meet following criterion:
(i) It gives Tollen’s reagent test (ii) It gives DNP test
(iii) It shows optical rotation (iv) On aldol condensation it goes upto - unsaturated carbonyl
(v) It forms crystals with NaHSO3
14. The structure of compound in bottle (X) using above information would be :
O CH3
CH3  CH 2  C  CH  CH3 CH3  CH2  CH  C  CH3
(A) (B)
CH3 O

(C) CH3  CH2  CH  CH2  CHO (D) CH3  C  CH2  CH2  CH 2  CH3
CH3 O
15. Structure of compound in bottle (Y) would be:
O
(A) CH3  CH 2  CH  C  CH3 (B) CH3  CH 2  CH  CH 2  CHO
CH 3 CH3

(C) CH3  CH 2  CH 2  CH  CHO (D) CH3  CH  CH 2  CH 2  CHO

CH3 CH3

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16. Which of the following benzyl halide would undergo S N 1 reaction faster ?

(A) (B) (C) (D)

17. Identify the dicarboxylic acid having molecular formula C5H8O4, which is chiral, form cyclic anhydride and does
not decarboxylate.
CH3
(A) HO2CCCO2H (B) HO2CCHCO2H
CH3 C2H5
(C) HO2CCHCH2CO2H (D) HO2CCH2CH2CH2CO2H
CH3
O O
18. 
PhNHNH2
 Product X, X is
Ph OEt
Ph Ph

N
N Ph N N Ph
N N N
N
Ph Ph Ph
O O O Ph O
(A) (B) (C) (D)
19. Natural rubber is 1, 4-addition polymer of isoprene. Find out number of carbon atoms in longest continuous carbon
chain of major product of reductive ozonolysis of natural rubber.
20. An effective atomic number of Co(CO) 4 is 35 and hence is less stable. It attains stability by :
[Atomic number of Co = 27]
I. Oxidation of Co II. Reduction of Co
III. Dimerization IV. Trimerization
The correct option is :
(A) I, II (B) II, III (C) I, II, III (D) II, IV
21. Match the following :
Column 1 (metallurgical process) Column 2 (ore)
(A) Smelting (p) Copper glance
(B) Self reduction (q) Silver glance
(C) Electrolytic reduction (r) Haematite
(D) Hydrometallurgy (s) Bauxite

22. Which of the following reactions liberate gaseous product?

(A) AlCl3  NaOH 
 (B) NaOH  P(white)  H2O 

Δ Δ
(C) Al  NaOH  (D) Zn  NaOH 

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23. The number of R 2Si(OH) 2 units required to prepare a linear silicone polymer containing eight Si–O–Si linkages,
is _________.

24. Which of the following is/are correct balanced equation(s) for the formation of P2 O 74  ?
Δ
(A) 2H3PO 4 
250260C
H 4 P2O7  H 2O (B) 5H 3PO 4  POCl3 
 3H 4P2O 7  3HCl

(C) P4O10  4H 2O 
 2H 4 P2O7 (D) H3PO 4  H3PO3 
 H 4 P2O7  H 2

25. Cr2+ is reducing while Mn3+ is oxidizing because :

(A) Both have d4 configuration
(B) In Cr2+ its electronic configuration changes from d4 to d3
(C) In Mn 3 its electronic configuration changes from d4 to d5
(D) Of the increasing stability of the species to which they are converted
26. A mixture of Na2C2O4 and KHC2O4.H2C2O4 required equal volumes of 0.2 M KMnO4 and 0.2 M NaOH separately for
complete titration. The mole ratio of Na2C2O4 and KHC2O4.H2C2O4 in the mixture is :
(A) 2/11 (B) 11/2 (C) 5/2 (D) 7/2

27. Consider the following dissociation of O 2 (dissociation energy 498 kJ mol1 )

hv
O2  O  O*
O* is more energetic than normal oxygen atom (O) by 1.967eV. The maximum wavelength in nm for

photochemical dissociation is ________. (Given : N A  6.02 1023 J mol1 , h  6.62 1034 Js, C  3 108 ms 1 )

28. Consider the reaction

2X(g)  3Y(g) 
 Z(g)
Where gases X and Y are insoluble and inert to water and Z form a basic solution. In an experiment 3 mole each
of X and Y are allowed to react in 15 lit flask at 500 K. When the reaction is complete, 5L of water is added to the
flask and temperature is reduced to 300 K. The pressure in the flask is (neglect aqueous tension)________atm.
[Given : R  0.0821Latm1 mol1 K 1 ]
29. Which of the following is incorrectly matched?
(A) H2O  HF - (Enthalpy of vaporistaion)
(B) SbH3  NH3  AsH3  PH3 - (Boiling point)
(C) CH2OHCHOHCH2OH  CH2OHCH2OH - (Viscosity)

(D) - (Basicity of starred nitrogen)

30. Match the following:

Column 1 Column 2
(A) For the equilibrium NH4 I  s  NH3  g   HI  g  , if pressure (p) Forward shift
is increased at equilibrium
(B) For the reaction : N2 (g)  3H2 (g) 2NH3 (g) at equilibrium, (q) No change
volume is increased at equilibrium
(C) For the reaction : H2O  g   CO  g  H2  g   CO2  g  inert (r) Backward shift
gas is added at constant pressure at equilibrium.
(D) For the equilibrium : PCl5 (g) PCl3 (g)  Cl2 (g) , Cl2 is (s) Final pressure is more than initial
removed at equilibrium pressure

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31. Find the pKa of a weak acid, if titration progress is monitored as follows:

32. The given reaction

2CO  O2 
 2CO2 H   560 kJ
2 moles 1mole
is carried in one litre container, if the pressure in the container gets changes from 70 atm to 40 atm as reaction gets
completed. Calculate U in kJ of the reaction. [1L atm = 0.1 kJ]
33. In the Lindemann theory of unimolecular reactions, it is shown that the apparent rate constant for such a reaction is
k1C
k app  here C is the concentration of the reactant, k1 and  are constants. The value of C for which kapp
1  C
has 90% of its limiting value at C tending to infinitely large values, given   9 105 is 10 x mol L1. Find value
of x.
34. Two volatile liquids A and B form ideal solution. Considering the following vapour-pressure composition graph

OR will be equal to :
(A) OP  OQ (B) OP  PR (C) OQ  QR (D) OQ  PQ
Paragraph for Questions 35- 37

The given electrochemical cell setup has standard hydrogen electrode as anode and Fe3 / Fe 2 half-cell as cathode. Ce4+
(cerric) ion is added from the burette to beaker containing Fe2+ ion, when following reaction occurs.

Fe2 aq Ce4 aq Fe3 aq Ce3 aq

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With the addition of Ce4+ ion, the half – cell potential changes, and is measured directly by the voltmeter. Given;
Eº  1.64V, Eº   0.80V . The concentration of Fe2+ solution is 0.1 M and its volume is 600 ml. The
Ce4 / Ce3 Fe2 / Fe3
concentration of Ce4+ solution added from burette is 0.1 M.
35. The potential of the cell after 1/3rd of the ferrous ion has been titrated will be :
(A) 1.64 V (B) 0.782 V (C) 1.522 V (D) 0.682 V
4+ 2+
36. The potential of the cell at equivalence point in the titration of Ce and Fe , will be :
(A) 1.22 V (B) 0.42 V (C) 1.64 V (D) 0.8 V
37. The equilibrium constant for the reaction in cathode half-cell is :
(A) (B) (C) (D)
38. Match the following :
Set – I Set – II
(Possible arrangement of atoms in different planes)
(1) Simple cubic (P)

(2) Body centred cubic (Q)

(3) Face centred cubic (R)

(4) Hexagonal close packing (S)

(A) 1 – Q, 2 – R, 3 – P,R,S 4 – P (B) 1 – Q, 2 – P, 3 – S, 4 – R

(C) 1 – P, 2 – R, 3 – Q, 4 – S (D) 1 – R, 2 – S, 3 – P, 4 – Q
39. Total number of stereo isomers corresponding to structure

40. How many of the following reactions are correctly represented?

1.

2.

3.

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4.

5.

6.

7.

8.

41.

The total number of isomeric products (including stereoisomers) formed at the end of the reaction is :
42. How many organic compounds (given below) react with NaHCO3 and liberate CO 2 ?

CCl3  COOH CH3  CH2  OH HCl

43. How many p-orbitals are parallel to each other in the following conjugated system ?

x
44. Graph between log and log P is a straight line inclined at an angle 45°. When pressure of 0.5atm and
m
log k  0.699, the amount of solute adsorbed per g of adsorbent will be :

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45. Match the following:

Set – I (Complex Compound) Set – II (Type of Isomerism Shown)
(1) [Co(H 2 O)3 F3 ] (P) Geometrical isomerism

(2) [Co(en)3 ]Cl3 (Q) Optical isomerism

(3) [Co(en) 2 (NO 2 ) 2 ]Cl (R) Linkage isomerism

(4) K 3 [Cr(CN) 6 ] (S) Ionisation isomerism

(A) 1 – P, 2 – Q, 3 – R, 4 – S (B) 1 – Q, 2 – P, 3 – S, 4 – R
(C) 1 – P, 2 – Q, 3 – P,Q,R,S 4 – R (D) 1 – R, 2 – Q, 3 – S, 4 – P

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46. How many of the following metals and method of their reduction are correctly matched?
1. Al; Electrolytic reduction 2. Pb; Self reduction
3. Sn; Carbon reduction 4. Mg; Electrolytic reduction
5. Hg; Self reduction 6. Cu; Self reduction
7. Ag; Chemical reduction 8. Fe; Carbon reduction
9. Zn; Carbon reduction
47. Number of non-radioactive alkali metals forming superoxide as major product on heating with excess O2  x
Number of II-A metals of periodic table whose hydrated halides suffer hydrolysis on heating = y
Number of non radio active alkali metals which dissolve in liquid ammonia and produce blue colour solution = u
The value of (x + y – u) would be ……
48. Match the column:
Column 1 (Reagent) Column 2 Reaction)
(A) O3 (p) SnCl 2  SnCl 4
(B) H 2O2 (q) Arsenite  Arsenate
(C) HNO3 (r) PbS  PbSO 4
(D) H 3 PO 3 (s) MnO4  Mn 2
(t) AgNO3 
 Ag
49. How many of the following chlorides can be hydrolysed?
BCl3 ,CCl4 ,SiCl 4 , NCl3 , PCl3 , AsCl3 ,SbCl3 ,SCl 4 , ICl3
50. Transition metals and their compound catalyse reactions because:
(A) They have completely filled s-subshell
(B) They have a comparable size due to poor shielding of d-subshell
(C) They introduce an entirely new reaction mechanism with a lower activation energy
(D) They have variable oxidation states differ by two units
51. A fluoride of Xenon reacts with excess of hydrogen to give 22.4 ml of Xenon at STP and liberated certain amount of
HF, which is trapped in water. This hydrofluoric acid solution requires 60 ml of 0.1 M NaOH to neutralize it completely. The
formula of Xenon fluoride will be:
(A) XeF2 (B) XeF4
(C) XeF6 (D) XeF8

52. The angular momentum of an electron in a Bohr's orbit of H-atom is 3.1652×10–34 kg-m2/sec. Calculate the
wavenumber in terms of Rydberg constant (R) of the spectral line emitted when an electron falls from this level to
the ground state.[Use h = 6.6 × 10–34 Js]
8 5 7
(A) R  (B) R  (C) R  (D) None of these
9 9 9
53. Which of the following is(are) correct for a gas obeying vander waal’s equation?
 a 
(A) A gas having negligible size and reasonable intermolecular force follow  P  2   Vm   RT
 Vm 

Pb
(B) A gas having negligible intermolecular force and reasonable size follow: Z = 1 
RT
(C) A gas having negligible size and negligible intermolecular force follow PVm  RT
(D) At Boyle’s temperature, gas follow PVm  RT at all pressure

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Paragraph for Questions 54 - 55

The shape of a molecule is determined by the number of groups of electrons around the central atom. The ‘groups’ might
be a non-bonding single electron, a non-bonding or bonding pair of electrons, a double pair of bonding electrons or triple
pair of bonding electrons etc. The electron ‘groupings’ minimise the repulsion to decrease potential energy of the system
i.e., to make the Q – X – Q angle as wide as possible. (X = central atom, Q = surrounding atom).
According to VSEPR theory repulsive interaction are summarized as lone pair – lone pair > lone pair – bond pair > bond
pair – bond pair. So that as the lone pair – ‘other pair repulsion increases, the angle between these pairs increases, so the
Q – X – Q angle will be slightly reduced compared to what might be expected from the simple geometry or shape.
54. In which of the following pair both species have same Cl – X – Cl bond angle?
I. CCl4, SiCl4 II. POCl3, SO2Cl2 III. BCl3, AlCl3 IV. SOCl2, COCl2
(A) I, II (B) III, II, I (C) I, III (D) II, IV
55. In which of the following species presence of L.P does not affect idealized bond angle?
I. PF3 II. BrF3 III. IF5 IV. ICI4 V. XeF2
(A) I, II, III (B) IV, V (C) II, V (D) None of these

56. The equation for the reaction in the figure below is :

H2 (g)  I2 (g)  Heat 2HI(g) .
At the instant 3 min, what change was imposed into the
equilibrium?
(A) Pressure was increased
(B) Temperature was increased
(C) Iodine was added to the system
(D) Hydrogen was added to the system

57. Which of the following indicator is most suitable for titration of HB with strong base :
(A) Phenolphthalein (8.3 – 10) (B) Bromothymol blue (6 – 7.6)
(C) Methyl red (4.2 – 6.3) (D) Malachite green (11.4 – 13)
58. Select the correct option(s) :
(A) Molar internal energy is an intensive property.
(B) Heat capacity at constant pressure is an extensive property
(C) Reversible process can be reversed at any point in the process by making infinitesimal change.
(D) Less heat is absorbed by the gas in the reversible isothermal expansion as compared to irreversible, when
expanded to same final volume.
59. Match the following:
Column 1 (Half – life) Column 2 (Order of reaction)
(A) t1/ 2  constant (p) First order

(B) t1/ 2  a (q) Pseudo first order

(C) 1 (r) Second order

t1/ 2 
a
(D) 1 (s) Zero order
t1/ 2 
p
a = Initial concentration of reactant ; p = Initial pressure of gaseous reactant
60. The vapour pressure of pure water at 37°C is 47.1 torr. What is the vapour pressure in torr of an aqueous solution
at 37°C containing 20 g of glucose dissolved in 500 gm of water.

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61. A galvanic cell is composed of two hydrogen electrodes, of which cathode is a standard hydrogen electrode. In
which of the following solutions, should the other electrode be immersed to get maximum e.m.f. ?
(A) 0.1 M HCl (B) 0.1 M H2SO4
(C) 0.1 M HCO2H (D) 0.01 M HCOOH
62. Which of the following statements are correct ?
(A) The co-ordination number of each type of ions in CsCl crystals is 8
(B) A metal which crystallizes in bcc structure has co-ordination number of 12
(C) 
The edge length of a unit cell in NaCl is 552 pm. rNa   95 pm, rC   181 pm 
(D) A unit cell of an ionic crystal shares some of its ions with other unit cells.
Br 3.0 eqv. CH I
63. C6 H5  CH  CH 2 
2
 A 
NaNH
 B 
3
 C Compound ‘C’ in the sequence is :
2

(A) (B) (C) (D)

64.

The major product of the above reaction is :

Et Me  C  CH  CH3
| |
Me  C  CH  CH2CH3 n  Pr

(A) (B) (C) (D)

65. Which of the following will not be formed on intramolecular aldol reaction of 6-oxoheptanal when treated with
aqueous solution of NaOH?

(A) (B) (C) (D)

66. Which of the following reactions are used for the preparation of aldehyde only :
(i) Sn  HCl
RCH2OH 
 Product
PCC
(A) R – C  N 
  Product (B)
(ii) H3O CH 2Cl2

LiAlH(t  BuO) Pd  BaSO

(C) RCOCl 
3
 Product (D) RCOCl + H2  4
S or Quinoline
 Product
67. Match the following:
Column 1 Column 2
(A) CH3CH2CH2NH2 (p) Treatment of NaNO2, HCl gives nitroso compound
Treatment of NaNO2, HCl gives stable diazonium
(B) CH3CH2NHCH3 (q)
chloride at lower temperature
Treatment of CH3I (excess) followed by AgOH,
(C) (r)
heat gives out alkene
Treatment with HCl and on heating gives
(D) (s)
dealkylation.
Treatment of benzene sulphonyl chloride produces
(t)
the compound soluble in alkali

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68. A reddish brown sol (containing Fe3+) is obtained by

(A) The addition of small amount of FeCl3 solution to freshly prepared Fe(OH)3 precipitate
(B) The addition of Fe(OH)3 to freshly prepared FeCl3 solution
(C) The addition of NH4OH to FeCl3 solution dropwise
(D) The addition of NaOH to FeCl3 solution dropwise
69. The pair in which both species have same magnetic moment [spin only]
2 2 2
Cr  H2 O 6  , CoCl4  Cr  H2 O 6  , Fe  H 2O 6 
2
(A) (B)
2 2 2
Mn  H2 O 6  , Cr  H2 O 6  CoCl4  , Fe  H2 O 6 
2
(C) (D)

70. Which of the following reactions occurs during calcination?

(A) CaCO3  MgCO3  CaO  MgO  CO2 (B) FeS2  11O2  2Fe2O3  8SO2
(C) 2Al(OH)3  Al2O3  3H2O (D) Cu 2S  2CuO  4Cu  SO2

71. Match the following:

Column 1 (Hydride) Column 2 (Type of hydride)
(A) BeH 2 (p) Complex

(B) AsH3 (q) Lewis acid

(C) B2 H 6 (r) Covalent

(D) LiAlH 4 (s) Polymeric

(t) Ionic

72. How many of the following ammonium salts on dry heating evolve ammonia gas?
NH4NO3, NH4NO2, NH4HS, NH4Cl, NH4COONH2, (NH4)2Cr2O7, (NH4)2CO3, (NH4)2C2O4, NH4ClO4
73. Which of the following dissociation results in an increase in paramagnetism?
 
(A) 2O3 
 3O2 (B) N2O4   2NO2
 
(C) N2O3   NO  NO2 (D) S8   4S2
74. How many of the following hydrated metal halides on heating directly can form anhydrous halides.
MgCl2  6H 2O, AlCl3  6H2O, FeCl3  6H2O, CrCl3  6H2O, LiCl  2H 2 O, BaCl2  6H2 O, CaCl2  6H 2 O ,
SnCl2  2H2O, ZnCl2  2H 2 O

75. How many of the following orders are correct:

(i) Be(OH)2  Mg(OH)2  Ca(OH)2  Ba(OH) 2 Basic character
(ii) BaCO3  SrCO3  CaCO3  MgCO3 Decomposition temperature

(iii) Na   Mg 2  Li   Be2 Size in gas phase

(iv) Li2CO3  Na 2 CO3  K 2 CO3  Rb2 CO3  Cs2CO3 Water solubility
(v) LiHCO3  NaHCO3  KHCO3  RbHCO3  CsHCO3 Thermal Stability
(vi) NaF  NaCl  NaBr  NaI Melting point
(vii) He  O2  CO2  O3  CH4 Value of poison’s ratio (  )
(viii) Na 2O2  KO2  O2 [AsF4 ] O  O bond length

VMC | Chemistry 13 ALPS-2212| JEE-2022